Hercules Sta Put
Manufacturer: HCC Holdings, Inc. an Oatey Affiliate
Version: 1.8.6.8
Issue Date: 07/21/2021
SECTION 1: Identification
Product Identifier: Hercules Sta Put
Chemical Name: Not Applicable
Synonyms: Not Available
Other means of identification: 25101, 25103, 25105, 25110, 25123
Recommended use: Plumbing Mastic
Manufacturer/Importer/Responsible Party:
- Company Name: HCC Holdings, Inc. an Oatey Affiliate
- Address: 4700 West 160th Street Cleveland, OH 44135 United States
- Telephone: 216-267-7100
- Email: info@oatey.com
Emergency Phone Numbers:
- Association/Organisation: Chemtrec
- Emergency Telephone: 1-800-424-9300 (Outside the US 1-703-527-3887)
- Other Emergency Telephone: Emergency First Aid: 1-877-740-5015
SECTION 2: Hazard(s) Identification
Classification of the substance or mixture: Not Applicable
Label elements:
- Hazard pictogram(s): Not Applicable
- Signal word: Not Applicable
Hazard statement(s): Not Applicable
Hazard(s) not otherwise classified: Not Applicable
Precautionary statement(s) Prevention: Not Applicable
Precautionary statement(s) Response: Not Applicable
Precautionary statement(s) Storage: Not Applicable
Precautionary statement(s) Disposal: Not Applicable
SECTION 3: Composition / Information on Ingredients
Substances: See section below for composition of Mixtures
| CAS No | %[weight] | Name |
|---|---|---|
| 1317-65-3* | 60-100 | calcium carbonate |
| 64741-88-4. | 1-5 | paraffinic distillate, heavy, solvent-refined (severe) |
| 1332-58-7* | 5-10 | Kaolin |
| 14808-60-7* | <2 | silica crystalline - quartz |
| 65997-17-3 | 1-5 | glass, oxide |
| 64742-88-7 | 0.1-1 | solvent naphtha petroleum, medium aliphatic. |
| 12001-26-2* | 0.1-1 | Mica |
| 13463-67-7* | 0.1-1 | Titanium dioxide |
| 14464-46-1 | 0.1-1 | cristobalite |
The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
SECTION 4: First-Aid Measures
Description of first aid measures:
- Eye Contact: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
- Skin Contact: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
- Inhalation: If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.
- Ingestion: Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Most important symptoms and effects, both acute and delayed: See Section 11
Indication of any immediate medical attention and special treatment needed: Treat symptomatically.
SECTION 5: Fire-Fighting Measures
Extinguishing media: Foam, Dry chemical powder, BCF (where regulations permit), Carbon dioxide, Water spray or fog - Large fires only.
Special hazards arising from the substrate or mixture:
- Fire Incompatibility: Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
Special protective equipment and precautions for fire-fighters:
- Alert Fire Department and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water courses.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
SECTION 6: Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: See section 8
Environmental precautions: See section 12
Methods and material for containment and cleaning up:
- Minor Spills: Clean up all spills immediately. Avoid contact with skin and eyes. Wear impervious gloves and safety glasses. Use dry clean up procedures and avoid generating dust. Vacuum up (consider explosion-proof machines designed to be grounded during storage and use). Do NOT use air hoses for cleaning. Place spilled material in clean, dry, sealable, labelled container.
- Major Spills: Clear area of personnel and move upwind. Alert Fire Department and tell them location and nature of hazard. Control personal contact with the substance, by using protective equipment and dust respirator. Prevent spillage from entering drains, sewers or water courses. Avoid generating dust. Sweep, shovel up. Recover product wherever possible. Put residues in labelled plastic bags or other containers for disposal. If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7: Handling and Storage
Precautions for safe handling:
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storage and handling recommendations contained within this SDS.
- Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
Other information: Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS. For major quantities: Consider storage in bunded areas ensure storage areas are isolated from sources of community water (including stormwater, ground water, lakes and streams}. Ensure that accidental discharge to air or water is the subject of a contingency disaster management plan; this may require consultation with local authorities.
Conditions for safe storage, including any incompatibilities:
- Suitable container: Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.
