Bosch Lead Acid Battery Automotive and Marine (Maintenance Free and Accessible) - Safety Data Sheet

1. Identification of the Material and Supplier

1.1 Product identifier

Product name: LEAD ACID BATTERY AUTOMOTIVE AND MARINE (MAINTENANCE FREE AND ACCESSIBLE)

Synonyms: DEEP CYCLE; DEEP CYCLE MARINE; HIGH CYCLE MARINE; MINING HEAVY DUTY • SM MEGA POWER; SM MEGA POWER PLUS; SM MEGA POWER SILVER • SMT MEGA POWER; SMT MEGA POWER PLUS; SMT MEGA POWER SILVER • ST HIGHTEC AGM; ST HIGHTEC EFB

1.2 Uses and uses advised against

Uses: AUTOMOTIVE APPLICATIONS • BATTERIES • COMMERCIAL APPLICATIONS • INDUSTRIAL APPLICATIONS • MARINE APPLICATIONS

1.3 Details of the supplier of the product

Supplier name: ROBERT BOSCH AUSTRALIA PTY LTD

Address: 1555 Centre Rd, Clayton, VIC, 3168, AUSTRALIA

Telephone: (03) 9541 5555

Fax: (03) 9541 5595

Website: www.bosch.com.au

1.4 Emergency telephone numbers

Emergency: 13 11 26 (24/7 Poisons Information Hotline)

2. Hazards Identification

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

2.1 Classification of the substance or mixture

Physical Hazards:

• Corrosive to Metals: Category 1
• In use, may form flammable/explosive vapour-air mixture.

Health Hazards:

• Acute Toxicity: Oral: Category 4
• Skin Corrosion/Irritation: Category 1A
• Serious Eye Damage / Eye Irritation: Category 1
• Acute Toxicity: Inhalation: Category 4
• Toxic to Reproduction: Category 1A
• Specific Target Organ Toxicity (Repeated Exposure): Category 2

Environmental Hazards:

• Aquatic Toxicity (Chronic): Category 1

2.2 GHS Label elements

Signal word: DANGER

Pictograms:

• [Corrosive symbol]
• [Exclamation mark symbol]
• [Health hazard symbol]
• [Environment hazard symbol]

Hazard statements

• H290: May be corrosive to metals.
• H302: Harmful if swallowed.
• H314: Causes severe skin burns and eye damage.
• H318: Causes serious eye damage.
• H332: Harmful if inhaled.
• H360: May damage fertility or the unborn child.
• H373: May cause damage to organs through prolonged or repeated exposure.
• H410: Very toxic to aquatic life with long lasting effects.

Prevention statements

• P201: Obtain special instructions before use.
• P202: Do not handle until all safety precautions have been read and understood.
• P234: Keep only in original container.
• P260: Do not breathe dust/fume/gas/mist/vapours/spray.
• P264: Wash thoroughly after handling.
• P270: Do not eat, drink or smoke when using this product.
• P271: Use only outdoors or in a well-ventilated area.
• P273: Avoid release to the environment.
• P280: Wear protective gloves/protective clothing/eye protection/face protection.

Response statements

• P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
• P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
• P304 + P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
• P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P308 + P313: IF exposed or concerned: Get medical advice/attention.
• P310: Immediately call a POISON CENTER or doctor/physician.
• P321: Specific treatment is advised - see first aid instructions.
• P363: Wash contaminated clothing before reuse.
• P390: Absorb spillage to prevent material damage.
• P391: Collect spillage.

Storage statements

• P405: Store locked up.
• P406: Store in corrosive resistant container with a resistant inner liner.

Disposal statements

• P501: Dispose of contents/container in accordance with relevant regulations.

2.3 Other hazards

No hazards occur during the normal operation of a lead acid battery as it is described in the instructions for use that are provided with the battery. Lead-acid batteries have three significant characteristics:

• They contain an electrolyte which contains dilute sulphuric acid. Sulphuric acid may cause severe chemical burns.
• During the charging process or during operation they might develop hydrogen gas and oxygen, which under certain circumstances may result in an explosive mixture.
• They can contain a considerable amount of energy, which may be a source of high electrical current and a severe electrical shock in the event of a short circuit.

3. Composition/Information on Ingredients

4. First Aid Measures

4.1 Description of first aid measures

Eye: Exposure to contents: If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.

