Cleanfix Tint-Ex Stain Remover - Safety Data Sheet

Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

1.1 Product Identifier:

• Trade Name: Fleckenentferner Tint-Ex
• UFI: T3J2-A0FW-6004-2R05

1.2 Relevant identified uses of the substance or mixture and uses advised against:

• No further relevant information available.
• Use of the substance/mixture: Cleaning agent

1.3 Details of the supplier of the safety data sheet:

• Manufacturer/Supplier: Cleanfix Reinigungssysteme AG
• Address: Stettenstrasse, 9247 Henau
• Tel: +41 (0)71 955 47 47
• Fax: +41 (0)71 955 47 60

1.4 Emergency telephone number:

• Swiss Toxicological Information Centre, Zurich: +41 (0)44 251 51 51 or 145 (from Switzerland)

Section 2: Hazards Identification

2.1 Classification of the substance or mixture:

• Classification according to Regulation (EC) No 1272/2008
• GHS05 (Corrosion)
• Eye Dam. 1: H318 Causes serious eye damage.
• GHS07
• Acute Tox. 4: H302 Harmful if swallowed.
• Skin Sens. 1: H317 May cause an allergic skin reaction.

2.2 Label elements:

• Product is classified and labelled according to CLP Regulation.
• Hazard pictograms: GHS05, GHS07
• Signal word: Danger
• Hazard-determining components for labelling: Benzyl alcohol, Alcohol C13-iso, ethoxylated 9.5 EO
• Hazard statements:
• H302 Harmful if swallowed.
• H318 Causes serious eye damage.
• H317 May cause an allergic skin reaction.

2.3 Other hazards:

• PBT assessment: Not applicable.
• vPvB assessment: Not applicable.

Section 3: Composition/Information on Ingredients

3.2 Mixtures:

Description: Mixture of the substances listed below with non-hazardous admixtures.

Hazardous ingredients:

Specific concentration limits:

• Eye Dam. 1; H318: C ≥ 10 %
• Eye Irrit. 2; H319: 5 % ≤ C < 10 %

Section 4: First Aid Measures

4.1 Description of first aid measures:

• General advice: Symptoms of poisoning may occur after several hours; medical supervision for at least 48 hours after the accident.
• After inhalation: Fresh air supply, consult a doctor in case of complaints.
• After skin contact: The product is generally not irritating to the skin.
• After eye contact: Rinse eyes cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Consult a doctor immediately.
• After ingestion: Seek immediate medical attention.

4.2 Most important symptoms and effects, both acute and delayed:

• No further relevant information available.

4.3 Indication of any immediate medical attention and special treatment needed:

• No further relevant information available.

Section 5: Firefighting Measures

5.1 Extinguishing media:

• Suitable extinguishing media: Adapt fire-fighting measures to the environment.

5.2 Special hazards arising from the substance or mixture:

• No further relevant information available.

5.3 Advice for firefighters:

• Special protective equipment: No special measures required.

Section 6: Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures:

• Not required.

6.2 Environmental precautions:

• Dilute with plenty of water.
• Do not allow to enter drains/surface water/groundwater.

6.3 Methods and material for containment and cleaning up:

• Absorb with liquid-binding material (sand, diatomaceous earth, acid binders, universal binders, sawdust).
• Dispose of contaminated material as waste according to Section 13.

6.4 Reference to other sections:

• For information on safe handling see Section 7.
• For information on personal protective equipment see Section 8.
• For information on disposal see Section 13.

Section 7: Handling and Storage

7.1 Precautions for safe handling:

• No special measures required for proper use.