- Storage incompatibility: Avoid reaction with oxidising agents
SECTION 8: Exposure Controls / Personal Protection
Control parameters:
Occupational Exposure Limits (OEL):
| Source | Ingredient | Material name | TWA | STEL | Peak | Notes |
|---|---|---|---|---|---|---|
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | calcium carbonate | Inert or Nuisance Dust: Total Dust | 15 mg/m3/50 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | calcium carbonate | Inert or Nuisance Dust: Respirable fraction | 5 mg/m3/15 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | calcium carbonate | Marble- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | calcium carbonate | Marble- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | calcium carbonate | Calcium Carbonate- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | calcium carbonate | Calcium Carbonate- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | calcium carbonate | Limestone- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | calcium carbonate | Limestone- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | calcium carbonate | Limestone - respirable | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | calcium carbonate | Limestone - total | 10 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | calcium carbonate | Calcium carbonate - respirable | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | calcium carbonate | Calcium carbonate - total | 10 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | calcium carbonate | Marble - respirable | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | calcium carbonate | Marble - total | 10 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | paraffinic distillate, heavy, solvent-refined (severe) | Oil mist, mineral | 5 mg/m3 | Not Available | Not Available | Not Available |
| US ACGIH Threshold Limit Values (TLV) | paraffinic distillate, heavy, solvent-refined (severe) | Mineral oil, excluding metal working fluids - Poorly and mildly refined | Not Available | Not Available | A2 | Not Available |
| US ACGIH Threshold Limit Values (TLV) | paraffinic distillate, heavy, solvent-refined (severe) | Mineral oil, excluding metal working fluids - Pure, highly and severely refined (Inhalable particulate matter) | 5 mg/m3 | Not Available | A4 | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | Kaolin | Inert or Nuisance Dust: Total Dust | 15 mg/m3/50 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | Kaolin | Inert or Nuisance Dust: Respirable fraction | 5 mg/m3/15 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | Kaolin | Kaolin- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | Kaolin | Kaolin- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | Kaolin | Kaolin - respirable | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | Kaolin | Kaolin - total | 10 mg/m3 | Not Available | Not Available | Not Available |
| US ACGIH Threshold Limit Values (TLV) | Kaolin | Kaolin (Respirable particulate matter) | 2 mg/m3 | Not Available | A4 | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | silica crystalline - quartz | Silica: Crystalline: Quartz (Respirable) | 10 (%SiO2+2) mg/m3/250 (%SiO2+5) mppcf | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | silica crystalline - quartz | Silica, crystalline (as respirable dust) | 0.05 mg/m3 | Not Available | Ca; See Appendix A | Not Available |
| US ACGIH Threshold Limit Values (TLV) | silica crystalline - quartz | Silica, crystalline - a-quartz and cristobalite (Respirable particulate matter) | 0.025 mg/m3 | Not Available | A2 | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | glass, oxide | Inert or Nuisance Dust: Total Dust | 15 mg/m3/50 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | glass, oxide | Inert or Nuisance Dust: Respirable fraction | 5 mg/m3/15 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | glass, oxide | Particulates Not Otherwise Regulated (PNOR)- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | glass, oxide | Particulates Not Otherwise Regulated (PNOR)- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | glass, oxide | Particulates not otherwise regulated | Not Available | Not Available | See Appendix D | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | solvent naphtha petroleum, medium aliphatic. | Oil mist, mineral | 5 mg/m3 | Not Available | Not Available | Not Available |
