3M Science. Applied to Life. 3M United States
Datasheet for 3M models including: 3M, Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500
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DocumentDocument3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Safety Data Sheet Copyright,2021, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: Issue Date: 16-3092-0 04/08/21 Version Number: Supercedes Date: 16.00 07/25/18 SECTION 1: Identification 1.1. Product identifier 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 Product Identification Numbers 60-4100-0946-2, 60-4100-0947-0, 60-4100-0967-8, 60-9800-4300-8, 60-9801-0556-7, 60-9801-0843-9, 62-5225-5236-3, 625239-5230-7 7000000623, 7000120525, 7010325699, 7000118401, 7010325697, 7010291349 1.2. Recommended use and restrictions on use Recommended use Marine Adhesive Sealant, One-part Polyurethane Adhesive for Marine Applications. This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(13)) for consumer paint or coating removal 1.3. Supplier's details MANUFACTURER: DIVISION: ADDRESS: Telephone: 3M Industrial Adhesives and Tapes Division Marine & Specialty Vehicle 3M Center, St. Paul, MN 55144-1000, USA 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Acute Toxicity (inhalation): Category 4. Respiratory Sensitizer: Category 1A. Skin Sensitizer: Category 1A. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 1B. 2.2. Label elements Signal word Danger __________________________________________________________________________________________ Page 1 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Symbols Exclamation mark | Health Hazard | Pictograms Hazard Statements May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Harmful if inhaled. May damage fertility or the unborn child. May cause cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. In case of inadequate ventilation wear respiratory protection. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Supplemental Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Urethane Polymer 68611-34-7 30 - 60 Trade Secret * Talc 14807-96-6 15 - 40 Trade Secret * Titanium Dioxide 13463-67-7 5 - 10 Trade Secret * Carbitol Acetate 112-15-2 1 - 5 Trade Secret * __________________________________________________________________________________________ Page 2 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Fumed Silica Zinc Oxide Alkyl Isocyanate Silane Toluene Diisocyanate Toluene Heptane (Gamma-Mercaptopropyl)trimethoxysilane Hexamethylene Diisocynate Methylene Chloride 112945-52-5 1314-13-2 85702-90-5 26471-62-5 108-88-3 142-82-5 4420-74-0 822-06-0 75-09-2 0.5 - 5 Trade Secret * < 2.5 Trade Secret * 0.5 - 1.5 Trade Secret * < 1 Trade Secret * < 0.5 Trade Secret * < 0.23 Trade Secret * < 0.19 Trade Secret * < 0.015 Trade Secret * < 0.01 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic respiratory reaction (difficulty breathing, wheezing, cough, and tightness of chest). Allergic skin reaction (redness, swelling, blistering, and itching). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Isocyanates Carbon monoxide Carbon dioxide Hydrogen Cyanide Irritant Vapors or Gases Oxides of Nitrogen Oxides of Sulfur Condition During Combustion During Combustion During Combustion During Combustion During Combustion During Combustion During Combustion __________________________________________________________________________________________ Page 3 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up residue. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Keep cool. Protect from sunlight. Store away from heat. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin, Ototoxicant Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm SILICA, AMORPHOUS 112945-52- OSHA TWA:20 millions of 5 particles/cu. ft.;TWA concentration:0.8 mg/m3 Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2 mg/m3;STEL(respirable fraction):10 mg/m3 Zinc Oxide 1314-13-2 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3;TWA(as __________________________________________________________________________________________ Page 4 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 fume):5 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) Talc 14807-96-6 ACGIH TWA(respirable fraction):2 A4: Not class. as human mg/m3 carcin Talc 14807-96-6 OSHA TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Toluene Diisocyanate 26471-62-5 ACGIH TWA(inhalable fraction and A3: Confirmed animal vapor):0.001 carcin., ppm;STEL(inhalable fraction Dermal/Respiratory and vapor):0.005 ppm Sensitizer Methylene Chloride 75-09-2 ACGIH