UNILAK Satin Black - Safety Data Sheet

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name: UNILAK SATIN BLACK

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.3 Details of the supplier of the safety data sheet

Akzo Nobel Coatings, S.L.U.
C/ Feixa LLarga 14-20
08040 Barcelona, España
Tel. (34).93.484.25.00
www.titanlux.pt

Email address of the competent person responsible for this SDS: HSE_ES@akzonobel.com

1.4 Emergency telephone number

National poison centre/National chemical emergency centre
Telephone number: (+351) 800 250 250

Section 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition: Mixture

Classification according to Regulation (EC) 1272/2008 [CLP/GHS]: Not classified.

The product is not classified as hazardous according to Regulation (EC) 1272/2008, with amendments. See Section 11 for detailed information on symptoms and health effects.

2.2 Label elements

Signal word: No signal word.

Hazard statements: Has not shown significant effects or critical risks.

Precautionary statements:

• General: P102 - Keep out of reach of children.
• Prevention: P101 - If medical advice is needed, have product container or label at hand. P262 - Do not get in eyes, on skin, or on clothing.
• Response: P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
• Storage: Not applicable.
• Disposal: P501 - Dispose of contents/container in accordance with local and national regulations.

Supplemental labelling elements: Contains adipohydrazide, 1,2-benzisothiazol-3(2H)-one and CMIT/MIT(3:1). May produce an allergic reaction.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles: Not applicable.

Special packaging requirements:

• Child-resistant fastenings: Not applicable.
• Tactile warning of danger: Not applicable.

2.3 Other hazards

The substance meets the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII: This mixture does not contain any substance that is assessed to be PBT or vPvB.

Other hazards which do not result in classification: None known.

Section 3: Composition/information on ingredients

3.2 Mixtures

Mixture

Consult Section 16 to obtain the full text of the H statements referred to herein.

There is no additional ingredient present which, within the current knowledge of the supplier and in the applicable concentrations, is classified as hazardous to health or the environment, is PBT or vPvB, or has been assigned an exposure limit and is therefore required to be reflected in this section.

[1] Substance classified with a physical, environmental and health hazard.

Occupational exposure limit(s), if available, are indicated in Section 8.

Section 4: First aid measures

4.1 Description of first aid measures

• Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse. Get medical attention if irritation occurs.
• Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if symptoms occur.
• Skin contact: Wash skin contaminated with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
• Ingestion: Wash out mouth with water. If material has been swallowed and the person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
• Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms/effects of exposure:

• Eye contact: No specific data.
• Inhalation: No specific data.
• Skin contact: No specific data.

Ingestion: No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

• Notes to physician: Treat symptomatically. Contact a poison specialist if large quantities have been ingested or inhaled.
• Specific treatments: No specific treatment.

Section 5: Firefighting measures

5.1 Suitable extinguishing media

Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media: None known.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or mixture: In case of fire or heating, an increase in pressure will occur and the container may burst.

Hazardous combustion products: Decomposition products may include the following materials: carbon dioxide, carbon monoxide

5.3 Advice for firefighters

• Special protective actions for firefighters: Immediately evacuate people from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
• Special protective equipment for firefighters: Firefighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Firefighter's protective clothing (including helmets, protective boots and gloves) in accordance with European standard EN 469 will provide a basic level of protection in the event of chemical incidents.

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

• For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. DO NOT walk through spilled material. Wear appropriate personal protective equipment.
• For emergency responders: If specialised equipment is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Also refer to information in the paragraph for "Non-emergency personnel".

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product causes environmental pollution (sewers, waterways, soil or air).

6.3 Methods and material for containment and cleaning up

Small spills: Stop leak if without risk. Remove containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in a suitable, labelled container for disposal. Dispose of via a licensed waste disposal contractor.

Large spills: Stop leak if without risk. Remove containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite or diatomaceous earth and place in a suitable, labelled container for disposal according to local legislation. Dispose of via a licensed waste disposal contractor.

6.4 Reference to other sections

Consult Section 1 for emergency contact information. Consult Section 8 for appropriate personal protective equipment. Consult Section 13 for further information on waste treatment.

Section 7: Handling and storage

The information in this section contains generic advice and guidance.