| US ACGIH Threshold Limit Values (TLV) | solvent naphtha petroleum, medium aliphatic. | Mineral oil, excluding metal working fluids - Pure, highly and severely refined (Inhalable particulate matter) | 5 mg/m3 | Not Available | A4 | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | Mica | Inert or Nuisance Dust: Respirable fraction | 5 mg/m3/15 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | Mica | Inert or Nuisance Dust: Total Dust | 15 mg/m3/50 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | Mica | Particulates Not Otherwise Regulated (PNOR)- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | Mica | Particulates Not Otherwise Regulated (PNOR)- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | Mica | Mica (containing less than 1% quartz) | 3 mg/m3 | Not Available | Not Available | Not Available |
| US ACGIH Threshold Limit Values (TLV) | Mica | Mica (Respirable particulate matter) | 0.1 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | Titanium dioxide | Inert or Nuisance Dust: Respirable fraction | 5 mg/m3/15 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | Titanium dioxide | Inert or Nuisance Dust: Total Dust | 15 mg/m3/50 mppcf | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | Titanium dioxide | Titanium dioxide - Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | Titanium dioxide | Titanium dioxide | Not Available | Not Available | Ca; See Appendix A | Not Available |
| US ACGIH Threshold Limit Values (TLV) | Titanium dioxide | Titanium dioxide | 10 mg/m3 | Not Available | (A4) | Use 1½ the value |
| US OSHA Permissible Exposure Limits (PELs) Table Z-3 | cristobalite | Silica: Crystalline: Cristobalite | Not Available | Not Available | calculated from the count or mass formulae for quartz. | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | cristobalite | Particulates Not Otherwise Regulated (PNOR)- Total dust | 15 mg/m3 | Not Available | Not Available | Not Available |
| US OSHA Permissible Exposure Limits (PELs) Table Z-1 | cristobalite | Particulates Not Otherwise Regulated (PNOR)- Respirable fraction | 5 mg/m3 | Not Available | Not Available | Not Available |
| US NIOSH Recommended Exposure Limits (RELs) | cristobalite | Particulates not otherwise regulated | Not Available | Not Available | See Appendix D | Not Available |
| US ACGIH Threshold Limit Values (TLV) | cristobalite | Silica, crystalline - a-quartz and cristobalite (Respirable particulate matter) | 0.025 mg/m3 | Not Available | A2 | Not Available |
Exposure controls:
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure.
- Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively large, a certain proportion will be powdered by mutual friction.
- Exhaust ventilation should be designed to prevent accumulation and recirculation of particulates in the workplace.
- If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be considered. Such protection might consist of: (a): particle dust respirators, if necessary, combined with an absorption cartridge; (b): filter respirators with absorption cartridge or canister of the right type; (c): fresh-air hoods or masks
- Build-up of electrostatic charge on the dust particle, may be prevented by bonding and grounding.
- Powder handling equipment such as dust collectors, dryers and mills may require additional protection measures such as explosion venting.
Type of Contaminant:
- Direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion): Air Speed: 1-2.5 m/s (200-500 f/min.)
- Grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of very high rapid air motion): Air Speed: 2.5-10 m/s (500-2000 f/min.)
Within each range the appropriate value depends on:
- Lower end of the range: Room air currents minimal or favourable to capture; Contaminants of low toxicity or of nuisance value only; Intermittent, low production; Large hood or large air mass in motion
- Upper end of the range: Disturbing room air currents; Contaminants of high toxicity; High production, heavy use; Small hood-local control only
Personal protection:
- Eye and face protection: Safety glasses with side shields; Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]
- Skin protection: See Hand protection below. Wear appropriate chemical resistant gloves.
- Hands/feet protection: Wear appropriate chemical resistant gloves.
- Body protection: See Other protection below.
- Other protection: No special equipment needed when handling small quantities. OTHERWISE: Overalls. Barrier cream. Eyewash unit.
Respiratory protection: Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures. The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data, and frequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to personal protective equipment (powered, positive flow, full face apparatus may be an option). Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may be government mandated or vendor recommended. Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory protection program. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Use approved positive flow mask if significant quantities of dust becomes airborne. Try to avoid creating dust conditions.
