User Guide for PARHyS models including: 2A9GC03664411000133, 2A9GC03664411000133, 03664411000133, Permanent Analysis of Renewable Hydrogen with Sensors, Renewable Hydrogen Permanent Analysis, Renewable Hydrogen with Sensors, Renewable Hydrogen

LIVREAU Florence (ENGIE R&I)

User manual

ENGIE Lab CRIGEN 03664411000133 PARHYS 2A9GC03664411000133 2A9GC03664411000133 03664411000133


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Permanent Analyses of Renewable Hydrogen with Sensors
User Guide

ENGIE 1 Place Samuel de Champlain ­ 92400 COURBEVOIE - FRANCE

Reserved ENGIE 2023

TABLE OF CONTENTS 1. OBJECTIVE ...........................................................................................................2 2. SYSTEM COMPONENTS......................................................................................3 3. INSTALLATION INSTRUCTIONS..........................................................................4 4. PROBLEMS AND SOLUTIONS DURING INSTALLATION ...................................7 5. PRODUCT SPECIFICATION SHEET ....................................................................8 6. GENERAL INFORMATION ­ CERTIFICATION ....................................................9
Hazard warnings and safety symbols
Information in this manual that may affect the safety of users. If the equipment is used in a manner not specified by the manufacturer, the protection provided by the equipment may be impaired Important/useful information and instructions are shown clearly throughout the manual in a note format.
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This document is the exclusive property of ENGIE. Any inappropriate use contrary to its original purpose, any dissemination, part or full publication of this document is prohibited without the prior written consent of ENGIE owner of this document.

1. OBJECTIVE
Hydrogen is a key component of the energy transition movement and natural hydrogen could be part of it. Indeed, emanations coming out of the ground have been detected in several places in the world. However, this molecular hydrogen is extremely diffuse and requires dedicated instrumentation to be detected. PARHyS instrument is designed to remotely and continuously monitor natural hydrogen emanations in the soil at a depth up to 1 meter. This measurement may be realized at regular interval (1h to 24h).
PARHyS use LoRaWan network (public or private) and Bluetooth communications.
PARHyS also allows the recovery of gas from the ground via a balloon that can be placed at the vent. The various components of the gas other than hydrogen can thus be measured by gas chromatography.

2. SYSTEM COMPONENTS
Bottom view of PARHyS sensor

 Globe  Inox sampling tubing  On/Off button  Bluetooth button  Identification label  Air vent silencer  Gas path  Hydrophobic filter

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3. INSTALLATION INSTRUCTIONS
Parts included in the package · PARHyS sensor packed. · Inox sampling tubing not plugged. · User Guide.
Tools box (not included in the package) · 2 Thionyl Chloride 3.6 V ­ Size D. · Screwdriver Philips medium to remove/install the top of the globe. · Portable perforator. · Drill 12x1000 mm. · Smartphone Android 10+. · Smartphone Apps, · Option: Gas sampling flask or bag with a minimum volume of 0.5 l.
First preparation before installation
· Remove the 6 screws on the bottom  to remove the top of the globe .
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· Place the 2 batteries - type 3.6V-19Ah Thionyl Chloride respecting the polarities . · Replace the top of the globe. · Switch the PARHyS sensor by pushing the On/Off button:
o 2 LED flashing consecutively. o When PARHyS sensor is started (around xx seconds) : rapid flashing of the power
button LED. · Start Apps Nanotech on your Smartphone (refer to Nanotech Apps documentation load on
www.website. Crigen.com). · Pair PARHyS sensor by pressing the Bluetooth button.
o BLE connectable: slow flashing of the BLE button LED. o BLE connected: rapid flashing of the BLE button LED. · If PARHyS Sensor is connected to the Gateway, the 2 LED simultaneous status are : o Transmission of the join request: 1 flash. o Failure of the join procedure: 2 flashes o Reception of the join successful: 4 flashes. o First frame received: 6 flashes. · Plug the sampling inox tubing with the globe . A mark on the sampling inox tubing indicates the ideal pushing length. The two O-rings must not be removed from their location. They are shown to indicate that providing the gas tight seal their presence should be checked.
Installing PARHyS sensor into the soil
Check on your smartphone that the module has been paired. · A hole about 1000 mm depth and 12 mm in diameter is drilled in the ground with a portable perforator. · Insert sampling tubing into the hole to a depth of 1000 mm (or less).
Ensure the path gas tube is not crushed, around 20 cm up to the soil.
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Measurement procedure (refer to Smartphone Apps User Guide) · Start the Manual measurement mode in the Smartphone Apps: data retrieved as a csv file on the Smartphone directly. · Start the Automatic measurement mode in the Smartphone Apps: data retrieved every hour from a server.