7.1 Precautions for safe handling

• Protective measures: Use appropriate personal protective equipment (see Section 8).
• General advice on hygiene: Eating, drinking and smoking should be prohibited in areas where this product is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Also refer to Section 8 for further information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in the original container protected from sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unmarked containers. Use an appropriate container to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

7.3 Specific end use(s)

• Recommendations: Not available.
• Specific solutions for the industry sector: Not available.

Section 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on the typical intended uses of the product. Additional measures may be required for bulk handling or other uses that may significantly increase worker exposure or environmental releases.

8.1 Control parameters

Occupational exposure limits: No exposure limit value known.

DNELS/DMELS

PNEC

8.2 Exposure controls

• Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
• Personal protective equipment:

Hygiene measures:

Wash hands, forearms and face thoroughly after handling chemical products, before eating, using the lavatory and smoking and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before re-use. Ensure eyewash stations and safety showers are close to the workstation.

Eye/face protection:

Safety glasses with a side-shield conforming to an approved standard should be used where a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be used, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Skin protection:

• Hand protection: Chemical-resistant, impervious gloves suitably protected against chemicals should be worn at all times when handling chemical products and when the risk assessment indicates this is necessary. For prolonged or repeated contact, the use of class 6 protective gloves (penetration time > 480 minutes, according to EN374) is recommended. Recommended gloves: Viton® or nitrile, thickness ≥ 0.38 mm. For brief contact, the use of class 2 or higher protective gloves (penetration time > 30 minutes, according to EN374) is recommended. Recommended gloves: Nitrile, thickness ≥ 0.12 mm. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Glove performance or effectiveness may be reduced by physical/chemical damage or lack of maintenance. The user should verify that the final choice of glove type for handling this product is the most suitable and takes into account their particular conditions of use as indicated in the user's risk assessment.
• Body protection: Personal protective equipment for the body should be selected according to the task being performed and the risks involved and should be approved by a specialist prior to handling this product.
• Other skin protection: Suitable footwear and any other skin protection measures should be selected based on the task to be performed and the risks involved, and should be approved by a specialist before handling this product.
• Respiratory protection: Based on the hazard and potential for exposure, select a respirator that complies with the appropriate standard or certification. Respirators must be worn in accordance with a respiratory protection program to ensure proper fitting, training and other important aspects of use. Use a respirator in accordance with EN140 with an A/P2 type filter or better. Dry sanding, cutting and/or welding of dry paint film generates dust and/or noxious fumes. Wherever possible, dry sanding should be avoided or wet sanded. If exposure cannot be avoided by the provision of local exhaust ventilation, respiratory protective equipment should be used. Wear a approved and certified disposable particulate respirator.

Environmental exposure controls:

Emissions from ventilation or work process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the equipment will be necessary to reduce emissions to acceptable levels.

Section 9: Physical and chemical properties

The conditions of measurement of all properties are at normal temperature and pressure unless otherwise indicated.

9.1 Basic physical and chemical properties

• Appearance:
  Physical state: Liquid.
• Colour: Black.
• Odour: Characteristic.
• Odour threshold: Not available.
• Melting point/freezing point: Not available.
• Boiling point, initial boiling point and boiling range: 100°C (212°F)
• Flammability: Not available.
• Upper/lower flammability or explosive limits: Upper: 12.6% (propane-1,2-diol), Lower: 2.6% (propane-1,2-diol)
• Flash point: Closed cup: Not applicable. [Pensky-Martens]
• Auto-ignition temperature:
  Ingredient name: propane-1,2-diol
  °C: 371
  °F: 699.8
  Method:
• Decomposition temperature: Not available.
• pH: 9 [Conc. (% p/p): 1%] [DIN EN 1262]
• Viscosity: Kinematic (ambient temperature): 1538 mm²/s [DIN EN ISO 3219] Kinematic (40°C): Not applicable. [DIN EN ISO 3219]
• Solubility(ies):
  Media: cold water
  Result: Soluble [OECD (TG 105)]
• Partition coefficient: n-octanol/water: Not applicable.
• Vapour pressure:
  Vapour pressure at 20 °C: mm Hg: 0.15, kPa: 0.02, Method: EU A.4
  Vapour pressure at 50 °C: mm Hg: , kPa: , Method:
• Relative density: 1.041
• Vapour density: Not available.
• Particle characteristics:
  Median particle size: Not applicable.
  Percentage of particles with aerodynamic diameter ≤ 10 μm: 0
• Minimum ignition energy (mJ): Not available.

