Material Safety Data Sheet

According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Revision: 08/08/2024

1. Identification of the substance/Preparation and company

1.1 PRODUCT IDENTIFICATION

PRODUCT NAME: Gouache -12colors

COLOR: Titanium White, Lemon Yellow, Yellow Ochre, Vermilion, Crimson, Viridian, Cerulean Blue, Phthalocyanine Blue, Purple, Burnt Sienna, Burnt Umber, Lamp Black

1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST

Paint by artist, amateur and students

1.3 COMPANY DETAILS:

NAME: Tianchang Jiafeng Painting Material Co., Ltd

ADDRESS: Shizhuang Village, Zhengji Town, Tianchang City, Anhui Province, China

TEL: +86-550-7964322

FAX: +86-550-7964422

CONTACT PERSON: Chen Feng

EMAIL ADDRESS: Chen-feng@jabp.com

1.4 EMERGENCY TELEPHONE

TEL: +86-550-7964322

2. Hazard identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008: The product is not classified according to CLP Regulation.

2.2 Label elements

Labeling according to Regulation (EC) No 1272/2008: Not applicable

2.3 Other hazards

None ingredients meets the criteria for PBT/vPvB in accordance with Annex XIII.

None ingredients identified as having endocrine disrupting properties according to Regulation (EU) 2017/2100.

3. Composition/information on ingredients

3.1 Substances

Information not relevant.

3.2 Mixtures.

Ingredient Name CAS Number Proportion According to Regulation (EC) No 1272/2008
1. Titanium White
Water 7732-18-5 42.6988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 10.0000% Not Classified
Silicon dioxide 7631-86-9 6.2000% Not Classified
Titanium dioxide (P.W.6) 13463-67-7 18.5000% Not Classified
2. Lemon Yellow
Water 7732-18-5 44.9988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 22.2000% Not Classified
Silicon dioxide 7631-86-9 6.2000% Not Classified
2-[(2-methoxy-4-nitrophenyl)azo]-N-(2-methoxyphenyl)-3-oxobutyramide (P.Y.74) 6358-31-2 4.0000% Not Classified
3. Yellow Ochre
Water 7732-18-5 39.3988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 18.0000% Not Classified
Silicon dioxide 7631-86-9 3.0000% Not Classified
Iron hydroxide oxide yellow (P.Y.42) 51274-00-1 17.0000% Not Classified
4. Vermilion
Water 7732-18-5 41.8988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 25.0000% Not Classified
Silicon dioxide 7631-86-9 5.0000% Not Classified
2-[(2-methoxy-4-nitrophenyl)azo]-N-(2-methoxyphenyl)-3-oxobutyramide (P.Y.74) 6358-31-2 4.0000% Not Classified
4-[(2,5-dichlorophenyl)azo]-3-hydroxy-N-phenylnaphthalene-2-carboxamide(P.R.2) 6041-94-7 1.5000% Not Classified
5. Crimson
Water 7732-18-5 45.1988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 22.8000% Not Classified
Silicon dioxide 7631-86-9 4.4000% Not Classified
6. Viridian
Calcium 3-hydroxy-4-[(4-methyl-2-sulphonatophenyl)azo]-2-naphthoate(P.R 57:1) 5281-04-9 5.0000% Not Classified
Water 7732-18-5 41.3988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 24.0000% Not Classified
Silicon dioxide 7631-86-9 7.2000% Not Classified
Polychloro copper phthalocyanine(P.G.7) 1328-53-6 2.9000% Not Classified
Titanium dioxide (P.W.6) 13463-67-7 1.9000% Not Classified
7. Cerulean Blue
Water 7732-18-5 42.1788% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 22.0000% Not Classified
Silicon dioxide 7631-86-9 6.0000% Not Classified
Titanium dioxide (P.W.6) 13463-67-7 3.3000% Not Classified
Polychloro copper phthalocyanine(P.G.7) 1328-53-6 0.8000% Not Classified
29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper Phthalo Blue BGS(P.B.15) 147-14-8 3.1200% Not Classified
8. Purple
Water 7732-18-5 52.5188% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 16.0000% Not Classified
Silicon dioxide 7631-86-9 8.0000% Not Classified
Titanium dioxide (P.W.6) 13463-67-7 2.4000% Not Classified
29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper Phthalo Blue BGS(P.B.15) 147-14-8 0.0800% Not Classified
8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo [3,2-b:3',2'-m]triphenodioxazine(P.V.23) 6358-30-1 0.8000% Not Classified
10. Burnt Sienna
Water 7732-18-5 48.6488% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 15.8500% Not Classified
Silicon dioxide 7631-86-9 6.1000% Not Classified
Iron hydroxide oxide yellow (P.Y.42) 51274-00-1 1.8000% Not Classified
Iron hydroxide oxide red (P.R.101) 1309-37-1 4.5000% Not Classified
Iron hydroxide oxide black (P.BK.11) 1317-61-9 0.5000% Not Classified
11. Burnt Umber
Water 7732-18-5 41.2488% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 18.0000% Not Classified
Silicon dioxide 7631-86-9 6.2500% Not Classified
Iron hydroxide oxide yellow (P.Y.42) 51274-00-1 4.2000% Not Classified
Iron hydroxide oxide red (P.R.101) 1309-37-1 1.3000% Not Classified
Iron hydroxide oxide black (P.BK.11) 1317-61-9 6.4000% Not Classified
12. Lamp Black
Water 7732-18-5 46.1988% Not Classified
Gum arabic 9000-01-5 20.0000% Not Classified
Glycerine 56-81-5 2.5000% Not Classified
2-phenoxyethanol 122-99-6 0.1000% Acute Tox. 4 (H302), Eye Dam. 1 (H318), STOT SE 3 (H335)
2-n-butyl-benzo[d]isothiazol-3-one 4299-07-4 0.0006% Skin Corr. 1B (H314), Skin Sens. 1 (H317), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine 2372-82-9 0.0006% Acute Tox. 3 (H301), Skin Corr. 1B (H314), Eye Dam. 1 (H318), STOT RE 2 (H373), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)
Calcium carbonate 471-34-1 18.0000% Not Classified
Silicon dioxide 7631-86-9 8.2000% Not Classified
Carbon Black (P.BK. 7) 1333-86-4 5.0000% Not Classified
Titanium dioxide with an aerodynamic diameter of ≤ 10 µm is less than 1%. Labeling is not applicable.

