Kärcher FloorPro Grundreiniger RM 69 eco!efficiency
Document Date: 20.06.2025
Safety Data Sheet according to Regulation (EC) No. 1907/2006, Article 31
Version Number: 8 (replaces Version 7)
Last Revised: 08.10.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product Identifier
Trade Name: FloorPro Grundreiniger RM 69 eco!efficiency
UFI: 1S50-300P-T006-5QHC
1.2 Relevant identified uses of the substance or mixture and uses advised against
For professional users only.
Use of the substance/mixture: Floor cleaner
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Alfred Kärcher SE & Co. KG
Alfred-Kärcher-Str. 28-40
D-71364 Winnenden
Tel.: +49-7195-14-0
Alfred Kärcher Ges.mbH
Lichtblaustr. 7
A-1220 Wien
Tel.: +43-1-25060-0
Kärcher AG
Industriestr. 16
CH-8108 Dällikon
Fon: +41-44-8466-777
Internet: www.karcher.com
Contact Point:
Regulatory Affairs
Tel.: +49-7195-14-0
productsafety.management.de@karcher.com
1.4 Emergency telephone number:
Poison Information Center (VIZ)
(+43) 1 406 43 43
In case of incidents involving hazardous substances [or dangerous goods]
Spillage, Leakage, Fire, Exposure or Accident:
Call CHEMTREC, 24 hours a day.
Outside USA and Canada: +1 703 741-5970 (R-calls possible)
Inside USA and Canada: 1-800-424-9300
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008
Skin Corr. 1 H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms:
GHS05
Signal word: Danger
Hazardous components for labelling:
Isotridecanol ethoxylate + 8 EO
Hazard statements:
H314 Causes severe skin burns and eye damage.
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Wash skin with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Assessment of endocrine-disrupting properties: Not applicable.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description: Cleaning agent.
Hazardous ingredients:
| CAS: | Name | % | Classification |
|---|---|---|---|
| 112-34-5 | Butyldiglycol | 1-5% | Eye Irrit. 2, H319 |
| 69011-36-5 | Isotridecanol ethoxylate + 8 EO | ≥3-≤5% | Eye Dam. 1, H318; Acute Tox. 4, H302 |
Regulation (EC) No. 648/2004 on detergents / Labelling of ingredients
Non-ionic surfactants: <5%
Fragrances (TERPINEOL)
Additional remarks: The wording of the listed hazard statements can be found in Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice: Remove contaminated clothing immediately.
After inhalation:
In case of unconsciousness place patient stably in side position for transport. Supply fresh air; in case of troubles call a doctor.
After skin contact: Immediately wash with soap and water and rinse thoroughly.
After eye contact:
Rinse eyes with open eyelids for several minutes under running water and consult a doctor.
After swallowing:
Rinse mouth and drink plenty of water. Do not induce vomiting, call for medical help immediately. Drink plenty of water and ensure fresh air. Call for medical help immediately.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
5.1 Suitable extinguishing media
Suitable extinguishing media: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol-resistant foam.
5.2 Special hazards arising from the substance or mixture
No further relevant information available.
5.3 Advice for firefighters
Special protective equipment: No special measures required.
Additional information: Collect contaminated extinguishing water separately, do not allow to reach sewage system.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected people away.
6.2 Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/surface water/groundwater.
Do not allow to penetrate the ground/soil.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomaceous earth, acid binder, universal binder). Apply neutralising agent.
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
6.4 Reference to other sections
Information for safe handling see section 7.
Information for personal protection see section 8.
Information for disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Avoid aerosol formation.
Avoid contact with eyes and skin.
Notes about fire and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements for storage rooms and containers: No special requirements.
Co-storage instructions: Keep away from foodstuffs, beverages and feed.
Further information about storage conditions: Keep container tightly closed.
VbF class: not applicable
7.3 Specific end use(s)
No further relevant information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Components with workplace-related control parameters:
112-34-5 Butyldiglycol
MAK Short-term value: 101.2 mg/m³, 15 ml/m³
Long-term value: 67.5 mg/m³, 10 ml/m³
8.2 Exposure controls
Appropriate engineering controls: No further information, see Section 7.
Individual protection measures, such as personal protective equipment
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Contaminated work clothing to be removed immediately.
Wash hands before breaks and at end of work.
Avoid contact with eyes and skin.
Respiratory protection:
For short-term or low exposure, use an approved respirator; for intensive or longer exposure, use self-contained breathing apparatus.
Filter A2 - P2.
Hand protection:
Protective gloves.