SECTION 9: Physical and Chemical Properties
Information on basic physical and chemical properties:
| Appearance | Solid off white putty | Relative density (Water = 1) | 1.8 |
|---|---|---|---|
| Physical state | Solid | Partition coefficient n-octanol / water | Not Available |
| Odour | Slight | Auto-ignition temperature (°C) | Not Available |
| Odour threshold | Not Available | Decomposition temperature | Not Available |
| pH (as supplied) | Not Available | Viscosity (cSt) | >277777.778 |
| Melting point / freezing point (°C) | Not Available | Molecular weight (g/mol) | Not Available |
| Initial boiling point and boiling range (°C) | Not Available | Flash point (°C) | >100 |
| Evaporation rate | Not Available | Explosive properties | Not Available |
| Flammability | Not Applicable | Oxidising properties | Not Available |
| Upper Explosive Limit (%) | Not Available | Surface Tension (dyn/cm or mN/m) | Not Applicable |
| Lower Explosive Limit (%) | Not Available | Volatile Component (%vol) | Not Available |
| Vapour pressure (kPa) | Not Available | Gas group | Not Available |
| Solubility in water | Immiscible | pH as a solution (%) | Not Available |
| Vapour density (Air = 1) | Not Available | VOC g/L | 6 |
SECTION 10: Stability and Reactivity
Reactivity: See section 7
Chemical stability: Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous reactions: See section 7
Conditions to avoid: See section 7
Incompatible materials: See section 7
Hazardous decomposition products: See section 5
SECTION 11: Toxicological Information
Information on toxicological effects:
- Inhaled: The material is not thought to produce adverse health effects or irritation of the respiratory tract. Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.
- Ingestion: The material has NOT been classified as 'harmful by ingestion'. This is because of the lack of corroborating animal or human evidence.
- Skin Contact: The material is not thought to produce adverse health effects or skin irritation following contact. Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.
- Eye: Although the material is not thought to be an irritant, direct contact with the eye may cause transient discomfort characterized by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result.
- Chronic: In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica inhaled from occupational sources can cause lung cancer in humans. However in making the overall evaluation, IARC noted that 'carcinogenicity was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs.' (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.)
| Acute Toxicity | X | Carcinogenicity | X |
| Skin Irritation/Corrosion | X | Reproductivity | X |
| Serious Eye Damage/Irritation | X | STOT - Single Exposure | X |
| Respiratory or Skin Sensitisation | X | STOT - Repeated Exposure | X |
| Mutagenicity | X | Aspiration Hazard | X |
SECTION 12: Ecological Information
Toxicity:
| Endpoint | Test Duration (hr) | Species | Value | Source | |
|---|---|---|---|---|---|
| Hercules Sta Put | Not Available | Not Available | Not Available | Not Available | |
| calcium carbonate | Not Available | Not Available | Not Available | Not Available | |
| paraffinic distillate, heavy, solvent-refined (severe) | ErC50 | 72h | Algae or other aquatic plants | >1000mg/l | 1 |
| NOEC(ECX) | 504h | Crustacea | >1mg/l | 1 | |
| EC50 | 48h | Crustacea | >1000mg/l | 1 | |
| EC50 | 96h | Algae or other aquatic plants | >1000mg/l | 1 | |
| Kaolin | Not Available | Not Available | Not Available | Not Available | |
| silica crystalline - quartz | Not Available | Not Available | Not Available | Not Available | |
| glass, oxide | NOEC(ECX) | 72h | Algae or other aquatic plants | >=1000mg/l | 2 |
| EC50 | 72h | Algae or other aquatic plants | >1000mg/l | 2 | |
| LC50 | 96h | Fish | >1000mg/l | 2 | |
| solvent naphtha petroleum, medium aliphatic. | EC50(ECx) | 48h | Crustacea | >100mg/l | 1 |
| EC50 | 48h | Crustacea | >100mg/l | 1 | |
| EC50 | 96h | Algae or other aquatic plants | 450mg/l | 1 | |
| Mica | Not Available | Not Available | Not Available | Not Available | |
| Titanium dioxide | EC50 | 72h | Algae or other aquatic plants | 3.75-7.58mg/l | 4 |
| BCF | 1008h | Fish | <1.1-9.6 | 7 | |
| EC50 | 48h | Crustacea | 1.9mg/l | 2 | |
| LC50 | 96h | Fish | 1.85-3.06mg/l | 4 | |
| NOEC(ECX) | 504h | Crustacea | 0.02mg/l | 4 | |
| EC50 | 96h | Algae or other aquatic plants | 179.05mg/l | 2 | |
| cristobalite | Not Available | Not Available | Not Available | Not Available |
Persistence and degradability:
| Ingredient | Persistence: Water/Soil | Persistence: Air |
|---|---|---|
| Titanium dioxide | HIGH | HIGH |
Bioaccumulative potential:
| Ingredient | Bioaccumulation |
|---|---|
| Titanium dioxide | LOW (BCF = 10) |
Mobility in soil:
| Ingredient | Mobility |
|---|---|
| Titanium dioxide | LOW (KOC = 23.74) |
SECTION 13: Disposal Considerations
Waste treatment methods:
- Recycle wherever possible.