4. First aid measures

4.1 Description of first aid measures

After skin Contact: If skin or hair contact occurs, Flush skin and hair with running water(and soap if available). Seek medical attention in event of irritation.

After eye Contact: If this Product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

After ingestion: Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

After inhalation: If fumes, aerosols or combustion products are inhaled, remove from contaminated area. Other measures are usually unnecessary.

4.2 Most important symptoms and effects, both acute and delayed.

No date available

4.3. Indication of any immediate medical attention and special treatment needed:

Information not available.

5. Fire fighting Measures

5.1 Suitable Extinguishing Media

These is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.

5.2 Combustion products and resulting gases

Carbon monoxide (CO) carbon dioxide (CO2) other pyrolysis products typical of burning organic material.

5.3 Special Protective Equipment

Avoid contamination with oxidising agents i.e.nitrates,oxidising acids, chlorine bleaches,pool chlorine ect. as ignition may result.

6. Accidental release Measures

6.1 Personal Protection

Clean up waste regularly and abnormal spills. Avoid breathing dust and contact with skin and eyes. Wear protective clothing, gloves, safety glasses and dust respirator. Use dry clean up procedures and avoid generating dust.

6.2 Environmental Protection

Not applicable

6.3 Methods for cleaning up

Not applicable

6.4 Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

7. Handling and storage

7.1 Handling Precautions

Store in cool, dry place in tightly closed receptacles. Keep ignition source away – Do not smoke.

Store in a cool location. Store away from flammable substances.

7.2 Storage Precautions

Information not available.

7.3 Specific end use(s)

Information not available.

8. Exposure controls/personal protection

8.1 Respiration Protection

Not required.

8.2 Hand Protection

The glove material has to be impermeable and resistant to the products/the substance/the preparation. Due to missing test no recommendation to the glove material can be given for the product/the preparation/the chemical mixture. Selection of the glove material on consideration of the penetration times, rate of diffusion and the degradation

8.3 Eye Protection

Not required

8.4 Skin Protection

Generally the product does not irritate the skin. If skin or hair contact occurs, Flush skin and hair with running water(and soap if available)

9. Physical and chemical properties

Appearance Paste Auto flammability Product is not self igniting.
Color 12colors Explosive properties Product dose not present explosion hazard
Odour No Oxidizing properties Not available
pH 6-7 Vapor pressure Not available
Boiling point/boiling range Not available Relative density 1.25-1.50g/cm 3
Melting point/melting range Not available Solubility in water Yes
Flash point Not available Partition coefficient Not available
Flammability No Others No

10. Stability and reactivity

10.1. Reactivity.

There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability.

