Brother Ink Safety Data Sheet

Product Name: BTD60BK, BTD61BK, BTD100BK, BTD180BK Ink

Revision Date: 07-Jul-2025

Issuing Date: 06-Mar-2017

Revision Number: 12

Safety Data Sheet Number: BHK168

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Safety data sheet number: BHK168

Product Name: BTD60BK, BTD61BK, BTD100BK, BTD180BK Ink

Other means of identification: No information available

Pure substance/mixture: Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use: Water based ink for inkjet printing machine

Uses advised against: No information available

1.3. Details of the supplier of the safety data sheet

Manufacturer: Brother Industries, Ltd.

15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan

Telephone (for information): +81-52-824-2735

Supplier (Europe): Brother International (Nederland) B.V.

Zanderij 25, 1185 ZM Amstelveen, The Netherlands

Supplier (Europe): Brother International Europe Ltd.

1 Tame Street, Audenshaw, Manchester M34 5JE, UK

Telephone (for information): +44-161-330-6531

For further information, please contact

E-mail address: sds.info@brother.co.jp

1.4. Emergency telephone number

Emergency Telephone: CHEMTREC +1-703-527-3887 (International)

For France only:

Antipoison Center telephone number: ORFILA +33-1-45-425-959

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]

2.2. Label elements

Regulation (EC) No 1272/2008: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]

Hazard statements: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]

EUH208 - Contains Aqueous Dye; 1,2-benzisothiazol-3(2H)-one May produce an allergic reaction.

Unknown acute toxicity

  • 7% of the mixture consists of ingredient(s) of unknown acute oral toxicity.
  • 7% of the mixture consists of ingredient(s) of unknown acute dermal toxicity.
  • 33% of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas).
  • 33% of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor).
  • 10% of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist).

Unknown aquatic toxicity: Contains 0 % of components with unknown hazards to the aquatic environment.

2.3. Other hazards

  • This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
  • This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

Endocrine Disruptor Information: This product does not contain any known or suspected endocrine disruptors.

SECTION 3: Composition/information on ingredients

3.1 Substances

Not applicable

3.2 Mixtures

3.2 Mixtures
Chemical NameCAS No.EC No (EU Index No)Weight-%Classification according to Regulation (EC) No. 1272/2008 [CLP]Specific concentration limit (SCL)M-FactorM-Factor (long-term)REACH registration number
Water7732-18-5231-791-260-70No data available---Not applicable
Glycerol56-81-5200-289-515-25No data available---Not applicable
Aqueous Dye **916-899-65-9Skin Sens. 1B (H317)---Not applicable
Triethylene glycol, monobutyl ether143-22-6205-592-6 (603-183-00-)1-5Eye Dam. 1 (H318)Eye Dam. 1 :: C>=30%--01-2119475107-38-XXXX
2,2'-(ethylenedioxy)diethanol112-27-6203-953-21-5Eye Irrit. 2 :: 20%<=C<30% (H319)---Not applicable
1,2,3-benzotriazole95-14-7202-394-1 (613-350-00-X)<0.3Aquatic Chronic 2 (H411)---Not applicable
1,2-benzisothiazol-3(2H)-one2634-33-5220-120-9 (613-088-00-6)<0.05Acute Tox. 4 (H302) Skin Irrit. 2 (H315) Eye Dam. 1 (H318) Skin Sens. 1A (H317) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410)C=0.036%11Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice: If symptoms persist, call a physician.

Inhalation: Remove to fresh air. Get immediate medical advice/attention.

Eye contact: In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. If eye irritation persists: Get medical advice/attention.

Skin contact: Wash with soap and water. If skin irritation persists, call a physician.

Ingestion: Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to drink.

Self-protection of the first aider: No information available.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms:

Inhalation (Vapor / Mist): No specific effects and/or symptoms have been reported or known.

Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians: Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable Extinguishing Media: Dry chemical, CO₂, water spray or regular foam.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the chemical: Thermal decomposition can lead to release of irritating and toxic gases and vapors. Carbon monoxide, Carbon dioxide (CO₂), Nitrogen oxides (NOx), Oxides of sulfur.

5.3. Advice for firefighters

Special protective equipment for fire-fighters: Wear self-contained breathing apparatus for fire fighting if necessary.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency personnel: Avoid contact with skin, eyes or clothing.

For emergency responders: Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions: Prevent entry into waterways, sewers, basements or confined areas.

6.3. Methods and material for containment and cleaning up

Methods for containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.

Methods for cleaning up: Wipe up with absorbent towel. Wash with water to remove remaining traces of ink.

Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections

Reference to other sections: See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling: Avoid contact with skin, eyes or clothing.

General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions: Keep out of the reach of children. Keep cool. Protect from sunlight.

7.3. Specific end use(s)

Specific use(s): Water based ink for inkjet printing machine.

Risk Management Methods (RMM): The information required is contained in this Safety Data Sheet.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure Limits:

Chemical nameEuropean UnionAustriaBelgiumBulgariaCroatia
Glycerol-TWA: 10 mg/m³TWA: 10 mg/m³TWA: 15.0 mg/m³TWA: 10 mg/m³
2,2'-(ethylenedioxy)diethanol112-27-6----
Chemical nameCyprusCzech RepublicDenmarkEstoniaFinland
GlycerolTWA: 10 mg/m³TWA: 10 mg/m³ Ceiling: 15 mg/m³-TWA: 10 mg/m³TWA: 20 mg/m³
2,2'-(ethylenedioxy)diethanol-----
Chemical nameFranceGermany TRGSGermany DFGGreeceHungary
GlycerolTWA: 10 mg/m³TWA: 200 mg/m³TWA: 200 mg/m³ Peak: 400 mg/m³TWA: 10 mg/m³TWA: 1000 mg/m³
2,2'-(ethylenedioxy)diethanol112-27-6TWA: 1000 mg/m³ Peak: 2000 mg/m³---
Chemical nameIrelandItaly MDLPSItaly AIDIILatviaLithuania
1,2,3-benzotriazole95-14-7--TWA: 5 mg/m³-
1,2-benzisothiazol-3(2H)-one2634-33-5----
Chemical nameLuxembourgMaltaNetherlandsNorwayPoland
Glycerol----TWA: 10 mg/m³
56-81-5-----
Chemical namePortugalRomaniaSlovakiaSloveniaSpain
GlycerolTWA: 10 mg/m³-TWA: 10 mg/m³TWA: 200 mg/m³ STEL: 400 mg/m³TWA: 10 mg/m³
56-81-5-----
2,2'-(ethylenedioxy)diethanol112-27-6TWA: 114 ppm TWA: 700 mg/m³ STEL: 163 ppm STEL: 1000 mg/m³-TWA: 1000 mg/m³ STEL: 2000 mg/m³--
Chemical nameSwedenSwitzerlandUnited Kingdom
GlycerolTWA: 50 mg/m³ STEL: 100 mg/m³TWA: 10 mg/m³ STEL: 30 mg/m³TWA: 10 mg/m³
56-81-5---
2,2'-(ethylenedioxy)diethanol112-27-6TWA: 1000 mg/m³ STEL: 2000 mg/m³--

Biological occupational exposure limits: This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies.

8.2. Exposure controls

Appropriate engineering controls: Good general ventilation should be sufficient under normal use.

Personal protective equipment: Not normally required. For use other than in normal operating procedures (such as in the event of large spill), the following should be applied:

Eye/face protection: Safety goggles

Hand protection: Protective gloves

Skin and body protection: Apron, Rubber boots

Respiratory protection: In case of large spillages: Wear suitable respiratory protective equipment.

Thermal hazards: No information available.