I could be necessary to Push Bluetooth button again since for energy saving the BLE switches off.

Balloon/bag installation procedure

PARHyS makes it possible to collect a punctual sample of gas from the soil for chromatographic analysis with a

balloon. · · · ·

Push Bluetooth button at the bottom of globe. Start up the Smartphone Apps Nanotech. Stop the automatic data transmission if in progress via the Apps. Place the balloon/bag at the vent either by :

o Inserting a latex balloon directly onto the air vent silencer. o Unscrewing the air silencer and screwing a balloon/bag with a M5x0.8 male connector directly
to the vent filter.

· Start the Balloon mode in the Apps. · Remove the balloon/bag after collecting the gas.

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This document is the exclusive property of ENGIE. Any inappropriate use contrary to its original purpose, any dissemination, part or full publication of this document is prohibited without the prior written consent of ENGIE owner of this document.

4. PROBLEMS AND SOLUTIONS DURING INSTALLATION

Good practices for transport and storage · Drive to the site with PARHyS sensor inside the vehicle, not in the trunk, where it could be subjected to extreme temperatures and possible shocks. · Do not place PARHyS sensor against a hot object (e.g. in a car left in the sun during the summer). · Protect PARHyS sensor from direct sunlight and heavy rain when installing to avoid temperature rising in PARHyS's measurement chamber which may result in erroneous readings.

Problems encountered After pushing the On/Off button PARHyS sensor does not activate.
Sampling inox tube is not properly inserted.
Pairing between PARHyS sensor and the Smartphone Apps fails. Pairing between Parhys and the Gateway fails.

Solutions
Check that the batteries are properly installed in the battery compartment and/or their status. Check that the On/Off button is not damaged. Check that the O-Rings and/or the mark on the sampling tubing are correctly positioned. Check that the smartphone is in Bluetooth mode. Press the BLE button under the globe.
Switch off Parhys sensor by pressing the On/Off button and repeat the procedure Before installation (§3).

For further problems contact CRIGEN-NSWLab@engie.com

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General

Measure

Communication

5. PRODUCT SPECIFICATION SHEET

Description Supply Voltage Range Operating Temperature Storage Temperature Operating Humidity Storage Humidity Battery type Battery capacity Battery replaceable Battery time life Upload interval range Sample interval range Warranty H2 concentration Accuracy Temperature Humidity Communication Protocol Frequency Receive sensibility RF output power Antenna gain: peak gain Antenna Type General Communication Equipment Globe height Globe diameter Globe material Globe color Sample tubing height Sample tubing diameter Sample tubing material Connection tubing-globe Weight
Smartphone Apps
LEGEND communication
Public LoRaWan

Values 3.6
1 000 -5 to + 50 -10 to +75 10 to 95
5 to 95 Thionyl Chloride 3.6 V
19 Yes 1 1 to 24 1 to 24 1 0 to 1 000 <  10 -5 to + 50 10 to 95 LoraWan , BLE
LORA EU 863-870MHz -137dBm +14dBm max, 25mW -3.2dBi
Omni directional CE
FCC, IC, RED ROHS 147 154
ABS-PMMA White glossy
1100 10.5 Inox 316L
1051.2
Android 8.1+
Contact us
Orange business LoRaWan
Bouygues Objenious Other network contact us

Units V
meter °C °C % %
Ah

Remarks Between PARHyS and LoRaWan gateway - free space
Best storage environment 0-20°C, 50%HR wo condensing 2 x Type D (SL-2780)

year hours hours year ppm
% °C %

PARHyS ­1 sample every 4 hour - 1 transmission by sample LoraWan configurable 1 to 24 time/day Configurable by customer or smartphone Apps
Temperature between 22 and 39°C

LORA US 902-928MHz -132dBm +18dBm max, 63mW -3.0dBi
dBi

LORA AU 915-928MHz -137dBm +18dBm max, 63mW -3.0dBi

Bluetooth BLE 2402-2480MHz -90dBm à 1 Mbps +4dBm max, 2.5mW

Cat 9 mm mm

mm mm
Two O-rings ensure the seal g Without battery.
Standalone measurements with csv data. Receiving flash local memory (up to 8000 samples). Configuration. Private LoRaWan gateway with Iridium satellite communication and energy harversting. LEGEND gateway: 100 PARHyS over 1 km distance. This solution is recommended out off Lora network.
Native language of public operators.