Section 10: Stability and reactivity

10.1 Reactivity

No specific test data related to reactivity is available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

No specific data.

10.5 Incompatible materials

No specific data.

10.6 Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products are not expected to be generated.

Section 11: Toxicological information

11.1 Information on toxicological effects

No data is available for the mixture itself. The mixture has been assessed according to the conventional method of the CLP Regulation (EC) No 1272/2008 and is classified accordingly, with respect to toxicological properties. Consult Chapters 2 and 3 for more information.

Acute toxicity:

Acute toxicity estimates:

Irritation/Corrosion:

Conclusion/Summary: Not available.

Sensitisation:

Conclusion/Summary: Not available.

Mutagenicity:

Conclusion/Summary: Not available.

Carcinogenicity:

Conclusion/Summary: Not available.

Reproductive toxicity:

Conclusion/Summary: Not available.

Teratogenicity:

Conclusion/Summary: Not available.

Specific Target Organ Toxicity - Single exposure:

Not available.

Specific Target Organ Toxicity - Repeated exposure:

Not available.

Aspiration hazard:

Not available.

Information on likely routes of exposure:

Not available.

Potential Acute Health Effects:

• Eye contact: Has not shown significant effects or critical risks.
• Inhalation: Has not shown significant effects or critical risks.
• Skin contact: Has not shown significant effects or critical risks.
• Ingestion: Has not shown significant effects or critical risks.

Symptoms related to the physical, chemical and toxicological characteristics:

• Eye contact: No specific data.
• Inhalation: No specific data.
• Skin contact: No specific data.
• Ingestion: No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure:

• Short term exposure:
  Potential immediate effects: Not available.
  Potential delayed effects: Not available.
• Long term exposure:
  Potential immediate effects: Not available.
  Potential delayed effects: Not available.

Potential Chronic Health Effects:

Not available.

Conclusion/Summary: Not available.

General: Has not shown significant effects or critical risks.

Carcinogenicity: Has not shown significant effects or critical risks.

Mutagenicity: Has not shown significant effects or critical risks.

Reproductive toxicity: Has not shown significant effects or critical risks.

Section 12: Ecological information

11.2 Other information

11.2.1 Endocrine disrupting properties

Not available.

11.2.2 Other information

No further information.

12.1 Toxicity

No data is available for the mixture itself. Do not allow to enter drains or watercourses. The mixture has been assessed according to the accumulation method of the CLP Regulation (EC) No 1272/2008 and is not classified as hazardous to the environment, but it contains substance(s) hazardous to the environment. Consult Section 3 for details.

12.2 Persistence and degradability:

Conclusion/Summary: Not available.

12.3 Bioaccumulative potential:

Not available.

12.4 Mobility in soil:

• Partition coefficient: soil/water (Koc): Not available.
• Mobility: Not available.

12.5 Results of PBT and vPvB assessment:

This mixture does not contain any substance that is assessed to be PBT or vPvB.

12.6 Endocrine disrupting properties:

Not available.

12.7 Other adverse effects:

Has not shown significant effects or critical risks.

Section 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of identified uses in Section 1 should be consulted to verify if there is any information relating to use indicated in the exposure scenario(s).

13.1 Waste treatment methods

Product:

• Disposal methods: Waste generation should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the environmental protection requirements and local/national waste disposal legislation. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of without treatment to sewer unless fully compliant with the requirements of the local authorities.
• Hazardous waste: According to the supplier's information, this product is not considered hazardous waste as defined by EU Directive 2008/98/EC.
• Disposal considerations: Do not allow to enter drains or watercourses. Dispose of in accordance with applicable federal, state and local regulations. If this product is mixed with other wastes, the original waste code may no longer apply and a new code should be assigned. For further information, contact the local waste authority.
• European Waste Catalogue (EWC): The classification of this product when disposed of as waste, according to the European Waste Catalogue, is:
  Waste code: EWC 08 01 12
  Waste designation: waste paints and varnishes not containing dangerous substances

Packaging:

• Disposal methods: Waste generation should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered if recycling is not feasible.
• Disposal considerations: Using the information provided in this safety data sheet, recommendations should be obtained from the waste disposal authority regarding the classification of empty containers. Empty containers must be denatured or reconditioned. Dispose of containers contaminated by the product in accordance with local or national legal provisions.
• Special precautions: Do not dispose of this product and its container in accordance with local or national legal provisions. Empty containers or liners may retain some product residue. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Section 14: Transport information

14.6 Special precautions for user

Transport within user's premises: always transport in closed containers that are secured and upright. Ensure persons transporting the product know what to do in case of an accident or spillage.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code:

Not applicable.