TWA:50 ppm A3: Confirmed animal carcin. Methylene Chloride 75-09-2 OSHA TWA:25 ppm;STEL:125 ppm 29 CFR 1910.1052, SKIN Hexamethylene Diisocynate 822-06-0 ACGIH TWA:0.005 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following __________________________________________________________________________________________ Page 5 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Solid White Specific Physical Form: Odor Odor threshold pH Melting point Boiling Point Flash Point Evaporation rate Flammability (solid, gas) Flammable Limits(LEL) Flammable Limits(UEL) Vapor Pressure Vapor Density Density Specific Gravity Solubility In Water Solubility- non-water Partition coefficient: n-octanol/ water Autoignition temperature Decomposition temperature Viscosity Hazardous Air Pollutants Molecular weight Percent volatile VOC Less H2O & Exempt Solvents Paste Urethane No Data Available No Data Available No Data Available No Data Available No flash point No Data Available Not Classified No Data Available No Data Available No Data Available No Data Available 1.36 g/ml 1.36 [Ref Std:WATER=1] No Data Available No Data Available No Data Available Not Applicable No Data Available 100,000 - 500,000 centipoise <=0.2 % weight [Test Method:Calculated] No Data Available 2.9 % weight 40 g/l [Test Method:tested per EPA method 24] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure __________________________________________________________________________________________ Page 6 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 buildup. Amines Alcohols Water 10.6. Hazardous decomposition products Substance None known. Condition Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Harmful if inhaled. Respiratory Tract Irritation: nose and throat pain. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation __________________________________________________________________________________________ Page 7 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Methylene Chloride Methylene Chloride Methylene Chloride Titanium Dioxide Toluene Diisocyanate Toluene Diisocyanate 75-09-2 75-09-2 75-09-2 13463-67-7 26471-62-5 26471-62-5 Grp. 2A: Probable human carc. Anticipated human carcinogen Cancer hazard Grp. 2B: Possible human carc. Grp. 2B: Possible human carc. Anticipated human carcinogen International Agency for Research on Cancer National Toxicology Program Carcinogens OSHA Carcinogens International Agency for Research on Cancer International Agency for Research on Cancer National Toxicology Program Carcinogens Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Overall product Overall product Talc Talc Titanium Dioxide Titanium Dioxide Titanium Dioxide Fumed Silica Fumed Silica Fumed Silica Zinc Oxide Zinc Oxide Zinc Oxide Carbitol Acetate Carbitol Acetate Toluene Diisocyanate Toluene Diisocyanate Toluene Diisocyanate Toluene Diisocyanate Toluene Toluene Toluene Heptane Heptane Heptane (Gamma-Mercaptopropyl)trimethoxysilane (Gamma-Mercaptopropyl)trimethoxysilane Hexamethylene Diisocynate Hexamethylene Diisocynate Hexamethylene Diisocynate Route InhalationVapor(4 hr) Ingestion Dermal Ingestion Dermal InhalationDust/Mist (4 hours) Ingestion Dermal InhalationDust/Mist (4 hours) Ingestion Dermal InhalationDust/Mist (4 hours) Ingestion Dermal Ingestion InhalationVapor (4 hours) Dermal InhalationDust/Mist (4 hours) Ingestion Dermal InhalationVapor (4 hours) Ingestion Dermal InhalationVapor (4 hours) Ingestion Dermal Ingestion Dermal InhalationDust/Mist (4 hours) Inhalation- Species Rabbit Rat Rat Rabbit Rat Rat Rat Rat Rabbit Rat Mouse Rabbit Rat Rat Rat Rat Rat Rabbit Rat Rat Rabbit Rat Rat Rat Rat Value No data available; calculated ATE10 - 20 mg/l No data available; calculated ATE >5,000 mg/kg LD50 estimated to be > 5,000 mg/kg LD50 estimated to be > 5,000 mg/kg LD50 > 10,000 mg/kg LC50 > 6.82 mg/l LD50 > 10,000 mg/kg LD50 > 5,000 mg/kg LC50 > 0.691 mg/l LD50 > 5,110 mg/kg LD50 estimated to be > 5,000 mg/kg LC50 > 5.7 mg/l LD50 > 5,000 mg/kg LD50 15,000 mg/kg LD50 11,000 mg/kg LC50 0.12 mg/l LD50 > 9,400 mg/kg LC50 0.35 mg/l LD50 > 5,000 mg/kg LD50 12,000 mg/kg LC50 30 mg/l LD50 5,550 mg/kg LD50 3,000 mg/kg LC50 103 mg/l LD50 > 15,000 mg/kg LD50 2,270 mg/kg LD50 770 mg/kg LD50 > 7,000 mg/kg LC50 0.124 mg/l LC50 0.124 mg/l __________________________________________________________________________________________ Page 8 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Hexamethylene Diisocynate Methylene Chloride Methylene Chloride Methylene Chloride ATE = acute toxicity estimate Vapor (4 hours) Ingestion Rat Dermal Rat