Certification

Mechanical

Addendum

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6. GENERAL INFORMATION ­ CERTIFICATION
General product information
Separate collection, handling and disposal for waste electrical and electronic equipment and its components.

Calibration gases The sensors are delivered with a calibration information. It is however possible to check the calibration with a standard H2 gas injected at 25°C and 50%RH.
Service PARHyS should be regularly serviced by ENGIE to ensure correct and accurate operation. At the end of the life, request RMA (Return Material Authorization) before returned to ENGIE for WEEE procedures.
Warranty policy This instrument is guaranteed, to the original end user purchaser, against defect in materials and workmanship for a period of 2 years from the date of the shipment to the user. During this period ENGIE will repair or replace defective parts on an exchange basis. The decision to repair or replace will be determined by ENGIE.

RF information

Changes or modifications not expressly approved by ENGIE could void the user's authority to operate the equipment.

FCC Part 15 compliance statement

This device complies with part 15 of the FCC Rules. Operation is subject to the following two conditions: (1) This device may not cause

harmful interference, and (2) this device must accept any interference received, including interference that may cause undesired

operation.

NOTE: This equipment has been tested and found to comply with the limits for a Class B digital device, pursuant to part 15 of the FCC

Rules. These limits are designed to provide reasonable protection against harmful interference in a residential installation. This

equipment generates uses and can radiate radio frequency energy and, if not installed and used in accordance with the instruction, may

cause harmful interference to radio communications. However, there is no guarantee that interference will not occur in a particular

installation. If this equipment does cause harmful interference to radio or television reception which can be determined by turning the

equipment off and on, the user is encouraged to try to correct interference by one or more of the following measures:

-

Reorient or relocate the receiving antenna.

-

Increase the separation between the equipment and receiver.

-

Connect the equipment into an outlet on circuit different from that to which the receiver is connected.

-

Consult the dealer or an experienced radio/TV technician for help.

License-Exempt Radio Apparatus (ISED)

This device contains license-exempt transmitter(s)/receiver(s) that comply with Innovation, Science and Economic Development Canada's

license-exempt RSS(s). Operation is subject to the following two conditions:

1.

This device may not cause interference.

2.

This device must accept any interference, including interference that may cause undesired operation of the device.

Appareils radio exempts de licence (ISDE)

L'émetteur/récepteur exempt de licence contenu dans le présent appareil est conforme aux CNR d'Innovation, Sciences et

Développement économique Canada applicables aux appareils radio exempts de licence. L'exploitation est autorisée aux deux conditions

suivantes :

1.

L'appareil ne doit pas produire de brouillage;

2.

L'appareil doit accepter tout brouillage radioélectrique subi, même si le brouillage est susceptible d'en compromettre le

fonctionnement.

Radio Frequency (RF) Exposure Compliance of Radiocommunication for mobile Apparatus To satisfy FCC and IC RF Exposure requirements for mobile devices, a separation distance of 20 cm or more should be maintained between the antenna of this device and persons during operation. To ensure compliance, operation at closer than this distance is not recommended. This transmitter must not be co-located or operating in conjunction with any other antenna or transmitter. Conformité à l'exposition aux champs RF des équipements radio mobiles Pour satisfaire aux exigences FCC et IC concernant l'exposition aux champs RF pour les appareils mobile, une distance de séparation de 20 cm ou plus doit être maintenu entre l'antenne de ce dispositif et les personnes pendant le fonctionnement. Pour assurer la conformité, il est déconseillé d'utiliser cet équipement à une distance inférieure. Cet émetteur ne doit pas être co-situé ou fonctionner conjointement avec une autre antenne ou un autre émetteur.

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This document is the exclusive property of ENGIE. Any inappropriate use contrary to its original purpose, any dissemination, part or full publication of this document is prohibited without the prior written consent of ENGIE owner of this document.

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This document is the exclusive property of ENGIE. Any inappropriate use contrary to its original purpose, any dissemination, part or full publication of this document is prohibited without the prior written consent of ENGIE owner of this document.


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