HP CH564 Series Ink Cartridge Safety Data Sheet

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

Important information

This Safety Data Sheet is only authorised for use by HP for HP Original products. Any unauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal action being taken by HP.

1.1. Product identifier

Trade name or designation of the mixture:

Identified uses: Inkjet printing

Uses advised against: None known.

1.3. Details of the supplier of the safety data sheet

Supplier: HP Inc UK Ltd, Regulatory Enquiries, Earley West, 300 Thames Valley Park Drive, Reading, RG6 1PT

Telephone: +44 20 7660 0596 (Consumer) / +44 20 7660 0403 (Commercial)

HP Inc. health effects line: 1-800-457-4209 (Toll-free US) / 1-760-710-0048 (Direct)

HP Inc. Customer Care Line: 1-800-474-6836 (Toll-free US) / 1-208-323-2551 (Direct)

Email: hpcustomer.inquiries@hp.com

1.4 Emergency telephone number

0207771 5307

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

This mixture does not meet the criteria for classification as hazardous according to Regulation (EC) No 1272/2008.

2.2. Label elements

Hazard pictograms: None

Signal word: None

Hazard statements: The mixture does not meet the criteria for classification.

Precautionary statements: Prevention: Not available, Response: Not available, Storage: Not available, Disposal: Not available

Supplemental label information

Contains 1,2-Benzisothiazolin-3-one. May produce an allergic reaction.

2.3. Other hazards

Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Chemical name % CAS-No. / EC No. Classification
Water 70-90 / 65-80 7732-18-5 / 231-791-2 -
Copper phthalocyanine direct dye salt <5 1025071-45-7 / 696-533-7 Eye Dam. 1;H318, Aquatic Chronic 3;H412
1,2-Benzisothiazolin-3-one <0.05 2634-33-5 / 220-120-9 Acute Tox. 4;H302, Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Dam. 1;H318, Aquatic Acute 1;H400

Composition comments: This ink supply contains an aqueous ink formulation.

SECTION 4: First Aid Measures

4.1. Description of first aid measures

Inhalation: Remove to fresh air. If symptoms persist, get medical attention.

Skin contact: Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists.

Eye contact: Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention.

Ingestion: If ingestion of a large amount does occur, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Not available.

4.3. Indication of any immediate medical attention and special treatment needed

Not available.

SECTION 5: Firefighting Measures

5.1. Extinguishing media

Suitable extinguishing media: Dry chemical, CO2, water spray or regular foam.

Unsuitable extinguishing media: None known.

5.2. Special hazards arising from the substance or mixture

Not available.

5.3. Advice for firefighters

Special protective equipment for firefighters: Not available.

Special fire fighting procedures: Not available.

Specific methods: None established.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency personnel: Wear appropriate personal protective equipment.

For emergency responders: Not available.

6.2. Environmental precautions

Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

6.3. Methods and material for containment and cleaning up

Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps.

6.4. Reference to other sections

Not available.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling

Avoid contact with skin, eyes and clothing.

7.2. Conditions for safe storage, including any incompatibilities

Keep out of the reach of children. Keep away from excessive heat or cold.

7.3. Specific end use(s)

Not available.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Occupational exposure limits: No exposure limits noted for ingredient(s).

Biological limit values: No biological exposure limits noted for the ingredient(s).

Recommended monitoring procedures: Not available.

Derived no effect levels (DNELs): Not available.

Predicted no effect concentrations (PNECs): Not available.

Exposure guidelines: Exposure limits have not been established for this product.

8.2. Exposure controls

Appropriate engineering controls: Use in a well ventilated area.

Individual protection measures, such as personal protective equipment

General information: Use personal protective equipment to minimize exposure to skin and eye.

Eye/face protection: Not available.

Skin protection: Hand protection: Not available, Other: Not available.

Respiratory protection: Not available.

Thermal hazards: Not available.

Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls: Not available.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance: Liquid.

Form: Not available.

Color: Cyan, Magenta, Yellow (product dependent)

Odor: Not available.

Odor threshold: Not available.

pH: 8 - 8.4

Melting point/freezing point: Not available.

