Product Information
| Field | Detail |
|---|---|
| Product Name | BCI-21C |
| Description | Ink Tank |
| Used with Machine(s) | MPC20, MPC50, MPC70, MPC80, MultiPASS C75, FAXB210c, FAXB230, BJC4000, BJC4100, BJC4200, BJC4300, BJC4550, BJC4650, BJC5500, BJC2100, S100 |
| Manufacturer | Canon Inc., 30-2, Shimomaruko 3-Chome, Ohta-Ku, Tokyo 146, Japan. Phone: 03-3758-2111 |
| Distributor | Canon UK Limited, Woodhatch, Reigate, Surrey. Phone: 01737 220000 |
| Date Prepared | 16/02/96 |
| Date Revised | 18/12/02 |
| UK MSDS Ref | MSDS3017 |
SECTION 1: Identification of the Substance/Preparation and of the Company/Undertaking
Product Name: Canon Ink Cartridge BCI-21 Color
Product Code: 0955A/F47-0741
Company Name: Canon Inc.
Address: 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan
Use of the Product: Ink for Ink Jet Printer
SECTION 2: Composition/Information on Ingredients
Ingredient(s)
| Chemical Name / Generic name | CAS # / EC # | Weight % | EU Symbol/ R-Phrase | USA OSHA PEL | ACGIH TLV | EU ILV | DFG MAK |
|---|---|---|---|---|---|---|---|
| Glycerin | 56-81-5 / 200-289-5 | 5-10 | None / None | (as mist) Total dust TWA = 15 mg/m³ Respirable fraction TWA = 5 mg/m³ | (as mist) TWA = 10 mg/m³ | Not established | Not established |
| Thiodiglycol | 111-48-8 / 203-874-3 | 5-10 | Xi / R36 | Not established | Not established | Not established | Not established |
| Copper compound (Contained only in cyan ink) | Confidential | 2-6 | None / None | Not established | Not established | Not established | Copper and its compounds Inhalable fraction 1.0 mg/m³ |
| Isopropyl alcohol | 67-63-0 / 200-661-7 | 1-3 | F / R11 Xi / R36 R67 | TWA = 400 ppm, 980 mg/m³ | TWA = 400 ppm, 983 mg/m³ STEL = 500 ppm, 1230 mg/m³ | Not established | 200 ppm, 500 mg/m³ |
| C.I. Direct Yellow 173 (Contained only in yellow ink) | Not registered / 414-410-6 | 1-3 | Xi / R41 | Not established | Not established | Not established | Not established |
| C.I. Direct Violet 107 (The substance name in accordance with 67/547/EEC is stated in SECTION 16 (Contained only in magenta ink)) | Not registered / 413-180-4 | 1-3 | Xi / R41 | Not established | Not established | Not established | Not established |
| Poly(oxy-1,2-ethanediyl), .alpha., .alpha.'-[1,4-dimethyl-1,4-bis(2-methylpropyl)-2-butyne-1,4-diyl]bis[.omega.-hydroxy- | 9014-85-1 / Not applicable | 1-3 | Xi / R41 | Not established | Not established | Not established | Not established |
| Ammonia derivative | Confidential | 5-10 | None / None | Not established | Not established | Not established | Not established |
| Water | 7732-18-5 / 231-79-12 | 60-80 | None / None | Not established | Not established | Not established | Not established |
SECTION 3: Hazards Identification
Carcinogen
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA regulations or Annex I to Directive 67/548/EEC.
EU Classification
Not classified as dangerous.
Emergency Overview
- A set of three colors ink cartridges (Cyan, Magenta and Yellow).
- All the ink is liquid mixture with slight odor.
Potential Health Effects and Symptoms
Inhalation
- No adverse effects are expected under intended use.
- Glycerin mist may cause physical irritation and difficulty breathing.
- Over exposure to isopropyl alcohol may cause headache, nausea, dizziness, vomiting, drowsiness, cough and sore throat.
Ingestion
- Ingestion of glycerin and/or isopropyl alcohol may cause headache, nausea, dizziness, vomiting, drowsiness, abdominal pain, dullness and sore throat.
