SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name: PC201, PC202RF, PC204RF, PC300RF, PC301, PC302RF, PC304RF Ink film
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant Identified Use(s): These products are thermal ink films for Brother Industries, Ltd. facsimile receivers. These products should be used as supplied by Brother and for use in the products stated. Information provided on this SDS is only consistent with the use specified by Brother.
1.3 Details of the supplier of the safety data sheet
Manufacturer: Brother Industries, Ltd. 15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan. Telephone (for information): +81-52-824-2735
Importer (USA): Brother International Corporation. 200 Crossing Boulevard, Bridgewater, NJ 08807, USA. Telephone (for information): +1-877-276-8437
Importer (Canada): Brother International Corporation (Canada) Ltd. 1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada. Telephone (for information): +1-514-685-0600
Importer (Europe): Brother International Europe Ltd. Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK. Telephone (for information): +44-161-330-6531
Importer (Australia): Brother International (Aust.) Pty. Ltd. ACN 001 393 835. Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia. Telephone (for information): +61-2-9887-4344
E-mail Address: sds.info@brother.co.jp
1.4 Emergency telephone number
Emergency Telephone (24 hours): CHEMTREC +1-703-527-3887 (International), +1-800-424-9300 (North America). For France only: Antipoison Center telephone number: ORFILA +33-1-45-425-959
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008: Not classified as hazardous
Classification according to Directive 1999/45/EC: Not classified as hazardous
Australia Classification: Not classified as hazardous according to the criteria of NOHSC
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008:
Hazard pictograms: None
Signal Word: None
Hazard Statements: None
Precautionary statements: None
2.3 Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description of the mixture: Ink on substrate film (Mixture).
| Chemical Name | CAS-No | EC-No | w/w% | Classification (EU Reg. 1272/2008) |
|---|---|---|---|---|
| Polyethylene terephthalate | 25038-59-9 | 48-54 | Not classified | |
| Paraffin wax | 8002-74-2 | 232-315-6 | 23-28 | Not classified |
| Carbon Black | 1333-86-4 | 215-609-9 | 6-9 | Not classified |
| Resin | ** | 5-7 | Not classified | |
| Carnauba wax | 8015-86-9 | 232-399-4 | 4-6 | Not classified |
| Ethylene-vinyl acetate copolymer | 24937-78-8 | 4-5 | Not classified | |
| Pigment | ** | 0.5-1 | Not classified |
For the full text of R-phrases and H-Statements see Section 16
** CONFIDENTIAL
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice: If symptoms persist, obtain medical attention.
Inhalation: Unlikely route of exposure. If symptoms develop obtain medical attention.
Skin contact: Wash affected skin with plenty of water or soap and water.
Eye contact: Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of water for at least 15 minutes.
Ingestion: Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to drink.
4.2 Most important symptoms and effects, both acute and delayed
No specific effects and/or symptoms have been reported or known.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable Extinguishing Media: Extinguish preferably with dry chemical, carbon dioxide, water, foam.
Unsuitable Extinguishing Media: None.
5.2 Special hazards arising from the substance or mixture
Thermal decomposition can lead to release of irritating and toxic gases and vapors: Carbon oxides.
5.3 Advice for firefighters
Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self-contained breathing apparatus (SCBA) during the attack phase of firefighting operations and during cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not having suitable respiratory protection must leave the area to prevent significant exposure to toxic combustion gases from any source.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Not normally required.
6.2 Environmental precautions
Not normally required.
6.3 Methods and materials for containment and cleaning up
Not applicable.
6.4 Reference to other sections
For personal protection: See section 8. For disposal considerations: See section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Keep out of the reach of children.
7.2 Conditions for safe storage, including any incompatibilities
Keep out of the reach of children. Keep away from oxidizing agents.
7.3 Specific end use(s)
These products are thermal ink films for Brother Industries, Ltd. facsimile receivers. These products should be used as supplied by Brother and for use in the products stated. Information provided on this SDS is only consistent with the use specified by Brother.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters
Occupational Exposure Limits
Paraffin wax (8002-74-2)
| ACGIH TLV | OSHA PEL | |
|---|---|---|
| European Union | TWA: 2 mg/m³ | |
| The United Kingdom | STEL: 6 mg/m³ | |
| France | TWA: 2 mg/m³ | |
| Spain | TWA: 2 mg/m³ | |
| Portugal | TWA: 2 mg/m³ | |
| Finland | TWA: 2 mg/m³ | |
| Denmark | TWA: 1 mg/m³ | |
| Switzerland | TWA: 2 mg/m³ | |
| Poland | TWA: 2 mg/m³ | |
| Norway | TWA: 2 mg/m³ | |
| Ireland | STEL: 4 mg/m³ |
Carbon Black (1333-86-4)
| ACGIH TLV | OSHA PEL | |
|---|---|---|
| European Union | TWA: 3 mg/m³ inhalable fraction | TWA: 3.5 mg/m³ |
| The United Kingdom | STEL: 7 mg/m³ | |
| France | TWA: 3.5 mg/m³ | |
| Spain | TWA: 3.5 mg/m³ | |
| Germany | Carc | |
| Portugal | TWA: 3.5 mg/m³ | |
| Finland | TWA: 3.5 mg/m³ | |
| Denmark | STEL: 7 mg/m³ | |
| Poland | TWA: 3.5 mg/m³ | |
| Norway | TWA: 4.0 mg/m³ | |
| Ireland | TWA: 3.5 mg/m³ | |
| STEL: 7 mg/m³ | ||
| TWA: 3.5 mg/m³ | ||
| STEL: 7 mg/m³ |
8.2 Exposure controls
Appropriate engineering controls: Good general ventilation should be sufficient under normal use.