Initial boiling point and boiling range: Not determined

Flash point: > 200.0 °F (> 93.3 °C) Pensky-Martens Closed Cup

Evaporation rate: Not determined

Flammability (solid, gas): Not available.

Upper/lower flammability or explosive limits: Flammability limit - lower (%): Not available, Flammability limit - upper (%): Not available.

Vapor pressure: Not determined

Vapor density: >= 1 (air = 1.0)

Solubility(ies): Solubility (water): Soluble in water

Partition coefficient (n-octanol/water): Not available.

Auto-ignition temperature: Not available.

Decomposition temperature: Not available.

Viscosity: <= 2 cp

Explosive properties: Not available.

Oxidizing properties: Not determined

9.2. Other information

VOC: < 171 g/L / < 172 g/L

SECTION 10: Stability and reactivity

10.1. Reactivity: Not available.

10.2. Chemical stability: Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions: Will not occur.

10.4. Conditions to avoid: Not available.

10.5. Incompatible materials: Incompatible with strong bases and oxidizing agents.

10.6. Hazardous decomposition products: Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.

SECTION 11: Toxicological information

General information

Not available.

Information on likely routes of exposure

Inhalation: Under normal conditions of intended use, this material is not expected to be an inhalation hazard.

Skin contact: Contact with skin may result in mild irritation.

Eye contact: Contact with eyes may result in mild irritation.

Ingestion: Health injuries are not known or expected under normal use.

Symptoms

Not available.

11.1. Information on toxicological effects

Acute toxicity: Based on available data, the classification criteria are not met.

Skin corrosion/irritation: Based on available data, the classification criteria are not met. Non irritant in rabbit (OECD 404)

Serious eye damage/eye irritation: Based on available data, the classification criteria are not met. Not classified as an irritant according to, Rabbit Enucleated Eye Test.

Respiratory sensitization: Based on available data, the classification criteria are not met.

Skin sensitization: Based on available data, the classification criteria are not met.

Germ cell mutagenicity: Based on available data, the classification criteria are not met.

Carcinogenicity: Based on available data, the classification criteria are not met.

Reproductive toxicity: Based on available data, the classification criteria are not met.

Specific target organ toxicity - single exposure: Based on available data, the classification criteria are not met.

Specific target organ toxicity - repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard: Based on available data, the classification criteria are not met.

Mixture versus substance information: Not available.

Other information: Complete toxicity data are not available for this specific formulation. Refer to Section 2 for potential health effects and Section 4 for first aid measures.

SECTION 12: Ecological information

12.1. Toxicity

Aquatic toxicity: No toxicity data noted for the ingredient(s). This product has not been tested for ecological effects.

12.2. Persistence and degradability

Not available.

12.3. Bioaccumulative potential

Not available.

Partition coefficient n-octanol/water (log Kow): Not available.

Bioconcentration factor (BCF): Not available.

12.4. Mobility in soil

Not available.

12.5. Results of PBT and vPvB assessment

Not a PBT or vPvB substance or mixture.

12.6. Other adverse effects

Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Residual waste: Not available.

Contaminated packaging: Not available.

EU waste code: Not available.

Disposal methods/information: Do not dispose of together with general office waste. Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.

HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit http://www.hp.com/recycle.

SECTION 14: Transport information

The product is not classified as a dangerous good for transport by DOT, IATA, ADR, IMDG, or RID.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code: Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulations: Various regulations listed, generally not applicable or not listed for this mixture.

Other regulations: All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China.

Other information: This Safety Data Sheet complies with the requirements of Regulation (EU) 2015/830. Classification according to Regulation (EC) No 1272/2008 as amended.

National regulations: Not available.

15.2. Chemical safety assessment

See attached SUMI or GEIS document, if applicable.

SECTION 16: Other information

References

Regulation (EC) No. 1907/2006 (REACH), Regulation (EU) 2015/830, Regulation (EC) No. 1272/2008 (CLP).

Information on evaluation method leading to the classification of mixture

The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available.

Full text of any H-statements not written out in full under Sections 2 to 15

H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Revision information

None.

Training information

Follow training instructions when handling this material.

Disclaimer

This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries.

This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled, remanufactured, compatible or other non-HP Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment, exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs.

