SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: PressurePro Machine Protector Advance 2 RM 111
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture: Scale inhibitor
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Alfred Kärcher SE & Co. KG
Alfred-Kärcher-Str. 28-40
D-71364 Winnenden
Tel.: +49-7195-14-0
Kärcher (UK) Ltd.
Kärcher House
Brookhill Way
Banbury
Oxon OX16 3ED
Great Britain
Tel.: +44-1295-752-000
Internet: www.karcher.com
Further information obtainable from:
Regulatory Affairs
Tel.: +49-7195-14-0
productsafety.management.de@karcher.com
1.4 Emergency telephone number:
For Hazardous Materials [or Dangerous Goods] Incidents
Spill, Leak, Fire, Exposure, or Accident
Call CHEMTREC Day or Night
Within USA and Canada: 1-800-424-9300
Outside USA and Canada: +1 703-741-5970 (collect calls accepted)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The product is not classified, according to the GB CLP regulation.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
Void
Hazard pictograms
Void
Signal word
Void
Hazard statements
Void
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description: Scale inhibitor
Dangerous components:
| CAS | EINECS | Reg.nr. | Substance | Classification | Concentration |
|---|---|---|---|---|---|
| 1312-76-1 | 215-199-1 | 01-2119456888-17 | potassium silicate | Met. Corr.1, H290; Skin Corr. 1B, H314; Eye Dam. 1, H318 | ≥5-≤20% |
| 15763-76-5 | 239-854-6 | 01-2119489411-37-xxxx | sodium p-cumenesulphonate | Eye Irrit. 2, H319 | 1-5% |
| 120313-48-6 | Alcohols, C12-15-branched and linear, ethoxylated propoxylated | Aquatic Acute 1, H400; Skin Irrit. 2, H315; Aquatic Chronic 3, H412 | ≥1-<2.5% |
Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
After inhalation
In case of unconsciousness place patient stably in side position for transportation. Supply fresh air; consult doctor in case of complaints.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Rinse out mouth and then drink plenty of water. Drink plenty of water and provide fresh air. Call for a doctor immediately. If symptoms persist consult doctor.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
No further relevant information available.
5.3 Advice for firefighters
Protective equipment:
No special measures required.
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions:
Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Do not allow to penetrate the ground/soil.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Use neutralising agent. Dispose contaminated material as waste according to section 13. Ensure adequate ventilation.
6.4 Reference to other sections
See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols.
Information about fire - and explosion protection:
No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Keep away from food, beverages and feed.
Further information about storage conditions:
Keep receptacle tightly sealed.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
DNELs
| 15763-76-5 sodium p-cumenesulphonate | Oral | DNEL | 3.8 mg/kgxd (consumer) | |
| Dermal | DNEL | 136.25 mg/kgxd (employee) | 68.1 mg/kgxd (consumer) | |
| Inhalative | DNEL | 26.9 mg/m3 (employee) | 6.6 mg/m3 (consumer) |
PNECs
| 15763-76-5 sodium p-cumenesulphonate | PNEC | 0.23 mg/l (freshwater) |
| 0.023 mg/l (marine water) | ||
| 100 mg/l (STP) | ||
| PNEC sediment | 0.862 mg/kg (freshwater) | |
| 0.086 mg/kg (marine water) | ||
| PNEC soil | 0.037 mg/kg (soil) |
8.2 Exposure controls
Appropriate engineering controls
No further data; see section 7.
Individual protection measures, such as personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin.
Respiratory protection:
Not necessary if room is well-ventilated.
Hand protection
Not required.
Material of gloves
Not required.
Penetration time of glove material
Not required.
Eye/face protection
Not required.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Physical state: Liquid
Colour: Yellow
Odour: Odourless
Odour threshold: Not determined.
Melting point/freezing point: 0 °C
Boiling point or initial boiling point and boiling range undetermined
Flammability Not applicable.
Lower and upper explosion limit
Lower: Not determined.
Upper: Not determined.
Flash point: Not applicable
Auto-ignition temperature: not applicable
Decomposition temperature: Not determined.
pH at 20 °C 12.3
pH-value 1 %: 10-11
Viscosity:
Kinematic viscosity Not determined.
dynamic: Not determined.
Solubility
Water: Fully miscible
Partition coefficient n-octanol/water (log value) Not determined.
Vapour pressure: Not determined.
Density and/or relative density
Density at 20 °C: 1.215 g/cm³
Relative density Not determined.
Vapour density Not determined.
Relative gas density Not determined.
9.2 Other information
Appearance:
Form: Fluid
Important information on protection of health and environment, and on safety.
Ignition temperature: Product is not selfigniting.