The product is stable in normal conditions of use and storage

10.3. Possibility of hazardous reactions.

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid

None in particular. However the usual precautions used for chemical products should be respected.

10.5. Incompatible materials

Information not available.

10.6. Hazardous decomposition products

No

11. Toxicological information

11.1 Information on toxicological effects

11.2 Information on other hazards

11.2.1 Endocrine disrupting properties:

None ingredient is considered to have endocrine-disrupting properties with respect to humans as it meets the criteria set out in section A of Regulation (EU) No 2017/2100.

11.2.2 Other information:

No known other relevant information on adverse health effects.

12. Ecological information

12.1. Toxicity

Ecology - general: The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

Hazardous to the aquatic environment, short-term(acute): Not classified

Hazardous to the aquatic environment, long-term(chronic): Not classified

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB, according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

General notes: WGK1 (German Regulation) (self-assessment): Low hazard to waters. Do not allow large quantities of the product to reach ground water, water course or sewage system.

13. Disposal considerations

13.1 Methods of disposal

Do not allow wash water from cleaning or process equipment to enter drains.

13.2 Dangers in disposal

No

14. Transport information

Transportation Status: Important! Statements below provide additional data on listed Dot classification. The listed Transportation Classification does not address regulatory variations due to changes in package size, mode of shipment or other regulatory descriptors.

US Department of Transportation

Shipping Name: IMDG NOT REGULATED

14.1 UN number No 14.4 Packing group Unregulated
14.2 UN proper shipping name No 14.5 Environmental hazards No
14.3 Transport hazard class(es) No 14.6 Special precautions for user No
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Unregulated

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation sp

EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and import of hazardous chemicals.

Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent organic pollutants

15.2 Chemical safety assessment:

A Chemical Safe Assessment has not been carried out.

16. Other information

16.1 Indication of changes:

None.

16.2 Abbreviations and acronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road).

IMDG: International Maritime Code for Dangerous Goods.

IATA: International Air Transport Association.

CAS: Chemical Abstracts Service (division of the American Chemical Society)

DNEL: Derived No-Effect Level (REACH)

PNEC: Predicted No-Effect Concentration (REACH)

PBT: Persistent, Bio accumulative and Toxic

vPvB: very persistent and very bio accumulative

SVHC: Substance of Very High Concern

LD50: Lethal dose, 50 percent

LC50: Lethal concentration, 50 percent

EC50: Concentration of maximal effect, 50 percent

NOEC: No observed effect concentration

Acute Tox. 3: Acute toxicity, hazard category 3

Acute Tox. 4: Acute toxicity, hazard category 4

Skin Irrit. 2: Skin corrosion/irritation, hazard category 2

Eye Dam. 1: Eye damage/irritation, hazard category 1

Eye Irrit. 2: Eye damage/irritation, hazard category 2

STOT SE 3: Specific target organ toxicity after single exposure, hazard category 3

Carc. 2: Carcinogenicity, hazard category 2

Aquatic Acute 1: Short-term (acute) aquatic hazard, hazard category 1

Aquatic Chronic 2: Long-term (chronic) aquatic hazard, hazard category 2

Aquatic Chronic 3: Long-term (chronic) aquatic hazard, hazard category 3

16.3 Key literature references and sources for data:

16.4 Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 [CLP]:

See section 2.1(classification).

16.5 Relevant H- and EUH-phrases (number and full text):

16.6 Training advice:

Workers must be educated and trained so they can read SDS and understand the hazards, and know how to work safely with hazardous products.

16.7 Further information

The contents and format of this MSDS are in accordance with Regulation (EC) No 1907/2006, its amendment Regulation (EU) No 2020/878 and (EC) No 1272/2008.

The information in this MSDS was obtained form sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or express arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

Models: DOA 551008, DOA 551008 Gouache Paint Set, Gouache Paint Set, Paint Set

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