Brother Industries, Ltd.
SAFETY DATA SHEET
Product Name: LC501BK, LC504BK, LC511BK, LC514BK, LC521BK, LC522BK, LC531BK, LC551BK ink
Revision Date: -
Issuing Date: 09-Apr-2025
Revision Number: 1
Safety Data Sheet Number: BHK336
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Safety data sheet number: BHK336
Product Name: LC501BK, LC504BK, LC511BK, LC514BK, LC521BK, LC522BK, LC531BK, LC551BK ink
Other means of identification: Mixture
Pure substance/mixture: Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: These products are black ink in a cartridge for Brother Industries, Ltd. inkjet multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and for use in the products stated. Information provided on this SDS is only consistent with the use specified by Brother.
Uses advised against: No information available
1.3. Details of the supplier of the safety data sheet
Manufacturer: Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Supplier (Europe): Brother International (Nederland) B.V.
Zanderij 25, 1185 ZM Amstelveen, The Netherlands
Brother International Europe Ltd.
1 Tame Street, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
For further information, please contact:
E-mail address: sds.info@brother.co.jp
1.4. Emergency telephone number
Emergency Telephone: CHEMTREC +1-703-527-3887 (International)
For France only: Antipoison Center telephone number: ORFILA +33-1-45-425-959
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]
2.2. Label elements
This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]
Hazard statements: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]
EUH208 - Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
Unknown acute toxicity:
- 0% of the mixture consists of ingredient(s) of unknown acute oral toxicity.
- 0% of the mixture consists of ingredient(s) of unknown acute dermal toxicity.
- 35.9% of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas).
- 35.9% of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor).
- 7.9% of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist).
Unknown aquatic toxicity: Contains 0 % of components with unknown hazards to the aquatic environment.
2.3. Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
Endocrine Disruptor Information: This product does not contain any known or suspected endocrine disruptors.
SECTION 3: Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
| Chemical name | CAS No. | EC No (EU Index No) | Weight-% | Classification according to Regulation (EC) No. 1272/2008 [CLP] | Specific concentration limit (SCL) | M-Factor | M-Factor (long-term) | REACH registration number |
|---|---|---|---|---|---|---|---|---|
| Water | 7732-18-5 | 231-791-2 | 65-75 | No data available | - | - | - | Not applicable |
| Glycerol | 56-81-5 | 200-289-5 | 5-15 | No data available | - | - | - | Not applicable |
| Diethylene glycol | 111-46-6 | 203-872-2 (603-140-00-6) | 5-9 | Acute Tox. 4 (H302) | - | - | - | Not applicable |
| Carbon Black | 1333-86-4 | 215-609-9 | 5-9 | No data available | - | - | - | Not applicable |
| [2-(2-methoxymethyl ethoxy)methylethoxy]propanol | 25498-49-1 | 247-045-4 | 1-5 | Eye Irrit. 2 (H319) | - | - | - | Not applicable |
| 2,2'-(ethylenedioxy)diethanol | 112-27-6 | 203-953-2 | 1-5 | No data available | - | - | - | Not applicable |
| 1,2,3-benzotriazole | 95-14-7 | 202-394-1 (613-350-00-X) | <0.3 | Aquatic Chronic 2 (H411) | - | - | - | Not applicable |
| 1,2-benzisothiazol-3(2H)-one | 2634-33-5 | 220-120-9 (613-088-00-6) | <0.05 | Acute Tox. 2 (H330) Skin Sens. 1A (H317) Acute Tox. 4 (H302) Skin Irrit. 2 (H315) Eye Dam. 1 (H318) Skin Sens. 1A (H317) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) |
C>=0.036% | 1 | 1 | Not applicable |
Acute Toxicity Estimate
If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture based on its components.
| Chemical name | Oral LD50 mg/kg | Dermal LD50 mg/kg | Inhalation LC50 - 4 hour - dust/mist - mg/L | Inhalation LC50 - 4 hour - vapor - mg/L | Inhalation LC50 - 4 hour - gas - ppm |
|---|---|---|---|---|---|
| Water (7732-18-5) | > 89838.9 | No data available | No data available | No data available | No data available |
| Glycerol (56-81-5) | 27200 | 10000 | 5.85 | No data available | No data available |
| Diethylene glycol (111-46-6) | 12565 | 11890 | 4.6 | No data available | No data available |
| Carbon Black (1333-86-4) | 10000 | 2000 | 0.0046 | No data available | No data available |
| [2-(2-methoxymethyl ethoxy)methylethoxy]propanol | 3200 | 15440 | No data available | No data available | No data available |
| 2,2'-(ethylenedioxy)diethanol (112-27-6) | 17000 | 22600 | 5.2 | No data available | No data available |
| 1,2,3-benzotriazole (95-14-7) | 560 | 10000 | 1.4325 | No data available | No data available |
| 1,2-benzisothiazol-3(2H)-one (2634-33-5) | 450 | 2000 | 0.21 | No data available | No data available |
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59)
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice: If symptoms persist, call a physician.