General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls: Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: Liquid

Color: black

Odor: Slight

Odor threshold: No information available

PropertyValuesRemarks • Method
Melting point / freezing point< -5 °CNone known
Initial boiling point and boiling range> 100 °CNone known
FlammabilityNo data availableNone known
Flammability Limit in AirNo data availableNone known
Upper flammability or explosive limitsNo data available
Lower flammability or explosive limitsNo data available
Flash point> 93.3 °CTag Closed Cup, Cleveland Open Cup
Autoignition temperature> 400 °CNone known
Decomposition temperatureNo data availableNo information available
pH (as aqueous solution)7 - 9No information available
Kinematic viscosityNo data availableNone known
Dynamic viscosity1 - 5 mPa·s
Water solubilitySoluble in water
Solubility(ies)No data availableNone known
Partition coefficientNo data availableNone known
Vapor pressureNo data availableNone known
Relative density1.0 - 1.1(H₂O=1)
Bulk densityNo data available
Liquid DensityNo data available
Relative vapor densityNo data availableNone known
Particle characteristicsNo data available
Particle SizeNo data available
Particle Size DistributionNo data available

9.2. Other information

9.2.1. Information with regard to physical hazard classes

ExplosivesExplosive properties: No information available
Oxidizing propertiesNo information available

9.2.2. Other safety characteristics

No information available

None known

SECTION 10: Stability and reactivity

10.1. Reactivity

None.

10.2. Chemical stability

Stable under normal conditions.

Explosion data

Sensitivity to mechanical impact: None.

Sensitivity to static discharge: None.

10.3. Possibility of hazardous reactions

None under normal processing.

10.4. Conditions to avoid

Keep away from heat. Keep away from water or moist air.

10.5. Incompatible materials

Acids, Bases, Oxidizing agent, Reducing agent.

10.6. Hazardous decomposition products

Carbon monoxide, Carbon dioxide (CO₂), Nitrogen oxides (NOx), Oxides of sulfur.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Information on likely routes of exposure

Product Information:

Inhalation: No information available

Eye contact: No information available

Skin contact: No information available.

Ingestion: Acute LD₅₀ > 2000 mg/kg (OECD 423 method)

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms: No information available.

Acute toxicity

Numerical measures of toxicity
Chemical nameOral LD50Dermal LD50Inhalation LC50
Water> 90 mL/kg (Rat)--
Glycerol= 27200 mg/kg (Rat)> 10 g/kg (Rabbit)> 5.85 mg/L (Rat) 4 h
2,2'-(ethylenedioxy)diethanol= 17 g/kg (Rat)> 20 mL/kg (Rabbit)> 5.2 mg/L (Rat) 4 h
Triethylene glycol, monobutyl ether= 5300 mg/kg (Rat)= 3540 mg/kg (Rabbit)
1,2,3-benzotriazole= 560 mg/kg (Rat)> 10000 mg/kg (Rabbit)= 1910 mg/m³ (Rat) 3 h
1,2-benzisothiazol-3(2H)-one= 450 mg/kg (Rat)> 2000 mg/kg (Rat)0.21 mg/L

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation: Non-irritant (OECD 404 method)

Serious eye damage/eye irritation: Non-irritant (OECD 405 method)

Respiratory or skin sensitization: Respiratory sensitization: No information available. It is not a skin sensitizer (OECD 406 method).

Germ cell mutagenicity: AMES test: Negative (OECD 471 method).

Carcinogenicity: Ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA.

Reproductive toxicity: No information available.

STOT - single exposure: No information available.

STOT - repeated exposure: No information available.

Aspiration hazard: No information available.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

No information available.

11.2.2. Other information

No information available.

SECTION 12: Ecological information

12.1. Toxicity

Ecotoxicity: The environmental impact of this product has not been fully investigated.