7.2 Conditions for safe storage, including any incompatibilities:

• Storage:
• Requirements for storage rooms and containers: No special requirements.
• Advice on common storage: Not required.
• Further information on storage conditions: None.
• Storage class: 12

Section 8: Exposure Controls/Personal Protection

8.1 Control parameters:

• Components with workplace-related exposure limits:
• 112-34-5 2-(2-Butoxyethoxy)ethanol: MAK Short-term value: 101 mg/m³, 15 ml/m³; Long-term value: 67 mg/m³, 10 ml/m³
• 100-51-6 Benzyl alcohol: MAK Long-term value: 22 mg/m³, 5 ml/m³

8.2 Exposure controls:

• Suitable technical control measures: No further information, see Section 7.
• Personal protective equipment:
• General protective and hygiene measures: Keep away from foodstuffs, beverages and feed. Remove contaminated clothing immediately. Wash hands before breaks and at the end of work.
• Eye/face protection: Avoid contact with eyes. Safety glasses are recommended when transferring.
• Hand protection:
• Material: Nitrile rubber
• Recommended material thickness: ≥ 0.1 mm
• Breakthrough time of the glove material: ≥ 8 h
• Respiratory protection: Not required.

Section 9: Physical and Chemical Properties

9.1 Information on basic physical and chemical properties:

• General Information:
• Colour: Colourless
• Odour: Characteristic
• Odour threshold: Not determined.
• Melting point/freezing point: Not determined.
• Boiling point or initial boiling point and boiling range: 100 °C
• Flammability: Not applicable.
• Lower and upper explosion limits: Lower: 0.9 Vol %; Upper: 13 Vol %
• Flash point: 225 °C
• Ignition temperature: Not determined.
• Decomposition temperature: Not determined.
• pH-value at 20 °C: 7
• Viscosity: Not determined.
• Solubility:
• Water: Miscible
• Partition coefficient n-octanol/water (log value): Not determined.
• Vapour pressure at 20 °C: 23 hPa
• Density and/or relative density:
• Density at 20 °C: 1.012 g/cm³
• Relative density: Not determined.
• Vapour density: Not determined.

9.2 Other information:

• Appearance:
• Form: Liquid
• Ignition temperature: The product is not self-igniting.
• Explosive properties: The product is not explosive.
• Organic solvents: 35.0%
• Water: 48.7%
• VOCV (CH): 35.00%
• Evaporation rate: Not determined.

Section 10: Stability and Reactivity

10.1 Reactivity:

• No further relevant information available.

10.2 Chemical stability:

• No decomposition under normal use.

10.3 Possibility of hazardous reactions:

• No hazardous reactions known.

10.4 Conditions to avoid:

• No further relevant information available.

10.5 Incompatible materials:

• No further relevant information available.

10.6 Hazardous decomposition products:

• No hazardous decomposition products known.

Section 11: Toxicological Information

11.1 Information on toxicological effects:

• Acute toxicity: Harmful if swallowed.
• Skin corrosion/irritation: Classification criteria are not met based on available data.
• Serious eye damage/eye irritation: Causes serious eye damage.
• Respiratory or skin sensitisation: May cause an allergic skin reaction.
• Germ cell mutagenicity: Classification criteria are not met based on available data.
• Carcinogenicity: Classification criteria are not met based on available data.
• Reproductive toxicity: Classification criteria are not met based on available data.
• STOT-single exposure: Classification criteria are not met based on available data.
• STOT-repeated exposure: Classification criteria are not met based on available data.
• Aspiration hazard: Classification criteria are not met based on available data.

11.2 Other hazards:

• Endocrine disrupting properties: None of the ingredients are contained.

Section 12: Ecological Information

12.1 Toxicity:

• Aquatic toxicity: No further relevant information available.

12.2 Persistence and degradability:

• No further relevant information available.

12.3 Bioaccumulative potential:

• No further relevant information available.

12.4 Mobility in soil:

• No further relevant information available.

12.5 Results of PBT and vPvB assessment:

• PBT: Not applicable.
• vPvB: Not applicable.

12.6 Endocrine disrupting properties:

• The product does not contain substances with endocrine-disrupting properties.

12.7 Other adverse effects:

• General notes: Do not allow undiluted or in large quantities to reach groundwater, water bodies or drains.
• Water hazard class 1 (self-classification): slightly hazardous to water.
• The surfactant contained in this mixture meets the conditions for biodegradability as laid down in Regulation (EC) No 648/2004 on detergents. Documentation confirming this is held for the competent authorities of the Member States and will be supplied to them either directly or upon request of a detergent manufacturer.