Inhalation: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get immediate medical advice/attention.
Eye contact: In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists.
Skin contact: Wash skin with soap and water. Get medical attention if irritation develops and persists.
Ingestion: Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to drink.
Self-protection of the first aider: No information available.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms:
- Inhalation: No specific effects and/or symptoms have been reported or known. For large quantities: May cause irritation to the respiratory system. Increased difficulty in breathing. Sneezing. Coughing.
4.3. Indication of any immediate medical attention and special treatment needed
Note to physicians: Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable Extinguishing Media: Dry chemical, CO2, water spray or regular foam
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical: Thermal decomposition can lead to release of irritating and toxic gases and vapors Carbon monoxide Carbon dioxide (CO2) Nitrogen oxides (NOx) Oxides of sulfur
5.3. Advice for firefighters
Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: Avoid contact with eyes, skin and clothing
For emergency responders: Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions: Prevent entry into waterways, sewers, basements or confined areas
6.3. Methods and material for containment and cleaning up
Methods for containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.
Methods for cleaning up: Wipe up with absorbent towel Wash with water to remove remaining traces of ink. Clean contaminated objects and areas thoroughly observing environmental regulations.
Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections: See section 8 for more information. See section 13 for more information.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling: Avoid contact with eyes, skin and clothing.
General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions: Keep out of the reach of children. Keep cool. Protect from sunlight.
7.3. Specific end use(s)
Specific use(s): These products are black ink in a cartridge for Brother Industries, Ltd. inkjet multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and for use in the products stated.
Risk Management Methods (RMM): The information required is contained in this Safety Data Sheet.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure Limits
| Chemical name | European Union | Austria | Belgium | Bulgaria | Croatia | Czech Republic | Denmark | Estonia | Finland | France | Germany TRGS | Germany DFG | Greece | Hungary | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Glycerol (56-81-5) | - | TWA: 10 ppm TWA: 44 mg/m³ STEL 40 ppm STEL 176 mg/m³ |
TWA: 10 mg/m³ | TWA: 10 mg/m³ | TWA: 10 mg/m³ TWA: 23 ppm TWA: 101 mg/m³ |
TWA: 10 mg/m³ Ceiling: 15 mg/m³ |
TWA: 2.5 ppm TWA: 11 mg/m³ STEL: 5 ppm STEL: 22 mg/m³ |
TWA: 10 mg/m³ TWA: 10 ppm TWA: 45 mg/m³ STEL: 20 ppm STEL: 90 mg/m³ A* |
TWA: 20 mg/m³ | TWA: 10 mg/m³ | TWA: 200 mg/m³ | TWA: 200 mg/m³ | TWA: 10 mg/m³ | - | |
| Diethylene glycol (111-46-6) | - | TWA: 10 mg/m³ | TWA: 15.0 mg/m³ | TWA: 10 mg/m³ | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
- | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
TWA: 10 mg/m³ | TWA: 10 ppm TWA: 45 mg/m³ STEL: 20 ppm STEL: 90 mg/m³ |
TWA: 10 mg/m³ | TWA: 44 mg/m³ | TWA: 10 mg/m³ | TWA: 10 mg/m³ | TWA: 10 ppm TWA: 44 mg/m³ Peak: 400 mg/m³ Peak: 40 ppm Peak: 176 mg/m³ |
|
| Carbon Black (1333-86-4) | - | TWA: 3 mg/m³ | TWA: 3 mg/m³ | TWA: 15.0 mg/m³ | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
TWA: 2.0 mg/m³ | TWA: 3 mg/m³ | TWA: 3 mg/m³ | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
TWA: 3 mg/m³ | TWA: 3 mg/m³ | TWA: 3 mg/m³ | TWA: 3 mg/m³ | TWA: 3.5 mg/m³ | |
| 2,2'-(ethylenedioxy)diethanol (112-27-6) | - | - | TWA: 1000 mg/m³ Peak: 2000 mg/m³ |
TWA: 1000 mg/m³ Peak: 2000 mg/m³ |
- | - | TWA: 1000 mg/m³ STEL: 2000 mg/m³ |
- | - | - | - | - | - | TWA: 1000 mg/m³ STEL: 2000 mg/m³ |
|
| 1,2,3-benzotriazole (95-14-7) | - | - | - | - | - | - | - | - | - | - | - | - | TWA: 5 mg/m³ | - | |
| 1,2-benzisothiazol-3(2H)-one (2634-33-5) | - | - | - | - | - | - | - | - | - | - | - | - | - | - | skin sensitizer |
| Chemical name | Ireland | Italy MDLPS | Italy AIDII | Latvia | Lithuania | Luxembourg | Malta | Netherlands | Norway | Poland | Portugal | Romania | Slovakia | Slovenia | Spain |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Diethylene glycol (111-46-6) | TWA: 23 ppm TWA: 100 mg/m³ STEL: 69 ppm STEL: 300 mg/m³ |
- | - | TWA: 10 mg/m³ | TWA: 10 ppm TWA: 45 mg/m³ STEL: 20 ppm STEL: 90 mg/m³ O* |
- | - | TWA: 10 ppm TWA: 44 mg/m³ Ceiling: 90 mg/m³ |
TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
TWA: 10 mg/m³ | TWA: 10 mg/m³ | TWA: 115 ppm TWA: 500 mg/m³ STEL: 184 ppm STEL: 800 mg/m³ |
TWA: 10 ppm TWA: 44 mg/m³ Ceiling: 10 mg/m³ |
TWA: 200 mg/m³ STEL: 400 mg/m³ |
TWA: 10 mg/m³ |
| Carbon Black (1333-86-4) | TWA: 3 mg/m³ STEL: 15 mg/m³ |
TWA: 3 mg/m³ | - | TWA: 3 mg/m³ | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
- | - | - | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
TWA: 4 mg/m³ | TWA: 3 mg/m³ | TWA: 2 mg/m³ TWA: 10 mg/m³ |
TWA: 10 mg/m³ | TWA: 3.5 mg/m³ | |
| 2,2'-(ethylenedioxy)diethanol (112-27-6) | TWA: 114 ppm TWA: 700 mg/m³ STEL: 163 ppm STEL: 1000 mg/m³ |
- | TWA: 1000 mg/m³ STEL: 2000 mg/m³ |
- | - | - | - | - | - | - | - | - | - | - | - |
| 1,2,3-benzotriazole (95-14-7) | - | - | - | TWA: 5 mg/m³ | - | - | - | - | - | - | - | - | - | - | - |
| Chemical name | Sweden | Switzerland | United Kingdom |
|---|---|---|---|
| Glycerol (56-81-5) | NGV: 10 ppm NGV: 45 mg/m³ |
TWA: 50 mg/m³ STEL: 100 mg/m³ |
TWA: 10 mg/m³ STEL: 30 mg/m³ |
| Diethylene glycol (111-46-6) | TWA: 10 ppm TWA: 44 mg/m³ |
TWA: 10 ppm TWA: 44 mg/m³ |
TWA: 23 ppm TWA: 101 mg/m³ |
| Carbon Black (1333-86-4) | NGV: 3 mg/m³ | - | TWA: 3.5 mg/m³ STEL: 7 mg/m³ |
| 2,2'-(ethylenedioxy)diethanol (112-27-6) | - | TWA: 1000 mg/m³ STEL: 2000 mg/m³ |
- |
| 1,2,3-benzotriazole (95-14-7) | - | - | - |
| 1,2-benzisothiazol-3(2H)-one (2634-33-5) | - | - | - |
Biological occupational exposure limits
| Chemical name | European Union | Austria | Bulgaria | Croatia | Czech Republic |
|---|---|---|---|---|---|
| Carbon Black (1333-86-4) | - (-) | - | - | - | - |
Derived No Effect Level (DNEL) - Workers: No information available
Derived No Effect Level (DNEL) - General Public: No information available.
Predicted No Effect Concentration (PNEC): No information available.
8.2. Exposure controls
Appropriate engineering controls: Good general ventilation should be sufficient under normal use.
Personal protective equipment: Not normally required. For use other than in normal operating procedures (such as in the event of large spill), the following should be applied:
- Eye/face protection: Safety goggles
- Hand protection: Protective gloves
- Skin and body protection: Apron, Rubber boots
- Respiratory protection: In case of large spillages: Wear suitable respiratory protective equipment.
Thermal hazards: No information available.
General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls: Avoid release to the environment.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state: Liquid
Color: black
Odor: Slight
Odor threshold: No information available
| Property | Values | Remarks • Method |
|---|---|---|
| Melting point / freezing point | < -5 °C | None known |
| Initial boiling point and boiling range | > 100 °C | None known |
| Flammability | No data available | None known |
| Flammability Limit in Air | No data available | None known |
| Upper flammability or explosive limits | No data available | None known |
| Lower flammability or explosive limits | No data available | None known |
| Flash point | > 93.3 °C | Tag Closed Cup, Cleveland Open Cup |
| Autoignition temperature | > 400 °C | None known |
| Decomposition temperature | No data available | None known |
| pH | 7 | None known |
| pH (as aqueous solution) | 9 | No information available |
| Kinematic viscosity | No data available | None known |
| Dynamic viscosity | 1.5 mPa-s | None known |
| Water solubility | Soluble in water | None known |
| Solubility(ies) | No information available | None known |
| Partition coefficient | No data available | None known |
| Vapor pressure | No data available | None known |
| Relative density | 1.0 - 1.1 | (H2O=1) |
| Bulk density | No data available | None known |
| Liquid Density | No data available | None known |
| Relative vapor density | No data available | None known |
| Particle characteristics | No data available | None known |
| Particle Size | No data available | None known |
| Particle Size Distribution | No data available | None known |
9.2. Other information
9.2.1. Information with regard to physical hazard classes
Explosives:
- Explosive properties: No information available
- Oxidizing properties: No information available
9.2.2. Other safety characteristics
No information available
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity: None.
10.2. Chemical stability
Stability: Stable under normal conditions.
Explosion data:
- Sensitivity to mechanical impact: None.
- Sensitivity to static discharge: None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions: None under normal processing.
10.4. Conditions to avoid
Conditions to avoid: Keep away from heat. Keep away from water or moist air.
10.5. Incompatible materials
Incompatible materials: Acids, Bases, Oxidizing agent, Reducing agent
10.6. Hazardous decomposition products
Hazardous decomposition products: Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx), Oxides of sulfur
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Information on likely routes of exposure
Product Information:
- Inhalation: No information available
- Eye contact: No information available
- Skin contact: No information available.
- Ingestion: Acute LD50 > 2000 mg/kg (OECD 420 method)
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms: No information available.
Acute toxicity
Numerical measures of toxicity
| Chemical name | Oral LD50 | Dermal LD50 | Inhalation LC50 |
|---|---|---|---|
| Water | > 90 mL/kg (Rat) | - | - |
| Glycerol | = 27200 mg/kg (Rat) | > 10 g/kg (Rabbit) | > 5.85 mg/L (Rat) 4 h |
| Diethylene glycol | = 12565 mg/kg (Rat) | = 11890 mg/kg (Rabbit) | > 4600 mg/m³ (Rat) 4 h |
| Carbon Black | > 10000 mg/kg (Rat) | > 2000 mg/kg (Rabbit) | > 4.6 mg/m³ (Rat) 4 h |
| Dipropylene glycol propyl ether | = 1620 µL/kg (Rat) | >= 2000 mg/kg (Rabbit) | - |
| [2-(2-methoxymethylethoxy)methylethoxy]propanol | = 3200 mg/kg (Rat) | = 15440 mg/kg (Rabbit) | - |
| 2,2'-(ethylenedioxy)diethanol | = 17 g/kg (Rat) | > 20 mL/kg (Rabbit) | > 5.2 mg/L (Rat) 4 h |
| 1,2,3-benzotriazole | = 560 mg/kg (Rat) | > 10000 mg/kg (Rabbit) | = 1910 mg/m³ (Rat) 3 h |
| 1,2-benzisothiazol-3(2H)-one | = 450 mg/kg (Rat) | > 2000 mg/kg (Rat) | 0.21 mg/L |
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation: Non-irritant (OECD 404 method)
Serious eye damage/eye irritation: Minimal irritant to the eye (OECD 405 method)
Respiratory or skin sensitization:
- Respiratory sensitization: No information available
- It is not a skin sensitizer (OECD 429 method)
Germ cell mutagenicity: AMES test : Negative (OECD 471 method)
Carcinogenicity: Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This classification is given to chemicals, for which there is inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats did not show any association between carbon black and lung tumors. Other ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA.
Reproductive toxicity: No information available
STOT - single exposure: No information available
STOT - repeated exposure: No information available
Aspiration hazard: No information available
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties
Endocrine disrupting properties: No information available.
11.2.2. Other information
Other adverse effects: No information available.
SECTION 12: Ecological information
12.1. Toxicity
The environmental impact of this product has not been fully investigated.
| Chemical name | Algae/aquatic plants | Fish | Toxicity to microorganisms | Crustacea |
|---|---|---|---|---|
| Glycerol | - | LC50: 51 - 57mL/L (96h, Oncorhynchus mykiss) | - | EC50: =84000mg/L (48h, Daphnia magna) |
| Diethylene glycol | - | LC50: =75200mg/L (96h, Pimephales promelas) | EC50 = 29228 mg/L 15 min | EC50: =84000mg/L (48h, Daphnia magna) |
| Carbon Black | - | LC50: =11619mg/L (96h, Pimephales promelas) | - | EC50: >10,000mg/L (48h, Daphnia magna) |
| [2-(2-methoxymethylethoxy)methylethoxy]propanol | - | LC50: 56200 - 63700mg/L (96h, Pimephales promelas) | - | EC50: =42426mg/L (48h, Daphnia magna) |
| 2,2'-(ethylenedioxy)diethanol | - | LC50: =10000mg/L (96h, Lepomis macrochirus) | - | - |
| 1,2,3-benzotriazole | EC50: =15.4mg/L (96h, freshwater algae) | LC50: =39mg/L (96h, Oncorhynchus mykiss) | - | EC50: =141.6mg/L (48h, water flea) |
12.2. Persistence and degradability
Persistence and degradability: No information available.
12.3. Bioaccumulative potential
Bioaccumulation: No information available.
| Component Information | Partition coefficient |
|---|---|
| Glycerol | -1.76 |
| Diethylene glycol | -1.98 |
| 2,2'-(ethylenedioxy)diethanol | -1.98 |
| 1,2-benzisothiazol-3(2H)-one | 0.99 |
12.4. Mobility in soil
Mobility in soil: No information available.
Mobility: No information available.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment: This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
| Chemical name | PBT and vPvB assessment |
|---|---|
| Glycerol | The substance is not PBT / vPvB |
| Diethylene glycol | The substance is not PBT / vPvB |
| Carbon Black | The substance is not PBT / vPvB |
| [2-(2-methoxymethylethoxy)methylethoxy]propanol | The substance is not PBT / vPvB |
| 2,2'-(ethylenedioxy)diethanol | The substance is not PBT / vPvB |
| 1,2,3-benzotriazole | The substance is not PBT / vPvB |
| 1,2-benzisothiazol-3(2H)-one | The substance is not PBT / vPvB |
12.6. Endocrine disrupting properties
Endocrine disrupting properties: No information available.
12.7. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste from residues/unused products: Dispose of in accordance with federal, state and local regulations.
SECTION 14: Transport information
IATA
14.1 UN number or ID number: Not regulated
14.2 UN proper shipping name: Not regulated
14.3 Transport hazard class(es): Not regulated
14.4 Packing group: Not regulated
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: None
IMDG
14.1 UN number or ID number: Not regulated
14.2 UN proper shipping name: Not regulated
14.3 Transport hazard class(es): Not regulated
14.4 Packing group: Not regulated
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: None
14.7 Maritime transport in bulk according to IMO instruments: Not applicable
RID
14.1 UN number or ID number: Not regulated
14.2 UN proper shipping name: Not regulated
14.3 Transport hazard class(es): Not regulated
14.4 Packing group: Not regulated
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: None
ADR
14.1 UN number or ID number: Not regulated
14.2 UN proper shipping name: Not regulated
14.3 Transport hazard class(es): Not regulated
14.4 Packing group: Not regulated
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: None
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National Regulations
France
Occupational Illnesses (R-463-3, France)
| Chemical name | French RG number |
|---|---|
| Diethylene glycol - 111-46-6 | RG 84 |
| Carbon Black - 1333-86-4 | RG 16,RG 16bis |
| [2-(2-methoxymethylethoxy)methylethoxy]propanol - 25498-49-1 | RG 84 |
| 2,2'-(ethylenedioxy)diethanol - 112-27-6 | RG 84 |
| 1,2-benzisothiazol-3(2H)-one - 2634-33-5 | RG 65 |
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work.