Explanation of abbreviations

ACGIH: American Conference of Governmental Industrial Hygienists, CAS: Chemical Abstracts Service, CERCLA: Comprehensive Environmental Response Compensation and Liability Act, CFR: Code of Federal Regulations, COC: Cleveland Open Cup, DOT: Department of Transportation, EPCRA: Emergency Planning and Community Right-to-Know Act (aka SARA), IARC: International Agency for Research on Cancer, NIOSH: National Institute for Occupational Safety and Health, NTP: National Toxicology Program, OSHA: Occupational Safety and Health Administration, PEL: Permissible Exposure Limit, RCRA: Resource Conservation and Recovery Act, REC: Recommended, REL: Recommended Exposure Limit, SARA: Superfund Amendments and Reauthorization Act of 1986, STEL: Short-Term Exposure Limit, TCLP: Toxicity Characteristics Leaching Procedure, TLV: Threshold Limit Value, TSCA: Toxic Substances Control Act, VOC: Volatile Organic Compounds.

Safe Use of Mixture Information (SUMI)

Water Based Ink: WB01 *English*

Disclaimer: This SUMI is a generic document for communicating conditions of safe use of a product in response to the REACH obligation. This document relates only to conditions of safe use and is not specific to a product. By adding this SUMI to a specific product SDS, the importer/formulator declares that the mixture can safely be used following the instructions below. Following occupational health legislation, the employer of workers remains responsible for communicating relevant use information to employees. When developing workplace instructions for employees, SUMI Sheets should always be considered in combination with the SDS and the label of the product. Derived No Effect Levels (DNEL) and Predicted No Effect Concentration (PNEC) values of substances derived from the Chemical Safety Assessment (CSA) will be given in section 8 of the SDS. The REACH registration number(s), where applicable, completes an extended product SDS.

Operational conditions

Maximum duration: Up to 8 hours per day

Frequency of exposure: < 240 days per year

Process conditions: Covers use at ambient temperatures. Adequate ventilation should be provided for the areas where printing is performed. ANSI/ASHRAE Standard 62.1-2013 provides guidelines to ensure acceptable air quality in the workspace.

Risk management measures

Conditions and measures related to Personal Protection Equipment, hygiene and health evaluation: Avoid direct contact. Regular cleaning of equipment and work area. Supervision in place to check that Risk Management Measures are in place are being correctly used and Operational Conditions followed. Wear safety glasses with side shields (or goggles), if splashing is possible. Wear appropriate chemical resistant gloves: see section 8 of the SDS. Wear appropriate chemical resistant clothing. In case of inadequate ventilation wear respiratory protection. Eye wash fountain and emergency showers are recommended. Avoid breathing mist/vapours. Avoid contact with skin, eyes and clothing. Training of workers in relation to proper use and maintenance of all Personal protection equipment (PPE) must be ensured.

Good practice advice

Use personal protective equipment as required. Wash hands before breaks and after work. Keep good industrial hygiene and safety practice. Use only with adequate ventilation. Do no eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Store at room temperature.

Environmental measures

Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal and Provincial Environmental Regulations. Ensure collection and disposal with appropriately licenced waste contractor.

Use descriptors

IS-Use at industrial sites, PW-Widespread use by professional workers, SU7-Printing and reproduction media, PC18-Inks and Toners, PROC1-Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions, PROC2-Chemical production or refinery in closed continuous process with occasional controlled exposure or processes with equivalent containment conditions, PROC3- Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment condition, PROC8a-Transfer of substance or mixture (charging and discharging) at non-dedicated facilities, PROC8b-Transfer of substance or mixture (charging and discharging) at dedicated facilities, ERC5-Use at industrial site leading to inclusion into/onto article, ERC8c-Widespread use leading to inclusion into/onto article (indoor).

Additional information on product composition

In section 2 of the SDS as well as on the label, the classification of the mixture is provided. Most of the water based inks are "not classified". The classification of the mixture is based on the individual ingredients and their concentration within the mixture. All ingredients contributing to the classification are stated in Section 3 of the SDS. Relevant limit values of ingredients on which the exposure assessment is based, are listed in section 8 of the SDS. The product may contain sensitizing ingredients that may cause allergic reaction to certain people. Section 2 of the SDS states these ingredients where applicable.

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