Explosive properties: Product does not present an explosion hazard.
Change in condition
Evaporation rate Not determined.
Information with regard to physical hazard classes
- Explosives: Void
- Flammable gases: Void
- Aerosols: Void
- Oxidising gases: Void
- Gases under pressure: Void
- Flammable liquids: Void
- Flammable solids: Void
- Self-reactive substances and mixtures: Void
- Pyrophoric liquids: Void
- Pyrophoric solids: Void
- Self-heating substances and mixtures: Void
- Substances and mixtures, which emit flammable gases in contact with water: Void
- Oxidising liquids: Void
- Oxidising solids: Void
- Organic peroxides: Void
- Corrosive to metals: Void
- Desensitised explosives: Void
SECTION 10: Stability and reactivity
10.1 Reactivity
Corresponds to 10.3
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions
No dangerous reactions known
10.4 Conditions to avoid
No further relevant information available.
10.5 Incompatible materials:
No further relevant information available.
10.6 Hazardous decomposition products:
No dangerous decomposition products known
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity: Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification:
| 15763-76-5 sodium p-cumenesulphonate | Oral LD50 >5000 mg/kg (Rat) (OECD 401) | Dermal LD50 >2000 mg/kg (Rabbit) |
Primary irritant effect:
Skin corrosion/irritation
No irritant effect (test report is available, OECD 404) Based on available data, the classification criteria are not met.
Serious eye damage/irritation
No irritant effect (Survey is available, OECD 405) Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation
Based on available data, the classification criteria are not met.
Germ cell mutagenicity
Based on available data, the classification criteria are not met.
11.2 Information on other hazards
Endocrine disrupting properties
None of the ingredients is listed.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
| 15763-76-5 sodium p-cumenesulphonate | LC50/96 h (static) >100 mg/l (Oncorhynchus mykiss) | EC50/48 h (static) >100 mg/l (Daphnia magna) |
| EC50/96 h (static) >100 mg/l (Pseudokirchneriella subcapitata) | ||
| 120313-48-6 Alcohols, C12-15-branched and linear, ethoxylated propoxylated | LC50/96 h >1-<10 mg/l (fish) | EC50/48 h ≤1 mg/l (Daphnia magna) |
| EC50/72 h ≤1 mg/l (Algae) | EC10/72 h >0.1-<1 mg/l (Algae) |
12.2 Persistence and degradability
No further relevant information available.
12.3 Bioaccumulative potential
No further relevant information available.
12.4 Mobility in soil
No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Endocrine disrupting properties
The product does not contain substances with endocrine disrupting properties.
12.7 Other adverse effects
Additional ecological information:
COD-value: 127.000 mg/l
General notes:
The product does not contain organically bounded halogens (AOX-free). The contained organic complexing agents reach a DOC-elimination grade of 80% (corresponding to No. 406 of Annex "Analytic and measuring methods") and with this meet the tightened demands of Annex 49 of the revised Direction on liqid waste.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations.
European waste catalogue
20 01 30 detergents other than those mentioned in 20 01 29
Uncleaned packaging:
Recommendation:
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.
Recommended cleansing agents:
Water, if necessary together with cleaning agents.
SECTION 14: Transport information
14.1 UN number or ID number
ADR, IMDG, IATA: Void
14.2 UN proper shipping name
ADR, ADN, IMDG, IATA: Void
14.3 Transport hazard class(es)
ADR, ADN, IMDG, IATA Class: Void
14.4 Packing group
ADR, IMDG, IATA: Void
14.5 Environmental hazards:
Not applicable.
14.6 Special precautions for user
Not applicable.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.
UN "Model Regulation": Void
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poisons Act
Regulated explosives precursors: None of the ingredients is listed.
Regulated poisons: None of the ingredients is listed.
Reportable explosives precursors: None of the ingredients is listed.
Reportable poisons: None of the ingredients is listed.
Directive 2012/18/EU
Named dangerous substances - ANNEX I: None of the ingredients is listed.
National regulations
Information about limitation of use: Employment restrictions concerning juveniles must be observed.
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. A product information sheet can be provided if requested.
Relevant phrases
H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.
Contact:
Regulatory Affairs
Tel.: +49-7195-14-0
productsafety.management.de@karcher.com
Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (UK REACH)
PNEC: Predicted No-Effect Concentration (UK REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Met. Corr.1: Corrosive to metals – Category 1
Skin Corr. 1B: Skin corrosion/irritation - Category 1B
Skin Irrit. 2: Skin corrosion/irritation - Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard - Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard - Category 3
* Data compared to the previous version altered.
0-011-798-0 RM 111/3 2-859