Eye
- May cause minimal irritation based on the animal test data of this ink. (See SECTION 11)
Skin
- May be no irritation and no sensitization based on the animal test data of this ink. (See SECTION 11)
Chronic Effects
Not identified.
Medical Conditions Generally known to be Aggravated by Exposure
Not identified.
SECTION 4: First Aid Measures
First Aid Measures
Inhalation
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion
- Rinse mouth.
- Give one or two glasses of water.
- If irritation or discomfort occurs, obtain medical advice immediately.
Eye
- Immediately flush with water for 5 minutes or until the chemical is removed.
- If irritation persists, obtain medical advice immediately.
Skin
- Wash with water and soap or mild detergent.
- If irritation persists, obtain medical advice.
Note to Physicians
None.
SECTION 5: Fire Fighting Measures
Fire Fighting Measures
Extinguishing Media
CO₂, water, foam or dry chemicals.
Unsuitable Extinguishing Media
None.
Special Fire Fighting Procedures
None.
Unusual Fire and Explosion Hazards
None.
Fire and Explosive Properties (See also Section 9)
Hazardous Combustion Products
CO, CO₂, NOx and SOx.
Other Properties
None.
SECTION 6: Accidental Release Measures
Personal Precautions
Avoid contact with skin, eyes and clothing.
Environmental Precautions
Do not release to sewer, surface water or ground water.
Method for Cleaning Up
Wipe off with wet cloth or paper.
SECTION 7: Handling and Storage
Handling
- Use with adequate ventilation.
- Avoid contact with skin, eyes and clothing.
- When contact, wash out immediately.
Storage
- Keep in a cool and dry place.
- Keep away from heat and flame.
- Protect from sunlight.
- Keep out of the reach of children.
Specific Uses
Ink for Ink Jet Printer. For more information, please refer to the instruction of this product.
SECTION 8: Exposure Controls / Personal Protection
Exposure Guidelines
Not established for this ink. (Also refer to SECTION 2)
Engineering Controls
Use adequate ventilation.
Personal Protection Equipment(s)
Respiratory Protection
☑ Not Required
Eye/Face Protection
☑ Not Required
Skin Protection
☑ Not Required
SECTION 9: Physical and Chemical Properties
| Property | Value |
|---|---|
| Appearance | Cyan, magenta and yellow liquid |
| Odor | Slight odor |
| pH | 8.2 - 10.3 |
| Boiling Point/Range(°C) | Not available |
| Melting Point/Range(°C) | Not available |
| Decomposition Temperature(°C) | Not available |
| Flash Point(°C) | Estimate 55 - 57 (Tag.closed cup. Do not sustain combustion.) |
| Flammable (Explosive) Limits | Not available |
| Autoignition Temperature(°C) | Estimate 460 - 490 (ASTM-E659) |
| Flammability | Classified as "Combustible liquid" under OSHA-HCS. Not classified as "flammable" or "combustible" under FHSA. Not classified as "flammable" under 1999/45/EC. |
| Explosive Properties | None |
| Oxidizing Properties | None |
| Vapor Pressure | Not available |
| Vapor Density | Not available |
| Density / Specific Gravity | 1.04 - 1.10 |
| Water Solubility | Miscible |
| Fat Solubility | Not available |
| Partition Coefficient (n-Octanol/Water) | Not available |
| Percent Volatile (%) | 60 - 80 |
| Evaporation Rate | Not available |
| Viscosity (mPa s) | 1.9 - 2.6 |
SECTION 10: Stability and Reactivity
Stability
☑ Stable
☐ Unstable
Conditions to Avoid
None.
Materials to Avoid
Acids, bases, oxidizing materials and reducing agents.
Hazardous Decomposition Products
CO, CO₂, NOx, Ammonia and SOx.
Hazardous Polymerization
☐ May Occur
☑ Will Not Occur
Conditions to Avoid
None.
SECTION 11: Toxicological Information
Acute Toxicity
Inhalation
Not available.
Ingestion
Not available.
Eye
- Cyan: Minimal irritant, Maximum Group Mean Score = 5.3, Class 3 (rabbit). OECD Guidelines No.405 (1987), 92/69/EEC Method B5.