Glove material: Butyl rubber 0.7 mm, 480 min
Breakthrough time of the glove material: The exact breakthrough time must be obtained from the glove manufacturer and observed.
Eye/face protection:
Tight-fitting safety goggles. EN 166
SECTION 9: Physical and chemical properties
9.1 Basic physical and chemical properties
General Information
Form: Liquid
Colour: blue
Odour: citrus-like
Odour threshold: Not determined.
Melting point/freezing point: -5 °C
Boiling point or initial boiling point and boiling range: Not determined.
Flammability: Not applicable.
Lower and upper explosion limits:
Lower: Not determined.
Upper: Not determined.
Flash point: Not applicable.
Auto-ignition temperature: Not applicable.
Decomposition temperature: Not determined.
pH-value at 20 °C: 12.2
Viscosity: Not determined.
Kinematic viscosity: Not determined.
dynamic: Not determined.
Solubility:
Water: completely miscible
Partition coefficient n-octanol/water (log value): Not determined.
Vapour pressure: Not determined.
Density and/or relative density
Density at 20 °C: 1.043 g/cm³
Relative density: Not determined.
Vapour density: Not determined.
Relative vapour density: Not determined.
Particle characteristics: Not applicable.
9.2 Other information
Appearance:
Form: liquid
Important information on protection and environmental protection and safety
Ignition temperature: The product is not self-igniting.
Explosive properties: The product is not explosive. (EEC 92/69/EWG, A4)
Change in state: Not determined.
Evaporation rate: Not determined.
Hazard classes for physical hazards:
Explosive substances/mixtures and explosives containing explosives: not applicable
Flammable gases: not applicable
Aerosols: not applicable
Oxidising gases: not applicable
Gases under pressure: not applicable
Flammable liquids: not applicable
Flammable solids: not applicable
Self-reactive substances and mixtures: not applicable
Pyrophoric liquids: not applicable
Pyrophoric solids: not applicable
Self-heating substances and mixtures: not applicable
Substances and mixtures which, in contact with water, emit flammable gases: not applicable
Oxidising liquids: not applicable
Oxidising solids: not applicable
Organic peroxides: not applicable
Substances and mixtures which, in contact with water, emit flammable gases: not applicable
Oxidising liquids: not applicable
Oxidising solids: not applicable
Organic peroxides: not applicable
Corrosive to metals: not applicable
Substances and mixtures with explosive properties of desensitised explosives: not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
corresponds to 10.3
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition by proper use.
10.3 Possibility of hazardous reactions
No hazardous reactions known.
10.4 Conditions to avoid
No further relevant information available.
10.5 Incompatible materials:
No further relevant information available.
10.6 Hazardous decomposition products:
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No. 1272/2008
Acute toxicity: Based on available data, the classification criteria are not met.
Relevant classified LD/LC50 values:
112-34-5 Butyldiglycol
Oral LD50 2410 mg/kg (mouse) (OECD 401)
Dermal LD50 2764 mg/kg (rabbit)
69011-36-5 Isotridecanol ethoxylate + 8 EO
Oral ATE 500 mg/kg (rat)
Primary irritant effect:
Skin corrosion/irritation: Causes severe skin burns and eye damage.
Serious eye damage/eye irritation: Causes serious eye damage.
Respiratory or skin sensitisation: Based on available data, the classification criteria are not met.
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
Specific target organ toxicity - single exposure: Based on available data, the classification criteria are not met.
Specific target organ toxicity - repeated exposure: Based on available data, the classification criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met.
11.2 Other hazards
Endocrine-disrupting properties
541-02-6 Decamethylcyclopentasiloxane: List II
540-97-6 Dodecamethylcyclohexasiloxane: List II
556-67-2 Octamethylcyclotetrasiloxane: List II; III
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
112-34-5 Butyldiglycol
LC50/96 h 1300 mg/l (Lepomis macrochirus)
EC10/16 h 1170 mg/l (Pseudomonas putida)
EC50/24 h 2850 mg/l (Daphnia magna) (DIN 38412)
NOEC >100 mg/l (Desmodesmus subspicatus)
69011-36-5 Isotridecanol ethoxylate + 8 EO
LC50/96 h >1-10 mg/l (Leuciscus idus)
EC50/48 h >1-10 mg/l (Aquatic invertebrates)
EC50/72 h >1-10 mg/l (Aquatic plants)
NOEC >1 mg/l (21 d)
12.2 Persistence and degradability
No further relevant information available.