Personal protective equipment: Not normally required. For use other than in normal operating procedures (such as in the event of large spill), the following should be applied:
- Eye Protection: None under normal use.
- Hand Protection: None under normal use. In case of prolonged contact wear protective gloves.
- Skin and body protection: None under normal use.
- Respiratory protection: None under normal use.
Environmental Exposure Controls: Not normally required.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance: Film
Physical state: Film
Color: Black
Odor: Odorless
Odor Threshold: Not applicable
pH: Not applicable
Melting point/freezing point: > 250 °C Film
Initial boiling point and boiling range: No information available
Flash Point: Not applicable
Evaporation rate: Not applicable
Flammability (solid, gas): Not applicable
Upper/lower flammability or explosive limits: No information available
Vapor pressure: Not applicable
Vapor density: Not applicable
Relative density: 1.4 (H2O=1) Film
Solubility(ies): Insoluble (water)
Partition coefficient: n-octanol/water: No information available
Auto-ignition temperature: No information available
Decomposition temperature: No information available
Viscosity: Not applicable
Explosive properties: Not explosive
Oxidizing properties: No information available
9.2 Other information
No information available.
SECTION 10: Stability and reactivity
10.1 Reactivity
No information available.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
No information available.
10.4 Conditions to avoid
Keep at a temperature not exceeding 200 °C. Avoid friction, sparks, or other means of ignition.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
Contains: Carbon monoxide (CO). Carbon dioxide (CO2).
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
- Inhalation: No information available.
- Eye contact: No information available.
- Skin contact: No information available.
- Ingestion: No information available.
Skin corrosion/irritation: No information available.
Serious eye damage/irritation: No information available.
Respiratory or skin sensitisation: No information available.
Mutagenicity: No information available.
Carcinogenicity
Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This classification is given to chemicals, for which there is inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats did not show any association between carbon black and lung tumors.
Other ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA.
SECTION 12: Ecological information
12.1 Toxicity
| Chemical Name | Toxicity to algae | Toxicity to fish | Toxicity to daphnia and other aquatic invertebrates |
|---|---|---|---|
| Carbon Black (1333-86-4) | EC50: >5600 mg/L 24 h (Daphnia magna) |
12.2 Persistence and degradability
No information available.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB assessment
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
12.6 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of in accordance with Federal, State, and local regulations.
SECTION 14: Transport information
Not classified as hazardous for transport
- 14.1 UN Number: None
- 14.2 UN proper shipping name: None
- 14.3 Transport hazard class(es): None
- 14.4 Packing Group: None
- 14.5 Environmental hazards: None
- 14.6 Special precautions for user: None
- 14.7 Transport in bulk according to Annex II of Marpol 73/78 and the IBC Code: Not applicable
Not regulated under DOT, IMDG, ADR, RID, IATA.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU: Not classified as dangerous for supply/use. (1999/45/EC)
USA: All chemical substances contained in this product are and had been listed on the TSCA Chemical Substances Inventory, and none is subject to any of the following TSCA requirements: section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent orders; section 8(a) preliminary assessment information rules; and section 8(d) health and safety data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article)
15.2 Chemical Safety Assessment
No.
SECTION 16: Other information
Full text of R-phrases referred to under sections 2 and 3: None
Full text of H-Statements referred to under sections 2 and 3: None
Additional information: The information relates only to this product. It may not be valid, if used in combination with any other materials or in any other process, and it is based on our best knowledge as of the date of preparation (revision).
Revision Note: SECTION 3
References:
- U.S. 29CFR Part 1910
- ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
- EU Directive 91/322/EEC and 2000/39/EC
- NTP 11th Report on Carcinogens
Abbreviations:
- ACGIH: American Conference of Governmental Industrial Hygienists
- ADR: European Agreement concerning the International carriage of Dangerous goods by Road (EU)
- DOT: Department Of Transportation (US)
- IARC: International Agency for Research on Cancer
- IATA: International Air Transport Association
- IMDG: International Maritime Dangerous Goods
- NOHSC: National Occupational Health and Safety Commission (Australia)
- NTP: National Toxicology Program (US)
- OSHA: Occupational Safety and Health Administration (US)
- PEL: Permissible Exposure Limit
- RID: Regulations concerning the International carriage of goods by Rail (EU)
- STEL: Short Term Exposure Limit
- TLV: Threshold Limit Value (ACGIH)
- TSCA: Toxic Substances Control Act (US)
- TWA: Time Weighted Average
- WHMIS: Workplace Hazardous Material Information System (Canada)