Chemical nameAlgae/aquatic plantsFishToxicity to microorganismsCrustacea
GlycerolLC50: 51 - 57mL/L (96h, Oncorhynchus mykiss)-
Triethylene glycol, monobutyl etherEC50: >500mg/L (72h, Desmodesmus subspicatus)LC50: =2400mg/L (96h, Pimephales promelas)EC50: >500mg/L (48h, Daphnia magna)
2,2'-(ethylenedioxy)diethanol-LC50: 56200 - 63700mg/L (96h, Pimephales promelas) LC50: =10000mg/L (96h, Lepomis macrochirus) LC50: =61000mg/L (96h, Lepomis macrochirus)-EC50: =42426mg/L (48h, Daphnia magna)
1,2,3-benzotriazoleEC50: =15.4mg/L (96h, freshwater algae)LC50: =39mg/L (96h, Oncorhynchus mykiss)EC50: =141.6mg/L (48h, water flea)

12.2. Persistence and degradability

Persistence and degradability: No information available.

12.3. Bioaccumulative potential

Bioaccumulation: No information available.

Component InformationPartition coefficient
Glycerol-1.76
Triethylene glycol, monobutyl ether0.51
2,2'-(ethylenedioxy)diethanol-1.98
1,2-benzisothiazol-3(2H)-one0.99

12.4. Mobility in soil

Mobility in soil: No information available.

Mobility: No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment: This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

Chemical namePBT and vPvB assessment
GlycerolThe substance is not PBT / vPvB
Triethylene glycol, monobutyl etherThe substance is not PBT / vPvB
2,2'-(ethylenedioxy)diethanolThe substance is not PBT / vPvB
1,2,3-benzotriazoleThe substance is not PBT / vPvB
1,2-benzisothiazol-3(2H)-oneThe substance is not PBT / vPvB

12.6. Endocrine disrupting properties

No information available.

12.7. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Dispose in accordance with federal, state and local regulations.

SECTION 14: Transport information

IATA

  • 14.1 UN number or ID number: Not regulated
  • 14.2 UN proper shipping name: Not regulated
  • 14.3 Transport hazard class(es): Not regulated
  • 14.4 Packing group: Not regulated
  • 14.5 Environmental hazards: Not applicable
  • 14.6 Special precautions for user: None

IMDG

  • 14.1 UN number or ID number: Not regulated
  • 14.2 UN proper shipping name: Not regulated
  • 14.3 Transport hazard class(es): Not regulated
  • 14.4 Packing group: Not regulated
  • 14.5 Environmental hazards: Not applicable
  • 14.6 Special precautions for user: None
  • 14.7 Maritime transport in bulk according to IMO instruments: Not applicable

RID

  • 14.1 UN number or ID number: Not regulated
  • 14.2 UN proper shipping name: Not regulated
  • 14.3 Transport hazard class(es): Not regulated
  • 14.4 Packing group: Not regulated
  • 14.5 Environmental hazards: Not applicable
  • 14.6 Special precautions for user: None

ADR

  • 14.1 UN number or ID number: Not regulated
  • 14.2 UN proper shipping name: Not regulated
  • 14.3 Transport hazard class(es): Not regulated
  • 14.4 Packing group: Not regulated
  • 14.5 Environmental hazards: Not applicable
  • 14.6 Special precautions for user: None

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National Regulations

France

Occupational Illnesses (R-463-3, France)

Chemical nameFrench RG number
Triethylene glycol, monobutyl ether - 143-22-6RG 84
2,2'-(ethylenedioxy)diethanol - 112-27-6RG 84
1,2-benzisothiazol-3(2H)-one - 2634-33-5RG 65

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work.