Degree of elimination:
112-34-5 Butyldiglycol
OECD 301C 80-90% (28 d)
OECD 301E >70% (28 d)
OECD 302B 100% (28 d)
69011-36-5 Isotridecanol ethoxylate + 8 EO
OECD 301B >60% (28 d)
OECD 301E ≥90% (28 d)
12.3 Bioaccumulative potential
No further relevant information available.
12.4 Mobility in soil
No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Endocrine-disrupting properties
For information on endocrine-disrupting properties see Section 11.
12.7 Other adverse effects
Further ecological advice:
General advice:
The product is free of organically bound halogens (AOX-free).
The surfactants contained in this formulation meet the biodegradability requirements as laid down in Regulation (EC) No. 648/2004 on detergents. Documents confirming this are held for the competent authorities of the Member States and are only made available to them either directly or at their request.
The organic complexing agents contained achieve a DOC elimination degree of 80% (according to No. 406 of Annex "Analysis and Measurement Methods") and thus meet the stricter requirements of Annex 49 of the new Wastewater Ordinance.
Do not allow undiluted or large quantities to enter groundwater, water bodies or the sewage system.
Flushing larger quantities into sewers or water bodies can lead to an increase in pH-value. A high pH-value damages aquatic organisms. When diluted to the application concentration, the pH-value is significantly reduced, so that wastewater entering the sewage system after use of the product has only a low hazard to water.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow to enter sewage system.
Must be disposed of by special treatment in accordance with official regulations.
European Waste Catalogue:
20 01 29* detergents containing dangerous substances
Uncleaned packaging:
Recommendation:
Contaminated packaging should be emptied optimally; after appropriate cleaning they can be passed on for recycling.
Recommended cleaning agent: Water, possibly with addition of cleaning agents.
SECTION 14: Transport information
14.1 UN number or ID number
ADR, IMDG, IATA: UN3267
14.2 UN proper shipping name
ADR: 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Methylglycinediacetic acid, trisodium salt, solution)
IMDG, IATA: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (methylglycine diacetic acid, trisodium salt, solution)
14.3 Transport hazard class(es)
ADR
Class: 8 (C7) Corrosive substances
Label: 8
IMDG, IATA
Class: 8 Corrosive substances
Label: 8
14.4 Packing group
ADR, IMDG, IATA: III
14.5 Environmental hazards:
Not applicable.
14.6 Special precautions for user
Kemler Number: 80
EMS Number: F-A,S-B
Segregation groups: (SGG18) Alkalis
Stowage Category: A
Stowage Code: SW2 Clear of living quarters.
Segregation Code: SG35 Stow "separated from" SGG1-acids
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.
Transport/further information:
ADR
Limited quantity (LQ): 5L
Excepted quantities (EQ): Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (METHYLGLYCINDIACETIC ACID, TRISODIUM SALT, SOLUTION), 8, III
Tunnel restriction code: E
IMDG
Limited quantities (LQ): 5L
Excepted quantities (EQ): Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/specific legislation for the substance or mixture
Directive 2012/18/EU
Named dangerous substances - ANNEX I: None of the ingredients is listed.
REGULATION (EC) No. 1907/2006 ANNEX XVII Conditions of restriction: 3, 55
National regulations:
Information on employment restrictions: Observe employment restrictions for young people.
Classification according to VbF: not applicable
Technical Instructions Air:
| Class | Proportion in % |
|---|---|
| NK | 5.0 |
ÖNORM M 9485:
| Class | Proportion in % |
|---|---|
| NK | 5.0 |
15.2 Chemical safety assessment:
A chemical safety assessment has not been carried out.
SECTION 16: Other information
The information provided is based on our current knowledge and experience, but does not constitute any assurance of product properties and does not establish any legally binding contractual relationship.
A product information sheet is available and will be sent on request.
Relevant sentences:
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
Classification according to Regulation (EC) No. 1272/2008
Skin irritating/corrosive effect: The classification of the mixture is generally based on the calculation method under Regulation (EC) No 1272/2008.
Serious eye damage/eye irritation:
Contact person:
Regulatory Affairs
Tel.: +49-7195-14-0
productsafety.management.de@karcher.com
Version number of the previous version: 7
Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VbF: Ordinance on flammable liquids, Austria (Ordinance on the storage of combustible liquids, Austria)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity - Category 4
Skin Corr. 1: Skin irritation/corrosion - Category 1
Eye Dam. 1: Serious eye damage/eye irritation - Category 1
Eye Irrit. 2: Serious eye damage/eye irritation - Category 2
Data compared to the previous version changed:
0-011-328-0 RM69Eco/7 2-775