Inhalation: Exposure to contents: If inhaled, remove from contaminated area. To protect rescuer, use a Type B (Inorganic and acid gas) respirator where an inhalation risk exists. Apply artificial respiration if not breathing.

Skin: Exposure to contents: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Ingestion: For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink.

First aid facilities: Eye wash facilities and safety shower should be available.

4.2 Most important symptoms and effects, both acute and delayed

The electrolyte is corrosive and may cause irritation or severe chemicals burns. Lead is a cumulative poison and has the potential to cause chronic health effects. Chronic exposure may result in blood, kidney and central nervous system/brain damage. Lead is classified as possibly carcinogenic to humans (IARC Group 2B). May cause harm to the unborn child. Possible risk of impaired fertility.

4.3 Immediate medical attention and special treatment needed

Treat symptomatically.

5. Fire Fighting Measures

5.1 Extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

5.2 Special hazards arising from the substance or mixture

Non flammable. Liquid component may evolve flammable hydrogen gas upon contact with metals. The potential for fire - explosion does exist through short circuit of terminals. Thermal shock may cause battery case to crack open. May explode if exposed to high temperatures due to pressure build up in battery casing.

5.3 Advice for firefighters

Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

5.4 Hazchem code

2R

2

Fine Water Spray.

R

Wear liquid-tight chemical protective clothing and breathing apparatus. Dilute spill and run-off.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Contact emergency services where appropriate.

6.2 Environmental precautions

Prevent product from entering drains and waterways.

6.3 Methods of cleaning up

Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.

6.4 Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

7. Handling and Storage

7.1 Precautions for safe handling

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. Batteries evolve flammable hydrogen gas during charging and may increase fire risk in poorly ventilated areas near sparks, excessive heat or open flames.

7.2 Conditions for safe storage, including any incompatibilities

Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate ventilation systems.

8. Exposure Controls / Personal Protection

8.1 Control parameters

Exposure standards

Biological limits

Reference: ACGIH Biological Exposure Indices

8.2 Exposure controls

Engineering controls: Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.

PPE:

• Eye / Face: Wear safety glasses. [ eyeglasses ]
• Hands: Wear PVC or rubber gloves. [ gloves ]
• Body: Wear safety boots. [ boots ]
• Respiratory: Where an inhalation risk exists, wear a Type B (Inorganic gases and vapours) respirator.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

• Appearance: LIQUID (BATTERY ENCLOSED)
• Odour: ODOURLESS
• Flammability: NON FLAMMABLE
• Flash point: NOT RELEVANT
• Boiling point: NOT AVAILABLE
• Melting point: NOT AVAILABLE
• Evaporation rate: NOT AVAILABLE
• pH: < 4
• Vapour density: NOT AVAILABLE
• Specific gravity: NOT AVAILABLE
• Solubility (water): INSOLUBLE
• Vapour pressure: NOT AVAILABLE
• Upper explosion limit: NOT RELEVANT
• Lower explosion limit: NOT RELEVANT
• Partition coefficient: NOT AVAILABLE
• Autoignition temperature: NOT AVAILABLE
• Decomposition temperature: > 100°C
• Viscosity: NOT AVAILABLE
• Explosive properties: NOT AVAILABLE
• Oxidising properties: NOT AVAILABLE
• Odour threshold: NOT AVAILABLE

10. Stability and Reactivity

10.1 Reactivity

If damaged, contents may be corrosive to metals.

10.2 Chemical stability

Stable under recommended conditions of storage.

10.3 Possibility of hazardous reactions

Hazardous polymerisation is not expected to occur.

10.4 Conditions to avoid

Avoid heat, sparks, open flames and other ignition sources. Avoid prolonged overcharging.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites), alkalis (e.g. sodium hydroxide), heat and ignition sources. Incompatible with acids (e.g. nitric acid), acid chlorides, acid anhydrides and chloroformates.

10.6 Hazardous decomposition products

May evolve toxic gases if heated to decomposition.

11. Toxicological Information

11.1 Information on toxicological effects

Acute toxicity: Exposure to battery contents may result in severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach. Lead compounds are expected to be harmful if swallowed, in contact with skin, and/or if inhaled.