Inhalation- Rat Vapor (4 hours) Ingestion Rat LD50 710 mg/kg LD50 > 2,000 mg/kg LC50 63.7 mg/l LD50 1,410 mg/kg Skin Corrosion/Irritation Name Species Value Talc Titanium Dioxide Fumed Silica Zinc Oxide Carbitol Acetate Toluene Diisocyanate Toluene Heptane (Gamma-Mercaptopropyl)trimethoxysilane Hexamethylene Diisocynate Methylene Chloride Rabbit Rabbit Rabbit Human and animal Human and animal Rabbit Rabbit Human Rabbit Rabbit Rabbit No significant irritation No significant irritation No significant irritation No significant irritation Minimal irritation Irritant Irritant Mild irritant No significant irritation Corrosive Irritant Serious Eye Damage/Irritation Name Species Value Talc Titanium Dioxide Fumed Silica Zinc Oxide Carbitol Acetate Toluene Diisocyanate Toluene Heptane (Gamma-Mercaptopropyl)trimethoxysilane Hexamethylene Diisocynate Methylene Chloride Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Professio nal judgeme nt Rabbit Rabbit Rabbit No significant irritation No significant irritation No significant irritation Mild irritant Severe irritant Corrosive Moderate irritant Moderate irritant No significant irritation Corrosive Severe irritant Skin Sensitization Name Titanium Dioxide Fumed Silica Zinc Oxide Carbitol Acetate Toluene Diisocyanate Toluene Species Human and animal Human and animal Guinea pig Human and animal Human and animal Guinea Value Not classified Not classified Not classified Not classified Sensitizing Not classified __________________________________________________________________________________________ Page 9 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 (Gamma-Mercaptopropyl)trimethoxysilane Hexamethylene Diisocynate pig Guinea pig Multiple animal species Sensitizing Sensitizing Respiratory Sensitization Name Species Value Talc Toluene Diisocyanate Hexamethylene Diisocynate Human Human Human and animal Not classified Sensitizing Sensitizing Germ Cell Mutagenicity Name Route Value Talc Talc Titanium Dioxide Titanium Dioxide Fumed Silica Zinc Oxide Zinc Oxide Carbitol Acetate Toluene Diisocyanate Toluene Toluene Heptane (Gamma-Mercaptopropyl)trimethoxysilane Hexamethylene Diisocynate Hexamethylene Diisocynate Methylene Chloride Methylene Chloride In Vitro In vivo In Vitro In vivo In Vitro In Vitro In vivo In Vitro In Vitro In Vitro In vivo In Vitro In Vitro In Vitro In vivo In vivo In Vitro Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Not mutagenic Some positive data exist, but the data are not sufficient for classification Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Talc Titanium Dioxide Titanium Dioxide Fumed Silica Toluene Diisocyanate Toluene Diisocyanate Toluene Toluene Toluene Hexamethylene Diisocynate Route Inhalation Ingestion Inhalation Not Specified Inhalation Ingestion Dermal Ingestion Inhalation Inhalation Species Rat Multiple animal species Rat Mouse Human and animal Multiple animal species Mouse Rat Mouse Rat Value Some positive data exist, but the data are not sufficient for classification Not carcinogenic Carcinogenic Some positive data exist, but the data are not sufficient for classification Not carcinogenic Carcinogenic Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Not carcinogenic __________________________________________________________________________________________ Page 10 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Methylene Chloride Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Talc Ingestion Not classified for development Fumed Silica Fumed Silica Fumed Silica Ingestion Not classified for female reproduction Ingestion Not classified for male reproduction Ingestion Not classified for development Zinc Oxide Toluene Diisocyanate Toluene Diisocyanate Toluene Diisocyanate Ingestion Not classified for reproduction and/or development Inhalation Not classified for female reproduction Inhalation Not classified for male reproduction Inhalation Not classified for development Toluene Toluene Toluene Toluene Hexamethylene Diisocynate Hexamethylene Diisocynate Hexamethylene Diisocynate Methylene Chloride Methylene Chloride Methylene Chloride Inhalation Not classified for female reproduction Inhalation Not classified for male reproduction Ingestion Toxic to development Inhalation Toxic to development Inhalation Not classified for female reproduction Inhalation Not classified for development Inhalation Not classified for male reproduction Inhalation Not classified for female reproduction Inhalation Not classified for male reproduction Inhalation Not classified for development Species Rat Rat Rat Rat Multiple animal species Rat