Section 13: Disposal Considerations

13.1 Waste treatment methods:

• Recommendation: Can be incinerated together with household waste, observing the necessary technical regulations, in consultation with the disposer and the competent authority.
• Do not dispose of with household waste. Do not allow to enter drains.

European Waste Catalogue:

• 20 01 29* Detergents containing hazardous substances

13.2 Packaging:

• Recommendation: Contaminated packaging should be emptied optimally; after appropriate cleaning, it can be recycled.

Section 14: Transport Information

14.1 UN number or ID number:

• ADR, ADN, IMDG, IATA: Not applicable.

14.2 UN proper shipping name:

• ADR, ADN, IMDG, IATA: Not applicable.

14.3 Transport hazard class(es):

• ADR, ADN, IMDG, IATA: Not applicable.

14.4 Packing group:

• ADR, IMDG, IATA: Not applicable.

14.5 Environmental hazards:

• Marine pollutant: No

14.6 Special precautions for user:

• Not applicable.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code:

• Not applicable.
• UN "Model Regulation": Not applicable.

Section 15: Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

• Swiss regulations are not applicable.
• Maternity protection ordinance, SR 822.111.52: Pregnant women and nursing mothers must not come into contact with this product (this substance/this mixture) during their work. If a risk assessment shows that there is no concrete health burden for the mother and child, or that this can be excluded by appropriate protective measures, they may work with this product (this substance/this mixture) (Art. 63 ArGV 1; SR 822.111).
• Directive 2012/18/EU: No ingredients are listed.
• REGULATION (EC) No 1907/2006 ANNEX XVII: Restrictions: 3, 55
• Directive 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment - Annex II: No ingredients are contained.
• REGULATION (EU) 2019/1148: Annex I - RESTRICTED DRUG PRECURSORS (Upper limit concentration for authorisation under Article 5(3)): No ingredients are contained.
• Annex II - REPORTABLE DRUG PRECURSORS: No ingredients are contained.
• Regulation (EC) No 273/2004 on drug precursors: No ingredients are contained.
• Regulation (EC) No 111/2005 on the monitoring of trade in drug precursors between the Community and third countries: No ingredients are contained.

National regulations:

• Classification of water-polluting liquids: Class B (self-classification)
• Regulation (EC) No 648/2004 on detergents / Ingredient labelling:
• Non-ionic surfactants: ≥5 - <15%
• Anionic surfactants: <5%
• VOCV (CH): 35.00 %

15.2 Chemical safety assessment:

• A chemical safety assessment has not been carried out.

Section 16: Other Information

The information provided is based on the current state of our knowledge and does not constitute an assurance of product properties, nor does it establish a contractual legal relationship.

Relevant sentences:

• H302 Harmful if swallowed.
• H312 Harmful in contact with skin.
• H315 Causes skin irritation.
• H317 May cause an allergic skin reaction.
• H318 Causes serious eye damage.
• H319 Causes serious eye irritation.
• H412 Harmful to aquatic life with long lasting effects.

Abbreviations and acronyms:

• ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road)
• IMDG: International Maritime Code for Dangerous Goods
• IATA: International Air Transport Association
• GHS: Globally Harmonised System of Classification and Labelling of Chemicals
• EINECS: European Inventory of Existing Commercial Chemical Substances
• ELINCS: European List of Notified Chemical Substances
• CAS: Chemical Abstracts Service (division of the American Chemical Society)
• VOCV: Ordinance on the control of volatile organic compounds, Switzerland
• PBT: Persistent, Bioaccumulative and Toxic
• vPvB: very Persistent and very Bioaccumulative
• ATE: Acute toxicity estimate values
• Acute Tox. 4: Acute toxicity - Category 4
• Skin Irrit. 2: Skin irritation - Category 2
• Eye Dam. 1: Serious eye damage/eye irritation - Category 1
• Eye Irrit. 2: Serious eye damage/eye irritation - Category 2
• Skin Sens. 1: Skin sensitisation - Category 1
• Skin Sens. 1B: Skin sensitisation - Category 1B
• Aquatic Chronic 3: Hazardous to the aquatic environment - long-term hazard - Category 3