Information available for the ingredients:

Skin: Due to product encapsulation, the potential for skin contact with contents is reduced. If the container is damaged, contact may result in irritation, redness, pain, rash, dermatitis and possible burns. Effects may be delayed.

Eye: Due to product encapsulation, the potential for eye contact with contents is reduced. If the container is damaged, direct contact may result in irritation, lacrimation and burns.

Sensitisation: Not classified as causing skin or respiratory sensitisation.

Mutagenicity: Not classified as a mutagen.

Carcinogenicity: Due to product encapsulation, the potential for exposure to the contents is reduced. Occupational exposure to strong inorganic acid mists containing sulphuric acid is classified as carcinogenic to humans (IARC Group 1). Lead compounds (inorganic) are classified as probably carcinogenic to humans (IARC Group 2A).

Reproductive: Due to product encapsulation, the potential for exposure to the contents is reduced. Exposure to high levels of lead and its compounds may cause adverse effects on male and female fertility, including adverse effects on sperm quality. Prenatal exposure to lead and its compounds is also associated with adverse effects on neurobehavioral development in children.

STOT - single exposure: Due to product encapsulation, the potential for exposure is unlikely. If the container is damaged, inhalation may result in mucous membrane irritation of the respiratory tract, coughing and inflammation. High level exposure may result in ulceration of the respiratory tract and lung tissue damage.

STOT - repeated exposure: Due to product encapsulation, the potential for exposure to the contents is reduced. Lead is a cumulative poison and may be absorbed into the body through ingestion or inhalation. Lead has been documented in observational human studies to produce toxicity in multiple organ systems and body function including the haematopoietic (blood) system, kidney function, reproductive function and the central nervous system.

Aspiration: Not classified as causing aspiration.

12. Ecological Information

12.1 Toxicity

Lead is potentially toxic to all aquatic organisms, with organic lead compounds tending to be more toxic than inorganic lead compounds. Lead becomes more toxic to fish as dissolved oxygen levels decrease. Toxicity to aquatic organisms increases in acidic or soft water. Very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability

Inorganic lead does not degrade.

12.3 Bioaccumulative potential

Lead bioconcentrates and bioaccumulates in both aquatic and terrestrial organisms.

12.4 Mobility in soil

Lead is sparingly soluble and is expected to be adsorbed onto soils and sediments. Mobility is expected to be low.

12.5 Other adverse effects

No information provided.

13. Disposal Considerations

13.1 Waste treatment methods

Waste disposal: This product is recyclable. Please return to manufacturer. Contact the manufacturer/supplier for additional information (if required).

Legislation: Dispose of in accordance with relevant local legislation.

14. Transport Information

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

14.6 Special precautions for user

Hazchem code: 2R

GTEPG: 8A1

EMS: F-A, S-B

Other information: Limited quantity (LQ) exception is possible.

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule: Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).

Classifications: Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals.

Inventory listings: AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.

16. Other Information

Additional information

RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.

ACIDS: When mixing acids with water (diluting), caution must be taken as heat will be generated which causes violent spattering. Always add a small volume of acid to a large volume of water, NEVER the reverse.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

Abbreviations:

• ACGIH: American Conference of Governmental Industrial Hygienists
• CAS #: Chemical Abstract Service number - used to uniquely identify chemical compounds
• CNS: Central Nervous System
• EC No.: EC No - European Community Number
• EMS: Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)
• GHS: Globally Harmonized System
• GTEPG: Group Text Emergency Procedure Guide
• IARC: International Agency for Research on Cancer
• LC50: Lethal Concentration, 50% / Median Lethal Concentration
• LD50: Lethal Dose, 50% / Median Lethal Dose
• mg/m³: Milligrams per Cubic Metre
• OEL: Occupational Exposure Limit
• pH: relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
• ppm: Parts Per Million
• STEL: Short-Term Exposure Limit
• STOT-RE: Specific target organ toxicity (repeated exposure)
• STOT-SE: Specific target organ toxicity (single exposure)
• SUSMP: Standard for the Uniform Scheduling of Medicines and Poisons
• SWA: Safe Work Australia
• TLV: Threshold Limit Value
• TWA: Time Weighted Average

Report status

This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by:

Risk Management Technologies
5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: info@rmt.com.au
Web: www.rmtglobal.com

[ End of SDS ]