- Product / Packaging disposal: Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
SECTION 14: Transport Information
Labels Required:
- Marine Pollutant: NO
- Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
- Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk according to Annex II of MARPOL and the IBC code: Not Applicable
Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code:
| Product name | Group |
|---|---|
| calcium carbonate | Not Available |
| paraffinic distillate, heavy, solvent-refined (severe) | Not Available |
| Kaolin | Not Available |
| silica crystalline - quartz | Not Available |
| glass, oxide | Not Available |
| solvent naphtha petroleum, medium aliphatic. | Not Available |
| Mica | Not Available |
| Titanium dioxide | Not Available |
| cristobalite | Not Available |
Transport in bulk in accordance with the ICG Code:
| Product name | Ship Type |
|---|---|
| calcium carbonate | Not Available |
| paraffinic distillate, heavy, solvent-refined (severe) | Not Available |
| Kaolin | Not Available |
| silica crystalline - quartz | Not Available |
| glass, oxide | Not Available |
| solvent naphtha petroleum, medium aliphatic. | Not Available |
| Mica | Not Available |
| Titanium dioxide | Not Available |
| cristobalite | Not Available |
SECTION 15: Regulatory Information
Safety, health and environmental regulations / legislation specific for the substance or mixture:
calcium carbonate is found on the following regulatory lists: US NIOSH Recommended Exposure Limits (RELs), US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
paraffinic distillate, heavy, solvent-refined (severe) is found on the following regulatory lists: Chemical Footprint Project - Chemicals of High Concern List, International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs, US ACGIH Threshold Limit Values (TLV), US ACGIH Threshold Limit Values (TLV) - Carcinogens
Kaolin is found on the following regulatory lists: Chemical Footprint Project - Chemicals of High Concern List, International WHO List of Proposed Occupational Exposure Limit (OEL) Values for Manufactured Nanomaterials (MNMS), US ACGIH Threshold Limit Values (TLV), US ACGIH Threshold Limit Values (TLV) - Carcinogens, US NIOSH Recommended Exposure Limits (RELs), US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
silica crystalline - quartz is found on the following regulatory lists: US DOE Temporary Emergency Exposure Limits (TEELs), US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
glass, oxide is found on the following regulatory lists: US DOE Temporary Emergency Exposure Limits (TEELs), US NIOSH Recommended Exposure Limits (RELs), US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
solvent naphtha petroleum, medium aliphatic. is found on the following regulatory lists: Chemical Footprint Project - Chemicals of High Concern List, International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs, International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Group 1: Carcinogenic to humans, US - California Proposition 65 - Carcinogens, US - California Safe Drinking Water and Toxic Enforcement Act of 1986 - Proposition 65 List, US ACGIH Threshold Limit Values (TLV), US ACGIH Threshold Limit Values (TLV) - Carcinogens, US DOE Temporary Emergency Exposure Limits (TEELs), US National Toxicology Program (NTP) 14th Report Part A Known to be Human Carcinogens, US NIOSH Carcinogen List, US NIOSH Recommended Exposure Limits (RELs), US OSHA Carcinogens Listing, US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
Mica is found on the following regulatory lists: US ACGIH Threshold Limit Values (TLV), US DOE Temporary Emergency Exposure Limits (TEELs), US NIOSH Recommended Exposure Limits (RELs), US OSHA Carcinogens Listing, US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