Rat Rat Human Rat Rat Human Rat Rat Rat Rat Rat Multiple animal species Test Result NOAEL 1,600 mg/kg NOAEL 509 mg/kg/day NOAEL 497 mg/kg/day NOAEL 1,350 mg/kg/day NOAEL 125 mg/kg/day NOAEL 0.002 mg/l NOAEL 0.002 mg/l NOAEL 0.004 mg/l NOAEL Not available NOAEL 2.3 mg/l LOAEL 520 mg/kg/day NOAEL Not available NOAEL 0.002 mg/l NOAEL 0.002 mg/l NOAEL 0.014 mg/l NOAEL 5.2 mg/l NOAEL 5.2 mg/l NOAEL 4.3 mg/l Exposure Duration during organogenesi s 1 generation 1 generation during organogenesi s premating & during gestation 2 generation 2 generation during organogenesi s occupational exposure 1 generation during gestation poisoning and/or abuse 7 weeks 7 weeks 4 weeks 2 generation 2 generation during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Carbitol Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Carbitol Acetate Ingestion central nervous system depression May cause drowsiness or dizziness Toluene Diisocyanate Inhalation respiratory irritation May cause respiratory irritation Toluene Inhalation central nervous May cause drowsiness or Species Human and animal Multiple animal species Human Human Test Result NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not Exposure Duration not applicable not applicable occupational exposure __________________________________________________________________________________________ Page 11 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Toluene Toluene Toluene Heptane Heptane Heptane Hexamethylene Diisocynate Hexamethylene Diisocynate Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Inhalation Inhalation system depression respiratory irritation immune system dizziness Some positive data exist, but the data are not sufficient for classification Not classified Ingestion Inhalation Inhalation Ingestion Inhalation central nervous system depression central nervous system depression respiratory irritation central nervous system depression respiratory irritation May cause drowsiness or dizziness May cause drowsiness or dizziness Some positive data exist, but the data are not sufficient for classification May cause drowsiness or dizziness May cause respiratory irritation Inhalation blood Not classified Dermal Inhalation Inhalation Inhalation blood central nervous system depression blood respiratory irritation Some positive data exist, but the data are not sufficient for classification May cause drowsiness or dizziness Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Human Mouse Human Human Human Human Human and animal Human Rat Human Human available NOAEL Not available NOAEL 0.004 mg/l NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available NOAEL Not available 3 hours poisoning and/or abuse occupational exposure 4 hours occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Talc Talc Titanium Dioxide Titanium Dioxide Inhalation Inhalation Inhalation Inhalation pneumoconiosis pulmonary fibrosis | respiratory system respiratory system pulmonary fibrosis Causes damage to organs through Human prolonged or repeated exposure Not classified Rat Some positive data exist, but the data are not sufficient for classification Not classified Rat Human Fumed Silica Zinc Oxide Inhalation Ingestion respiratory system | silicosis nervous system Not classified Not classified Human Rat Zinc Oxide Carbitol Acetate Toluene Diisocyanate Toluene Toluene Toluene Ingestion Inhalation Inhalation Inhalation Inhalation Inhalation endocrine system | hematopoietic system | kidney and/or bladder respiratory system | liver | immune system | kidney and/or bladder respiratory system auditory system | eyes | olfactory system nervous system respiratory system Not classified Other Not classified Rat Causes damage to organs through prolonged or repeated exposure Causes damage to organs through prolonged or repeated exposure Human Human May cause damage to organs though prolonged or repeated exposure Some positive data exist, but the data are not sufficient for classification Human Rat Test Result NOAEL Not available NOAEL 18 mg/m3 LOAEL 0.01 mg/l Exposure Duration occupational exposure 113 weeks 2 years NOAEL Not available NOAEL Not available NOAEL 600 mg/kg/day NOAEL 500 mg/kg/day occupational exposure occupational exposure 10 days 6 months NOAEL 0.48 2 weeks mg/l NOAEL 0 mg/l NOAEL Not available occupational exposure poisoning and/or abuse NOAEL Not poisoning available and/or abuse LOAEL 2.3 mg/l 15 months __________________________________________________________________________________________ Page 12 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Toluene Toluene Toluene Toluene