- Magenta: Minimal irritant, Maximum Group Mean Score = 3.3, Class 3 (rabbit). OECD Guidelines No.405 (1987), 92/69/EEC Method B5.
- Yellow: Minimal irritant, Maximum Group Mean Score = 4.0 (rabbit). EPA (FIFRA) Pesticide Assessment Guideline par.81-4, EPA (TSCA) Federal Regulation Subpart E Sec.798.4500.
Skin
- Cyan and Magenta: Non irritant, Primary Irritation Index = 0.0 (rabbit). OECD Guidelines No.404 (1992), 92/69/EEC Method B4.
- Yellow: Non irritant, Primary Irritation Index = 0.0 (rabbit). EPA (FIFRA) Pesticide Assessment Guideline par.81-5, EPA (TSCA) Federal Regulation Subpart E Sec.798.4470.
Sensitization
- Magenta: Non sensitizer, Sensitization rate = 0 % (0/10) (guinea pig). OECD Guidelines No.406 (1992), 96/54/EC Method B6.
- Cyan and Yellow: Non sensitizer, Sensitization rate = 0 % (0/10) (guinea pig). OECD Guidelines No.406 (1992), 92/69/EEC Method B6.
Mutagenicity
Ames test: Negative (test strains: S.typhimurium).
Reproductive Toxicity
Not available.
Carcinogenicity
Not available.
Others
Not available.
SECTION 12: Ecological Information
| Property | Value |
|---|---|
| Mobility | Not available |
| Persistence / Degradability | Not available |
| Bioaccumulation | Not available |
| Ecotoxicity | Not available |
| Other Adverse Effects | Not available |
SECTION 13: Disposal Consideration
Method of Disposal
Disposal may be subject to federal, state and local laws.
SECTION 14: Transport Information
| Property | Value |
|---|---|
| UN # | None |
| UN Shipping Name | None |
| UN Classification | None |
| UN Packing Group | None |
| Marine Pollutant | ☑ No |
| Special Precautions | None |
SECTION 15: Regulatory Information
EU Information
Information on the Label
Symbol & Indication: Not required
R-Phrase: Not required
S-Phrase: Not required
Dangerous Component(s): None
Special Precautions under 1999/45/EC Annex V
Not required
Specific Provisions in Relation to Protection of Man or the Environment
- 76/769/EEC: Not regulated
- (EC)2037/2000: Not regulated
- (EEC)2455/92: Not regulated
Others
None.
SECTION 16: Other Information
USA Information
Information on the Label under FHSA
Signal Word: Not required
Hazard warning: Not required
Safety Advice: Not required
Hazardous Component(s): None
SARA Title III §313
| Chemical Name | Weight % |
|---|---|
| "Copper Compounds" (Contained only in cyan ink) (as Cu) | 2 - 6 (<0.35) |
California Proposition 65
| Chemical Name | Weight % |
|---|---|
| None |
Canada Information
WHMIS Controlled Product: Not applicable (Manufactured article)
Australia Information
Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC.
SECTION 2 Ingredient(s) / Substance name(s)
"C. I. Direct Violet 107": "A mixture of: sodium 5-[8-[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-disulfonatonaphthalen-2-ylazo]-isophthalate; ammonium 5-[8-[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-disulfonatonaphthalen-2-ylazo]-isophthalate; 5-[8-[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-disulfonaphthalen-2-ylazo]-isophthalic acid"
R phrase list
- R11: Highly flammable.
- R22: Harmful if swallowed.
- R36: Irritating to eyes.
- R41: Risk of serious damage to eyes.
- R67: Vapours may cause drowsiness and dizziness.
Revised information from the previous version
Entirely revised.
Literature Reference
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EEC)2455/92
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
Abbreviations
- EU: European Union.
- OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
- ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
- EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
- DFG MAK: MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
- TWA: Time Weighted Average.
- IARC: International Agency for Research on Cancer.
- NTP: National Toxicology Program (USA).
- OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
- FHSA: Federal Hazardous Substances Act (USA).
- WHMIS: Workplace Hazardous Materials Information System.
- NOHSC: National Occupational Health and Safety Commission Act 1985.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