Titanium dioxide is found on the following regulatory lists: Chemical Footprint Project - Chemicals of High Concern List, International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs, International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Group 2B: Possibly carcinogenic to humans, International WHO List of Proposed Occupational Exposure Limit (OEL) Values for Manufactured Nanomaterials (MNMS), US - California Proposition 65 - Carcinogens, US - California Safe Drinking Water and Toxic Enforcement Act of 1986 - Proposition 65 List, US ACGIH Threshold Limit Values (TLV), US ACGIH Threshold Limit Values (TLV) - Carcinogens, US ACGIH Threshold Limit Values (TLV) - Notice of Intended Changes, US DOE Temporary Emergency Exposure Limits (TEELs), US List of Active Substances Exempt from the TSCA Inventory Notifications (Active-Inactive) Rule, US NIOSH Carcinogen List, US NIOSH Recommended Exposure Limits (RELs), US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
cristobalite is found on the following regulatory lists: Chemical Footprint Project - Chemicals of High Concern List, US - California Proposition 65 - Carcinogens, US - California Safe Drinking Water and Toxic Enforcement Act of 1986 - Proposition 65 List, US ACGIH Threshold Limit Values (TLV), US ACGIH Threshold Limit Values (TLV) - Carcinogens, US DOE Temporary Emergency Exposure Limits (TEELs), US NIOSH Carcinogen List, US NIOSH Recommended Exposure Limits (RELs), US OSHA Carcinogens Listing, US OSHA Permissible Exposure Limits (PELs) Table Z-1, US OSHA Permissible Exposure Limits (PELs) Table Z-3, US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory, US TSCA Chemical Substance Inventory - Interim List of Active Substances
Federal Regulations:
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Section 311/312 hazard categories:
- Flammable (Gases, Aerosols, Liquids, or Solids): No
- Gas under pressure: No
- Explosive: No
- Self-heating: No
- Pyrophoric (Liquid or Solid): No
- Pyrophoric Gas: No
- Corrosive to metal: No
- Oxidizer (Liquid, Solid or Gas): No
- Organic Peroxide: No
- Self-reactive: No
- In contact with water emits flammable gas: No
- Combustible Dust: No
- Carcinogenicity: No
- Acute toxicity (any route of exposure): No
- Reproductive toxicity: No
- Skin Corrosion or Irritation: No
- Respiratory or Skin Sensitization: No
- Serious eye damage or eye irritation: No
- Specific target organ toxicity (single or repeated exposure): No
- Aspiration Hazard: No
- Germ cell mutagenicity: No
- Simple Asphyxiant: No
- Hazards Not Otherwise Classified: No
US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4): None Reported
State Regulations:
US. California Proposition 65: WARNING: This product can expose you to chemicals including silica, crystalline, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
National Inventory Status:
| National Inventory | Status |
|---|---|
| USA - TSCA | Yes |
SECTION 16: Other Information
Revision Date: 07/21/2021
Initial Date: 07/16/2021
Other information: The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations:
- PC-TWA: Permissible Concentration-Time Weighted Average
- PC-STEL: Permissible Concentration-Short Term Exposure Limit
- IARC: International Agency for Research on Cancer
- ACGIH: American Conference of Governmental Industrial Hygienists
- STEL: Short Term Exposure Limit
- TEEL: Temporary Emergency Exposure Limit。
- IDLH: Immediately Dangerous to Life or Health Concentrations
- ES: Exposure Standard
- OSF: Odour Safety Factor
- NOAEL: No Observed Adverse Effect Level
- LOAEL: Lowest Observed Adverse Effect Level
- TLV: Threshold Limit Value
- LOD: Limit Of Detection
- OTV: Odour Threshold Value
- BCF: BioConcentration Factors
- BEI: Biological Exposure Index
- AIIC: Australian Inventory of Industrial Chemicals
- DSL: Domestic Substances List
- NDSL: Non-Domestic Substances List
- IECSC: Inventory of Existing Chemical Substance in China
- EINECS: European Inventory of Existing Commercial chemical Substances
- ELINCS: European List of Notified Chemical Substances
- NLP: No-Longer Polymers
- ENCS: Existing and New Chemical Substances Inventory
- KECI: Korea Existing Chemicals Inventory
- NZIoC: New Zealand Inventory of Chemicals
- PICCS: Philippine Inventory of Chemicals and Chemical Substances
- TSCA: Toxic Substances Control Act
- TCSI: Taiwan Chemical Substance Inventory
- INSQ: Inventario Nacional de Sustancias Químicas
- NCI: National Chemical Inventory
- FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances
