SAFETY DATA SHEET
Product Information
Product Name: TN-110M, TN-115M, TN-130M, TN-135M, TN-150M, TN-155M, TN-170M, TN-175M, TN-190M, TN-195M Toner
Revision Date: 11-May-2020
Issuing Date: 10-Nov-2012
Revision Number: 3
Safety data sheet number: MT402-02
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product Name: TN-110M, TN-115M, TN-130M, TN-135M, TN-150M, TN-155M, TN-170M, TN-175M, TN-190M, TN-195M Toner
Product Form: Mixture
Safety data sheet number: MT402-02
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: These products are magenta toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and for use in the products stated. Information provided on this SDS is only consistent with the use specified by Brother.
Uses advised against: No information available
1.3. Details of the supplier of the safety data sheet
Manufacturer: Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Importer: Brother International Europe Ltd.
Brother House, 1 Tame Street, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
For further information, please contact:
E-mail address: sds.info@brother.co.jp
1.4. Emergency telephone number
Emergency Telephone: CHEMTREC +1-703-527-3887 (International)
For France only: Antipoison Center telephone number: ORFILA +33-1-45-425-959
Section 2: Hazard(s) identification
2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]
2.2. Label elements
Regulation (EC) No 1272/2008: This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]
2.3. Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
Section 3: Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
| Chemical name | CAS No | EC No | EC Index No | Weight-% | Classification according to Regulation (EC) No. 1272/2008 [CLP] | REACH Registration Number |
|---|---|---|---|---|---|---|
| Styrene-acrylate-copolymer | 25767-47-9 | - | - | 82-86 | Not classified | No data available |
| Fatty acid ester | ** | - | - | 3-7 | Not classified | No data available |
| Pigment | ** | - | - | 2-5 | Not classified | No data available |
| PMMA | 9011-14-7 | - | - | 1-3 | Not classified | No data available |
| Pigment | ** | - | - | 1-3 | Not classified | No data available |
| Silicon dioxide (amorphous) | 112945-52-5 | 231-545-4 | - | <3 | Not classified | No data available |
| Styrene-acrylate Resin | ** | - | - | <2 | Not classified | No data available |
| Silicon dioxide (amorphous) | 844491-94-7 | 430-570-1 | - | <1 | Not classified | No data available |
| Pigment | ** | - | - | <1 | Not classified | No data available |
** CONFIDENTIAL
Full text of H- and EUH-phrases: see section 16
Section 4: First aid measures
4.1. Description of first aid measures
General advice: If symptoms persist, call a physician.
Inhalation: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get immediate medical advice/attention.
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin contact: Take off contaminated clothing. Wash off immediately with soap and plenty of water.
Ingestion: Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to drink.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms:
Inhalation (dust): For large quantities: May cause irritation to the respiratory system. Increased difficulty in breathing. Sneezing. Coughing
Eye contact: May cause eye irritation
Ingestion: May cause stomach ache. Unlikely route of exposure
4.3. Indication of any immediate medical attention and special treatment needed
Note to physicians: Treat symptomatically.
Section 5: Firefighting measures
5.1. Extinguishing media
Suitable Extinguishing Media: Dry chemical, CO2, water spray or regular foam
Unsuitable extinguishing media: Do not use water jet.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical: May form explosive dust clouds in air.
5.3. Advice for firefighters
Special protective equipment for fire-fighters: Do not use high-pressure water in order to prevent creating a dust cloud and spreading fire dust. Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self-contained breathing apparatus (SCBA) during the attack phase of firefighting operations and during cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not having suitable respiratory protection must leave the area to prevent significant exposure to toxic combustion gases from any source.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: Avoid generation of dust. Do not breathe dust. A suitable dust mask or dust respirator with filter type A/P may be appropriate.
For emergency responders: Use personal protection recommended in Section 8.
6.2. Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water drains.
6.3. Methods and material for containment and cleaning up
Methods for containment: Sweep the spilt toner or remove it with a vacuum cleaner and transfer into a sealed container carefully. Sweep slowly to minimize generation of dust during cleanup. If a vacuum cleaner is used, the motor must be rated as dust explosion proof. Potential for very fine particles to be taken into the vacuum only to be passed back into the environment due to pore size in the bag or filter.
Methods for cleaning up: Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
See section 8 for more information. See section 13 for more information.
Section 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling: Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high concentrations of dust. Avoid contact with eyes.
General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions: Keep away from oxidizing agents.
7.3. Specific end use(s)
Specific use(s): These products are magenta toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and for use in the products stated.
Section 8: Exposure controls and personal protection
8.1. Control parameters
| Chemical name | Austria | Switzerland | Poland | Norway | Ireland |
|---|---|---|---|---|---|
| Silicon dioxide (amorphous) 112945-52-5 | TWA: 4 mg/m³ | TWA: 4 mg/m³ | - | - | - |
Derived No Effect Level (DNEL): No information available.
Predicted No Effect Concentration (PNEC): No information available.
8.2. Exposure controls
Appropriate engineering controls: Good general ventilation should be sufficient under normal use.
Personal protective equipment: Not normally required. For use other than in normal operating procedures (such as in the event of large spill), the following should be applied:
Eye/face protection: Safety goggles.
Hand protection: Protective gloves.
Skin and body protection: Long sleeved clothing and long pants.
Respiratory protection: Face Mask. In case of large spillages: Wear suitable respiratory protective equipment.
Environmental exposure controls: Avoid release to the environment.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Physical state: Solid Powder
Color: magenta
Odor: Odorless.
Odor threshold: No information available
Property
- pH: Not applicable
- Melting point / freezing point: 110 °C
- Flash point: Not applicable
- Boiling point / boiling range: Not applicable
- Evaporation rate: Not applicable
- Flammability (solid, gas): Not applicable
- Flammability Limit in Air: None known
- Upper flammability limit: No data available
- Lower flammability limit: 95 - 100 g/m³
- Vapor pressure: Not applicable
- Vapor density: Not applicable
- Relative density: 1.15 (H2O=1)
Water solubility: Insoluble in water
Solubility(ies): No data available
Partition coefficient: No data available
Autoignition temperature: None known
Decomposition temperature: No data available
Kinematic viscosity: None known
Dynamic viscosity: Not applicable
Explosive properties: Explosive limits of toner particles suspended in air approximately equal to that of coal dust
Oxidizing properties: No information available
9.2. Other information
No information available
Section 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No information available.
10.4. Conditions to avoid
Keep away from heat. Avoid friction, sparks, or other means of ignition
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx)
Section 11: Toxicological information
11.1. Information on toxicological effects
Product Information: This assessment is based on information available on similar products
Inhalation: No information available
Eye contact: No information available
Skin contact: No information available
Ingestion: No information available
The following values are calculated based on chapter 3.1 of the GHS document:
ATEmix (oral): 5,266.70 mg/kg
Skin corrosion/irritation: No information available
Serious eye damage/eye irritation: No information available
Respiratory or skin sensitization: No information available
Germ cell mutagenicity: AMES test: Negative (OECD 471 method)
Carcinogenicity: Ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA
Section 12: Ecological information
12.1. Toxicity
Ecotoxicity: The environmental impact of this product has not been fully investigated.
Contains 0 % of components with unknown hazards to the aquatic environment.
12.2. Persistence and degradability
No information available.
12.3. Bioaccumulative potential
No information available.
12.4. Mobility in soil
No information available.
12.5. Results of PBT and vPvB assessment
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
12.6. Other adverse effects
No information available.
Section 13: Disposal considerations
13.1. Waste treatment methods
Do not put toner or toner cartridges into a fire, this can cause fire to spread with the risk of causing burn injuries. Shred toner cartridges in a dust/explosion controlled environment. Finely dispersed particles may form explosive mixtures in the air. Dispose of in accordance with Federal, State, and local regulations.
Section 14: Transport Information
IMDG
- 14.1 UN/ID no: Not regulated
- 14.2 Proper shipping name: Not regulated
- 14.3 Hazard Class: Not regulated
- 14.4 Packing group: Not regulated
- 14.5 Marine pollutant: Not applicable
- 14.6 Special Provisions: None
- 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
RID
- 14.1 UN/ID no: Not regulated
- 14.2 Proper shipping name: Not regulated
- 14.3 Hazard Class: Not regulated
- 14.4 Packing group: Not regulated
- 14.5 Environmental hazard: Not applicable
- 14.6 Special Provisions: None
ADR
- 14.1 UN/ID no: Not regulated
- 14.2 Proper shipping name: Not regulated
- 14.3 Hazard Class: Not regulated
- 14.4 Packing group: Not regulated
- 14.5 Environmental hazard: Not applicable
- 14.6 Special Provisions: None
IATA
- 14.1 UN/ID no: Not regulated
- 14.2 Proper shipping name: Not regulated
- 14.3 Hazard Class: Not regulated
- 14.4 Packing group: Not regulated
- 14.5 Environmental hazard: Not applicable
- 14.6 Special Provisions: None
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU-Regulations:
- Contains no substances listed in REACH Regulation (EC) No.1907/2006 ANNEX XVII.
- Contains no substance listed in REACH Regulation (EC) No.1907/2006 Candidate List for Authorization.
- Contains no substances listed in REACH Regulation (EC) No.1907/2006 ANNEX XIV.
National Regulations:
No information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
Section 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend:
SVHC: Substances of Very High Concern for Authorization:
- TWA: TWA (time-weighted average)
- STEL: STEL (Short Term Exposure Limit)
- **: Trade secret
Key literature references and sources for data
No information available
Revision Date:
11-May-2020
Issuing Date:
10-Nov-2012
Revision Note:
No information available
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
Disclaimer
The information relates only to this product. It may not be valid, if used in combination with any other materials or in any other process, and it is based on our best knowledge as of the date of preparation (revision).