Authorizations and/or restrictions on use:

This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Chemical nameRestricted substance per REACH Annex XVIISubstance subject to authorization per REACH Annex XIV
Triethylene glycol, monobutyl ether - 143-22-6Use restricted. See entry 75.-
1,2-benzisothiazol-3(2H)-one - 2634-33-5Use restricted. See entry 75.-

Persistent Organic Pollutants

Not applicable

Ozone-depleting substances (ODS) regulation (EC) 1005/2009

Not applicable

Biocidal Products Regulation (EU) No 528/2012 (BPR)

Chemical name: 1,2-benzisothiazol-3(2H)-one - 2634-33-5

Product-type 2: Disinfectants and algaecides not intended for direct application to humans or animals Product-type 6: Preservatives for products during storage Product-type 9: Fiber, leather, rubber and polymerized materials preservatives Product-type 11: Preservatives for liquid-cooling and processing systems Product-type 12: Slimicides Product-type 13: Working or cutting fluid preservatives

International Inventories

  • TSCA: Complies
  • DSL/NDSL: Complies
  • EINECS/ELINCS: Complies
  • ENCS: Complies
  • IECSC: Complies
  • KECL: Complies
  • PICCS: Complies
  • AICS: Complies
  • NZIOC: Complies

15.2. Chemical safety assessment

Chemical Safety Report: No information available.

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3

  • H302 - Harmful if swallowed
  • H315 - Causes skin irritation
  • H317 - May cause an allergic skin reaction
  • H318 - Causes serious eye damage
  • H330 - Fatal if inhaled
  • H400 - Very toxic to aquatic life
  • H410 - Very toxic to aquatic life with long lasting effects

Legend

  • SVHC: Substances of Very High Concern for Authorization:
  • PBT: Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
  • vPvB: Very Persistent and very Bioaccumulative (vPvB) Chemicals

Legend SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

  • TWA: TWA (time-weighted average)
  • Ceiling: Ceiling Limit Value
  • +: Sensitizers
  • STEL: STEL (Short Term Exposure Limit)
  • *: Skin designation
  • **: Trade secret

Classification procedure

Classification according to Regulation (EC) No. 1272/2008 [CLP]Method Used
Acute oral toxicityOn basis of test data
Acute dermal toxicityCalculation method
Acute inhalation toxicity - gasCalculation method
Acute inhalation toxicity - vaporCalculation method
Acute inhalation toxicity - dust/mistCalculation method
Skin corrosion/irritationOn basis of test data
Serious eye damage/eye irritationOn basis of test data
Respiratory sensitizationCalculation method
Skin sensitizationOn basis of test data
MutagenicityOn basis of test data
CarcinogenicityCalculation method
Reproductive toxicityCalculation method
STOT - single exposureCalculation method
STOT - repeated exposureCalculation method
Chronic aquatic toxicityCalculation method
Acute aquatic toxicityCalculation method
Aspiration hazardCalculation method
OzoneCalculation method

Key literature references and sources for data used to compile the SDS

  • Agency for Toxic Substances and Disease Registry (ATSDR)
  • U.S. Environmental Protection Agency ChemView Database
  • European Food Safety Authority (EFSA)
  • European Chemicals Agency (ECHA) Committee for Risk Assessment (ECHA_RAC)
  • European Chemicals Agency (ECHA) (ECHA_API)
  • EPA (Environmental Protection Agency)
  • Acute Exposure Guideline Level(s) (AEGL(s))
  • U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
  • U.S. Environmental Protection Agency High Production Volume Chemicals
  • Food Research Journal
  • Hazardous Substance Database
  • International Uniform Chemical Information Database (IUCLID)
  • National Institute of Technology and Evaluation (NITE)
  • Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
  • NIOSH (National Institute for Occupational Safety and Health)
  • National Library of Medicine's ChemID Plus (NLM CIP)
  • National Library of Medicine's PubMed database (NLM PUBMED)
  • National Toxicology Program (NTP)
  • New Zealand's Chemical Classification and Information Database (CCID)
  • Organization for Economic Co-operation and Development Environment, Health, and Safety Publications
  • Organization for Economic Co-operation and Development High Production Volume Chemicals Program
  • Organization for Economic Co-operation and Development Screening Information Data Set
  • World Health Organization

Issuing Date: 06-Mar-2017

Revision date: 07-Jul-2025

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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