Loctite SF 7840 #693-797, 693-804 (NZ)

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier

• Product name: Loctite SF 7840 #693-797, 693-804 (NZ)
• Synonyms: Product Code: 693-797; 693-804
• Chemical Name: Not Applicable
• Chemical formula: Not Applicable
• Other means of identification: Not Available

Relevant identified uses of the substance or mixture and uses advised against

• Relevant identified uses: Cleaner.

Details of the manufacturer or importer of the safety data sheet

• Registered company name: RS Components
• Address: PO Box 12-127 Penrose, Auckland New Zealand
• Telephone: +64 27 4747122
• Fax: +64 9 579 1700
• Website: www.nz.rs-online.com
• Email: nzorder@rs-components.com

Emergency telephone number

• Association / Organisation: CHEMWATCH EMERGENCY RESPONSE (24/7)
• Emergency telephone number(s): +64 800 700 112 (ID#: 5417-15)
• Other emergency telephone number(s): +61 3 9573 3188

SECTION 2 Hazards identification

Classification of the substance or mixture

Not considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. Not regulated for transport of Dangerous Goods.

Chemwatch Hazard Ratings

Legend: 0 = Minimum, 1 = Low, 2 = Moderate, 3 = High, 4 = Extreme

Classification [1]: Non hazardous

Determined by Chemwatch using GHS/HSNO criteria: Not Available

Label elements

• Hazard pictogram(s): Not Applicable
• Signal word: Not Applicable
• Hazard statement(s): Not Applicable
• Precautionary statement(s) Prevention: Not Applicable
• Precautionary statement(s) Response: Not Applicable

SECTION 3 Composition / information on ingredients

Mixtures

Legend: 1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 4. Classification drawn from C&L; * EU IOELVs available

SECTION 4 First aid measures

Description of first aid measures

• Eye Contact: If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
• Skin Contact: If skin or hair contact occurs: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
• Inhalation: If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.
• Ingestion: If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Firefighting measures

Extinguishing media

• Water spray or fog.
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.

Special hazards arising from the substrate or mixture

• Fire Incompatibility: Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.

Advice for firefighters

• Fire Fighting: Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Avoid spraying water onto liquid pools. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.
• Fire/Explosion Hazard: Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO). May emit acrid smoke. Mists containing combustible materials may be explosive.
• Combustion products: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

• Minor Spills: Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.
• Major Spills: Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

• Safe handling: Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.

Other information

• Store in original containers.
• Keep containers securely sealed.
• No smoking, naked lights or ignition sources.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

• Suitable container: Metal can or drum, Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.
• Storage incompatibility: Avoid reaction with oxidising agents.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

MATERIAL DATA

Exposure controls

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in special circumstances. If risk of overexposure exists, wear approved respirator. Supplied-air type respirator may be required in special circumstances. Correct fit is essential to ensure adequate protection. Provide adequate ventilation in warehouses and enclosed storage areas. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.

Type of Contaminant:

• solvent, vapours, degreasing etc., evaporating from tank (in still air). Air Speed: 0.25-0.5 m/s (50-100 f/min)
• aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) Air Speed: 0.5-1 m/s (100-200 f/min.)
• direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) Air Speed: 1-2.5 m/s (200-500 f/min.)
• grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of very high rapid air motion) Air Speed: 2.5-10 m/s (500-2000 f/min.)

Within each range the appropriate value depends on:

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used.

Individual protection measures, such as personal protective equipment

• Eye and face protection: Safety glasses with side shields. Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
• Skin protection: See Hand protection below.
• Hands/feet protection: Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber.
• Body protection: Overalls. P.V.C apron.
• Other protection: Barrier cream. Skin cleansing cream. Eye wash unit.

Respiratory protection

Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required. Degree of protection varies with both face-piece and Class of filter; the nature of protection varies with Type of filter.

Legend: * CPI - Chemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion C: Poor to Dangerous Choice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

SECTION 10 Stability and reactivity

• Reactivity: Unstable in the presence of incompatible materials.
• Chemical stability: Product is considered stable.
• Possibility of hazardous reactions: Hazardous polymerisation will not occur.
• Conditions to avoid: See section 7
• Incompatible materials: See section 7 (Avoid reaction with oxidising agents)
• Hazardous decomposition products: See section 5

SECTION 11 Toxicological information

Information on toxicological effects

• a) Acute Toxicity: Based on available data, the classification criteria are not met.
• b) Skin Irritation/Corrosion: Based on available data, the classification criteria are not met.
• c) Serious Eye Damage/Irritation: Based on available data, the classification criteria are not met.
• d) Respiratory or Skin sensitisation: Based on available data, the classification criteria are not met.
• e) Mutagenicity: Based on available data, the classification criteria are not met.
• f) Carcinogenicity: Based on available data, the classification criteria are not met.
• g) Reproductivity: Based on available data, the classification criteria are not met.
• h) STOT - Single Exposure: Based on available data, the classification criteria are not met.
• i) STOT - Repeated Exposure: Based on available data, the classification criteria are not met.
• j) Aspiration Hazard: Based on available data, the classification criteria are not met.

Inhaled: The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This is because of the lack of corroborating animal or human evidence. In the absence of such evidence, care should be taken nevertheless to ensure exposure is kept to a minimum and that suitable control measures be used, in an occupational setting to control vapours, fumes and aerosols.

