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No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA regulations or Annex I to Directive 67/548/EEC.
EU Classification:
Not classified as dangerous.
Emergency Overview:
Ink cartridge containing black liquid ink with slight odor.
Potential Health Effects and Symptoms:
Inhalation:
No adverse effects are expected under intended use.
Glycerin mist may cause physical irritation and difficulty breathing.
Over exposure to ethylene glycol and/or isopropyl alcohol may cause headache, nausea, dizziness, vomiting, drowsiness, cough and sore throat.
Ingestion:
Ingestion of glycerin, ethylene glycol and/or isopropyl alcohol may cause headache, nausea, dizziness, vomiting, drowsiness, abdominal pain, dullness and sore throat.
Eye:
May cause minimal irritation based on the animal test data of this ink. (See SECTION 11)
Skin:
May be no irritation and no sensitization based on the animal test data of this ink. (See SECTION 11)
Chronic Effects:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified
SECTION 4: FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Immediately flush with water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Note to Physicians:
None
SECTION 5: FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO₂, water, foam or dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO, CO₂, and NOx
Other Properties:
None
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid contact with skin, eyes and clothing.
Environmental Precautions:
Do not release to sewer, surface water or ground water.
Method for Cleaning Up:
Wipe off with wet cloth or paper.
SECTION 7: HANDLING AND STORAGE
Handling:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
When contact, wash out immediately.
Storage:
Keep in a cool and dry place. Keep away from heat and flame.
Protect from sunlight.
Keep out of the reach of children.
Specific Uses:
Ink for Ink Jet Printer. For more information, please refer to the instruction of this product.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Not established for this ink. (Also refer to SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Respiratory Protection:
☐ Required ☑ Not Required
Eye/Face Protection:
☐ Required ☑ Not Required
Skin Protection:
☐ Required ☑ Not Required
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black liquid
Odor: Slight odor
pH: 9.5 - 10.5
Boiling Point/Range(°C): Not available
Melting Point/Range(°C): Not available
Decomposition Temperature(°C): Not available
Flash Point(°C): 49.0 (Tag.closed cup. Do not sustain combustion.)
Flammable (Explosive) Limits: Not available
Autoignition Temperature(°C): Not available
Flammability: Classified as "Combustible liquid" under OSHA-HCS. Not classified as "flammable" or "combustible" under FHSA. Not classified as "flammable" under 1999/45/EC.
Explosive Properties: None
Oxidizing Properties: None
Vapor Pressure: Not available
Vapor Density: Not available
Density / Specific Gravity: 1.04
Water Solubility: Miscible
Fat Solubility: Not available
Partition Coefficient (n-Octanol/Water): Not available
Percent Volatile (%): 60 - 80
Evaporation Rate: Not available
Viscosity (mPa s): 1.5 - 2.1
SECTION 10: STABILITY AND REACTIVITY
Stability: ☑ Stable ☐ Unstable
Conditions to Avoid: None
Materials to Avoid: Acids, bases, oxidizing materials and reducing agents
Hazardous Decomposition Products: CO, CO₂, NOx and Ammonia
Hazardous Polymerization: ☐ May Occur ☑ Will Not Occur
Conditions to Avoid: None
SECTION 11: TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Not available
Eye:
Minimal irritant, Maximum Group Mean Score = 2.7, Class 3 (rabbit) OECD Guidelines No.405 (1987) 92/69/EEC Method B5
Skin:
Non irritant, Primary Irritation Index = 0.0 (rabbit) OECD Guidelines No.404 (1992) 92/69/EEC Method B4
Disposal may be subject to federal, state and local laws.
SECTION 14: TRANSPORT INFORMATION
UN #: None
UN Shipping Name: None
UN Classification: None
UN Packing Group: None
Marine Pollutant: ☐ Yes Chemical name (wt%): ☑ No
Special Precautions: None
SECTION 15: REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase: Not required
S-Phrase: Not required
Dangerous Component(s): None
Special Precautions under 1999/45/EC Annex V: Not required
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated
(EC)2037/2000: Not regulated
(EEC)2455/92: Not regulated
Others: None
SECTION 16: OTHER INFORMATION
<R phrase list>
R11: Highly flammable.
R22: Harmful if swallowed.
R36: Irritating to eyes.
R67: Vapours may cause drowsiness and dizziness.
<Revised information from the previous version>
Entirely revised.
Literature Reference:
U.S. Department of Labor, 29CFR Part 1910
U.S. Environmental Protection Agency, 40CFR Part 372
U.S. Consumer Product Safety Commission, 16CFR Part 1500
ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of Chemicals to Humans
DFG, List of MAK and BAT Values
EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
EU Regulation (EC)2037/2000, (EEC)2455/92
Canada Workplace Hazardous Materials Information System
Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission Act 1985.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any nature whatsoever resulting from the use or reliance upon the Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
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