Section 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulation (EC) No 1907/2006 (REACH)

• Annex XIV - List of substances subject to authorisation:
  Annex XIV: None of the components are included in any list.
• Substances of very high concern: None of the components are included in any list.
• Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles: Not applicable.

Other EU regulations:

• VOC:
  VOC for ready-to-use mixtures: The provisions of Directive 2004/42/EC on VOCs apply to this product. Refer to the product label and/or technical data sheet for further information.
• Industrial emissions (prevention and control of pollution) - Air: Not available.
• Industrial emissions (prevention and control of pollution) - Water: Not listed.

Substances that deplete the ozone layer (1005/2009/EU): Not listed.

Prior Informed Consent (PIC) (649/2012/EU): Not listed.

Persistent organic pollutants: Not listed.

15.2 Chemical safety assessment:

No Chemical Safety Assessment has been carried out.

Section 16: Other information

Indicate information that has changed from the previous version.

Abbreviations and acronyms:

ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DMEL = Derived Minimum Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
mPmB = very Persistent and very Bioaccumulative

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Full text of abbreviated H statements:

• H301: Toxic if swallowed.
• H302: Harmful if swallowed.
• H310: Fatal in contact with skin.
• H314: Causes severe skin burns and eye damage.
• H315: Causes skin irritation.
• H317: May cause an allergic skin reaction.
• H318: Causes serious eye damage.
• H330: Fatal if inhaled.
• H400: Very toxic to aquatic life.
• H410: Very toxic to aquatic life with long lasting effects.
• H411: Toxic to aquatic life with long lasting effects.
• EUH071: Corrosive to the respiratory tract.

Full text of classifications [CLP/GHS]:

• Acute Tox. 2: ACUTE TOXICITY - CATEGORY 2
• Acute Tox. 3: ACUTE TOXICITY - CATEGORY 3
• Acute Tox. 4: ACUTE TOXICITY - CATEGORY 4
• Aquatic Acute 1: HAZARD TO THE AQUATIC ENVIRONMENT (ACUTE) - CATEGORY 1
• Aquatic Chronic 1: HAZARD TO THE AQUATIC ENVIRONMENT (CHRONIC) - CATEGORY 1
• Aquatic Chronic 2: HAZARD TO THE AQUATIC ENVIRONMENT (CHRONIC) - CATEGORY 2
• Eye Dam. 1: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1
• Skin Corr. 1C: SKIN CORROSION/IRRITATION - CATEGORY 1C
• Skin Irrit. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
• Skin Sens. 1: SKIN SENSITISATION - CATEGORY 1
• Skin Sens. 1A: SKIN SENSITISATION - CATEGORY 1A

Date of printing: 28-5-2025

Date of release/Revision date: 14-4-2024

Previous edition date: 14-4-2024

Version: 1

Unique ID: D2A5A60AAB0B1EEEAF903B9907B00532

Reader's notice:

IMPORTANT NOTICE: The information in this document is based on our current knowledge and the laws in force. Any user who uses the product for a purpose other than that specifically recommended in the technical bulletin, without first obtaining our written confirmation of the product's suitability for the intended purpose, assumes the risk of this procedure. The user is always responsible for taking all necessary precautions to comply with local standards and legislation requirements. Always read the Material Safety Data Sheet and the Technical Bulletin for this product. All recommendations or statements about the product (in this information sheet or in another document) are correct according to our best current knowledge, but we have no control over the quality or conditions of the substrate or many other factors affecting the use and application of the product. However, unless specifically attested by us otherwise, we do not accept any liability for the product's performance or for any loss or damage arising from its use. All products supplied and recommendations made are subject to our standard terms and conditions of sale. The user should request a copy of this document and review it carefully. The content of this information sheet is subject to periodic modification based on our experience and continuous development policy. The user is responsible for verifying that this information sheet is up-to-date before using the product.

Trade names mentioned in this information sheet are registered trademarks licensed to or belonging to Akzo Nobel.