Ingestion: Ingestion may result in nausea, abdominal irritation, pain and vomiting.

Skin Contact: Open cuts, abraded or irritated skin should not be exposed to this material. Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye: The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.

Chronic: Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of course.

Ingredient Specific Data:

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

PROPYLENE GLYCOL MONOMETHYL ETHER - ALPHA ISOMER: NOTE: For PGE - mixed isomers: Exposure of pregnant rats and rabbits to the substance did not give rise to teratogenic effects at concentrations up to 3000 ppm. Foetotoxic effects were seen in rats but not in rabbits at this concentration; maternal toxicity was noted in both species. For propylene glycol ethers (PGEs): ... (detailed toxicological information follows)

N-COCOALKYL-BETA-IMINODIPROPIONIC ACID, SODIUM SALT & DISODIUM DICARBOXYETHYL COCOPROPYLENEDIAMINE: No significant acute toxicological data identified in literature search.

Legend: ☑ - Data either not available or does not fill the criteria for classification

SECTION 12 Ecological information

Toxicity

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

Persistence and degradability

Bioaccumulative potential

Mobility in soil

SECTION 13 Disposal considerations

Waste treatment methods

• Product / Packaging disposal: DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Authority for disposal. Bury or incinerate residue at an approved site. Recycle containers if possible, or dispose of in an authorised landfill. Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017.

Disposal Requirements: Not applicable as substance/ material is non hazardous.

SECTION 14 Transport information

Labels Required

• Marine Pollutant: NO
• HAZCHEM: Not Applicable

Transport Classification:

• Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
• Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
• Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.7. Maritime transport in bulk according to IMO instruments

• 14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code: Not Applicable
• 14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code:

14.7.3. Transport in bulk in accordance with the IGC Code:

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

This substance is to be managed using the conditions specified in an applicable Group Standard

• HSR Number: Not Applicable
• Group Standard: Not Applicable

Please refer to Section 8 of the SDS for any applicable tolerable exposure limit or Section 12 for environmental exposure limit.

Regulatory Lists:

• propylene glycol monomethyl ether - alpha isomer is found on the following regulatory lists: New Zealand Approved Hazardous Substances with controls, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals - Classification Data, New Zealand Inventory of Chemicals (NZIoC), New Zealand Workplace Exposure Standards (WES).
• N-cocoalkyl-beta-iminodipropionic acid, sodium salt is found on the following regulatory lists: New Zealand Inventory of Chemicals (NZIoC).
• disodium dicarboxyethyl cocopropylenediamine is found on the following regulatory lists: New Zealand Inventory of Chemicals (NZIoC).
• triethanolamine is found on the following regulatory lists: International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals - Classification Data, New Zealand Inventory of Chemicals (NZIoC), New Zealand Workplace Exposure Standards (WES).

Additional Regulatory Information: Not Applicable

Hazardous Substance Location: Subject to the Health and Safety at Work (Hazardous Substances) Regulations 2017.

• Hazard Class: Not Applicable
• Quantities: Not Applicable

Certified Handler: Subject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

• Class of substance: Not Applicable
• Quantities: Not Applicable

Refer Group Standards for further information.

Maximum quantities of certain hazardous substances permitted on passenger service vehicles: Subject to Regulation 13.14 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

Tracking Requirements: Not Applicable

National Inventory Status:

Legend: Yes = All CAS declared ingredients are on the inventory. No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration.

SECTION 16 Other information

Revision Date: 04/04/2025

Initial Date: 24/07/2020

SDS Version Summary

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

• PC-TWA: Permissible Concentration-Time Weighted Average
• PC-STEL: Permissible Concentration-Short Term Exposure Limit
• IARC: International Agency for Research on Cancer
• ACGIH: American Conference of Governmental Industrial Hygienists
• STEL: Short Term Exposure Limit
• TEEL: Temporary Emergency Exposure Limit
• IDLH: Immediately Dangerous to Life or Health Concentrations
• ES: Exposure Standard
• OSF: Odour Safety Factor
• NOAEL: No Observed Adverse Effect Level
• LOAEL: Lowest Observed Adverse Effect Level
• TLV: Threshold Limit Value
• LOD: Limit Of Detection
• OTV: Odour Threshold Value
• BCF: BioConcentration Factors
• BEI: Biological Exposure Index
• DNEL: Derived No-Effect Level
• PNEC: Predicted no-effect concentration
• MARPOL: International Convention for the Prevention of Pollution from Ships
• IMSBC: International Maritime Solid Bulk Cargoes Code
• IGC: International Gas Carrier Code
• IBC: International Bulk Chemical Code
• AIIC: Australian Inventory of Industrial Chemicals
• DSL: Domestic Substances List
• NDSL: Non-Domestic Substances List
• IECSC: Inventory of Existing Chemical Substance in China
• EINECS: European Inventory of Existing Commercial chemical Substances
• ELINCS: European List of Notified Chemical Substances
• NLP: No-Longer Polymers
• ENCS: Existing and New Chemical Substances Inventory
• KECI: Korea Existing Chemicals Inventory
• NZIoC: New Zealand Inventory of Chemicals
• PICCS: Philippine Inventory of Chemicals and Chemical Substances
• TSCA: Toxic Substances Control Act
• TCSI: Taiwan Chemical Substance Inventory
• INSQ: Inventario Nacional de Sustancias Químicas
• NCI: National Chemical Inventory
• FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

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