Authorizations and/or restrictions on use:
This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
| Chemical name | Restricted substance per REACH Annex XVII | Substance subject to authorization per REACH Annex XIV |
|---|---|---|
| Diethylene glycol - 111-46-6 | Use restricted. See entry 75. | - |
| Carbon Black - 1333-86-4 | Use restricted. See entry 75. | - |
| 1,2-benzisothiazol-3(2H)-one - 2634-33-5 | Use restricted. See entry 75. | - |
Persistent Organic Pollutants: Not applicable
Ozone-depleting substances (ODS) regulation (EC) 1005/2009: Not applicable
EU - Plant Protection Products (1107/2009/EC)
| Chemical name | EU - Plant Protection Products (1107/2009/EC) |
|---|---|
| Carbon Black - 1333-86-4 | Plant protection agent |
| Chemical name | Biocidal Products Regulation (EU) No 528/2012 (BPR) |
|---|---|
| 1,2-benzisothiazol-3(2H)-one - 2634-33-5 | Product-type 2: Disinfectants and algaecides not intended for direct application to humans or animals Product-type 6: Preservatives for products during storage Product-type 9: Fiber, leather, rubber and polymerized materials preservatives Product-type 11: Preservatives for liquid-cooling and processing systems Product-type 12: Slimicides Product-type 13: Working or cutting fluid preservatives |
International Inventories
- TSCA: Complies
- DSL/NDSL: Complies
- EINECS/ELINCS: Complies
- ENCS: Complies
- IECSC: Complies
- KECL: Complies
- PICCS: Complies
- AICS: Complies
- NZIOC: Complies
15.2. Chemical safety assessment
Chemical Safety Report: No chemical safety assessment has been carried out
SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Full text of H-Statements referred to under section 3
- H302 - Harmful if swallowed
- H315 - Causes skin irritation
- H317 - May cause an allergic skin reaction
- H318 - Causes serious eye damage
- H319 - Causes serious eye irritation
- H330 - Fatal if inhaled
- H400 - Very toxic to aquatic life
- H410 - Very toxic to aquatic life with long lasting effects
Legend
SVHC: Substances of Very High Concern for Authorization:
PBT: Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB: Very Persistent and very Bioaccumulative (vPvB) Chemicals
Legend SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
| TWA (time-weighted average) | STEL (Short Term Exposure Limit) | STEL (Short Term Exposure Limit) | Skin designation | |
|---|---|---|---|---|
| TWA | - | - | - | - |
| Ceiling | Ceiling Limit Value | - | - | - |
| * | Sensitizers | - | - | - |
Classification procedure
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | Method Used |
|---|---|
| Acute oral toxicity | On basis of test data |
| Acute dermal toxicity | Calculation method |
| Acute inhalation toxicity - gas | Calculation method |
| Acute inhalation toxicity - vapor | Calculation method |
| Acute inhalation toxicity - dust/mist | Calculation method |
| Skin corrosion/irritation | On basis of test data |
| Serious eye damage/eye irritation | On basis of test data |
| Respiratory sensitization | Calculation method |
| Skin sensitization | On basis of test data |
| Mutagenicity | Calculation method |
| Carcinogenicity | Calculation method |
| Reproductive toxicity | Calculation method |
| STOT - single exposure | Calculation method |
| STOT - repeated exposure | Calculation method |
| Chronic aquatic toxicity | Calculation method |
| Acute aquatic toxicity | Calculation method |
| Aspiration hazard | Calculation method |
| Ozone | Calculation method |
Key literature references and sources for data used to compile the SDS
- Agency for Toxic Substances and Disease Registry (ATSDR)
- U.S. Environmental Protection Agency ChemView Database
- European Food Safety Authority (EFSA)
- European Chemicals Agency (ECHA) Committee for Risk Assessment (ECHA_RAC)
- European Chemicals Agency (ECHA) (ECHA_API)
- EPA (Environmental Protection Agency)
- Acute Exposure Guideline Level(s) (AEGL(s))
- U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
- U.S. Environmental Protection Agency High Production Volume Chemicals
- Food Research Journal
- Hazardous Substance Database
- International Uniform Chemical Information Database (IUCLID)
- National Institute of Technology and Evaluation (NITE)
- Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
- NIOSH (National Institute for Occupational Safety and Health)
- National Library of Medicine's ChemID Plus (NLM CIP)
- National Library of Medicine's PubMed database (NLM PUBMED)
- National Toxicology Program (NTP)
- New Zealand's Chemical Classification and Information Database (CCID)
- Organization for Economic Co-operation and Development Environment, Health, and Safety Publications
- Organization for Economic Co-operation and Development High Production Volume Chemicals Program
- Organization for Economic Co-operation and Development Screening Information Data Set
- World Health Organization
Issuing Date: 09-Apr-2025
Revision date: -
Disclaimer: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