Toluene Toluene Toluene Toluene Toluene Toluene Toluene Toluene Heptane Hexamethylene Diisocynate Hexamethylene Diisocynate Hexamethylene Diisocynate Hexamethylene Diisocynate Hexamethylene Diisocynate Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Inhalation Inhalation heart | liver | kidney and/or bladder endocrine system Not classified Not classified Inhalation immune system Not classified Inhalation Inhalation Inhalation bone, teeth, nails, and/or hair hematopoietic system | vascular system gastrointestinal tract Not classified Not classified Not classified Ingestion nervous system Ingestion heart Some positive data exist, but the data are not sufficient for classification Not classified Ingestion liver | kidney and/or Not classified bladder Ingestion Ingestion hematopoietic system endocrine system Not classified Not classified Ingestion immune system Not classified Inhalation Inhalation Inhalation liver | nervous system | kidney and/or bladder liver | kidney and/or bladder endocrine system Not classified Not classified Not classified Inhalation blood Not classified Inhalation nervous system Not classified Inhalation heart Not classified Inhalation kidney and/or bladder Inhalation liver Inhalation respiratory system Inhalation heart Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Not classified Inhalation immune system Not classified Ingestion liver Ingestion blood Some positive data exist, but the data are not sufficient for classification Not classified Ingestion kidney and/or bladder Not classified Ingestion eyes Not classified Rat Rat Mouse Mouse Human Multiple animal species Rat Rat Multiple animal species Mouse Mouse Mouse Rat Rat Rat Rat Rat Rat Rat Rat Multiple animal species Human Rat Rat Rat Rat Rat NOAEL 11.3 mg/l NOAEL 1.1 mg/l NOAEL Not available NOAEL 1.1 mg/l NOAEL Not available 15 weeks 4 weeks 20 days 8 weeks occupational exposure NOAEL 11.3 15 weeks mg/l NOAEL 625 13 weeks mg/kg/day NOAEL 2,500 mg/kg/day NOAEL 2,500 mg/kg/day NOAEL 600 mg/kg/day NOAEL 105 mg/kg/day NOAEL 105 mg/kg/day NOAEL 12 mg/l 13 weeks 13 weeks 14 days 28 days 4 weeks 26 weeks NOAEL 0.002 mg/l NOAEL 0.0014 mg/l NOAEL 0.0012 mg/l NOAEL 0.002 mg/l NOAEL 0.001 mg/l LOAEL 6.95 mg/l 3 weeks 4 weeks 2 years 7 weeks 90 days 2 years NOAEL 0.17 2 years mg/l LOAEL 35 mg/l 8 weeks NOAEL Not available NOAEL 18 mg/l LOAEL 1,200 mg/kg/day NOAEL 249 mg/kg/day NOAEL 1,469 mg/kg/day NOAEL 249 mg/kg/day 28 days 3 months 2 years 3 months 104 weeks Aspiration Hazard __________________________________________________________________________________________ Page 13 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Name Toluene Heptane Value Aspiration hazard Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Acute toxicity Carcinogenicity Reproductive toxicity Respiratory or Skin Sensitization Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt __________________________________________________________________________________________ Page 14 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Toluene Diisocyanate 26471-62-5 Trade Secret < 1 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) Toluene Diisocyanate (Benzene, 1,3diisocyanatomethyl-) Toluene Diisocyanate Methylene Chloride C.A.S. No 26471-62-5 26471-62-5 75-09-2 Regulation Toxic Substances Control Act (TSCA) 5 SNUR or Consent Order Chemicals Toxic Substances Control Act (TSCA) 5 SNUR or Consent Order Chemicals Toxic Substances Control Act (TSCA) 6 Banned or Restricted Use Chemicals Status Proposed Proposed Applicable This material contains a chemical subject to a proposed EPA Significant New Use Rule (TSCA Section 5) Ingredient (Category if applicable) Toluene Diisocyanate Additional TSCA Information C.A.S. No 26471-62-5 Reference 80 FR 2068 Components Methylene Chloride 15.2. State Regulations Contact 3M for more information. California Proposition 65 CAS No 75-09-2 Additional Information This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as defined in TSCA section 3(13)) for consumer paint or coating removal. Ingredient Toluene diisocyanate C.A.S. No. 26471-62-5 Listing Carcinogen 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 16-3092-0 Version Number: 16.00 __________________________________________________________________________________________ Page 15 of 16 3MTM Marine Adhesive Sealant 5200, White, PN 05203, PN 05206, PN 06500 04/08/21 Issue Date: 04/08/21 Supercedes Date: 07/25/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com __________________________________________________________________________________________ Page 16 of 16