Aspirmatic® Cleaner - Safety Data Sheet

Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

1.1 Product Identifier

Trade Name: aspirmatic® cleaner

Unique Formula Identifier (UFI): 2P20-V06W-7006-A4W3

1.2 Relevant Identified Uses

Use of the substance/mixture: Cleaning agent

Recommended use restrictions: For professional users only.

1.3 Supplier Details

Manufacturer/Supplier: Schülke & Mayr GmbH

Robert-Koch-Str. 2

22851 Norderstedt

Germany

Phone: +49 (0)40/ 52100-0

Fax: +49 (0)40/ 52100318

Email: mail@schuelke.com

Website: www.schuelke.com

Contact for SDS: Application Specialists

Phone: +49 (0)40/ 521 00 666

Email: AD@schuelke.com

1.4 Emergency Telephone Number

Emergency number: Carechem 24 International: 0800 000 7801 (Toll-free)

Carechem 24 International: +49 89 220 61012

Section 2: Hazards Identification

2.1 Classification of the substance or mixture

Classification (Regulation (EC) No. 1272/2008):

• Corrosive to metals, Category 1 (H290: May be corrosive to metals.)
• Eye irritation, Category 2 (H319: Causes serious eye irritation.)
• Specific target organ toxicity - single exposure, Category 3, Respiratory system (H335: May cause respiratory irritation.)

2.2 Label Elements

Signal Word: Warning

Hazard Statements:

• H290: May be corrosive to metals.
• H319: Causes serious eye irritation.
• H335: May cause respiratory irritation.

Precautionary Statements:

• Prevention: P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
• Response: P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P337+P313: If eye irritation persists: Get medical advice/attention.

2.3 Other Hazards

This substance/mixture contains no components in concentrations of 0.1% or higher that are classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

Environmental information: The substance/mixture contains no constituents that have endocrine-disrupting properties according to REACH Article 57(f) or delegated regulations (EU) 2017/2100 or (EU) 2018/605 in quantities of 0.1% or more.

Toxicological information: The substance/mixture contains no constituents that have endocrine-disrupting properties according to REACH Article 57(f) or delegated regulations (EU) 2017/2100 or (EU) 2018/605 in quantities of 0.1% or more.

Section 3: Composition/Information on Ingredients

3.2 Mixtures

Chemical Characterisation: Solution of the following substances with non-hazardous admixtures.

Ingredients

Section 4: First-Aid Measures

4.1 Description of First-Aid Measures

General Advice: Immediately take off contaminated clothing. Seek medical attention if symptoms persist.

Inhalation: Move to fresh air. Seek medical attention if breathing difficulties occur.

Skin Contact: Wash with soap and water. Seek medical attention if skin irritation persists.

Eye Contact: Remove contact lenses if present. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention.

Ingestion: Do NOT induce vomiting. Rinse mouth with water. Seek medical attention if symptoms persist.

4.2 Most Important Symptoms and Effects

Symptoms: Symptomatic treatment.

Risks: Causes serious eye irritation. May cause respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment: For advice from a specialist, consult the poison control center.

Section 5: Firefighting Measures

5.1 Extinguishing Media

Suitable Extinguishing Media: Dry powder, Foam, Water spray, Carbon dioxide (CO2).

Unsuitable Extinguishing Media: Do not use a solid water stream.

5.2 Special Hazards Arising from the Substance or Mixture

Special Hazards: No information available.

Hazardous Combustion Products: No hazardous combustion products known.

5.3 Advice for Firefighters

Protective Equipment: Wear self-contained breathing apparatus in case of fire.

Section 6: Accidental Release Measures

6.1 Personal Precautions, Protective Equipment and Emergency Procedures

Personal Precautions: Risk of slipping due to spilled/leaked product. Use personal protective equipment.

6.2 Environmental Precautions

Environmental Precautions: Prevent entry into the subsoil.

6.3 Methods and Material for Containment and Cleaning Up

Cleaning Procedures: Wipe up with absorbent material (e.g., cloth, fleece). Collect with inert liquid-binding material (e.g., sand, silica gel, acid binder, universal binder, sawdust).

6.4 Reference to Other Sections

See Sections 8 + 13.

Section 7: Handling and Storage

7.1 Precautions for Safe Handling

Advice on Safe Handling: Prepare the use solution as indicated on the label(s) and/or instructions for use.

Precautions for Fire and Explosion Protection: No special fire protection measures required.

Hygiene Measures: Keep away from food and drinks.

7.2 Conditions for Safe Storage, Including any Incompatibilities

Requirements for Storage Rooms and Containers: Store in original container at room temperature.

Further Information: Protect from heat. Keep container tightly closed. Recommended storage temperature: 15 - 25°C.

Incompatible Materials: Do not store with bases (alkalis).

Storage Class (TRGS 510): 12

7.3 Specific End Uses

Specific Use(s): None.

Section 8: Exposure Controls/Personal Protection

8.1 Control Parameters

Occupational Exposure Limits

Peak limitation: Exceedance factor (Category): 2;(I)

Further Information: No risk of damage to the unborn child is to be expected when adhering to the occupational exposure limit and the biological limit value (BLW).

Derived No-Effect Concentration (DNEL) and Predicted No-Effect Concentration (PNEC)

Estimated No-Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

8.2 Exposure Controls

Personal Protective Equipment

Eye/Face Protection: Safety glasses with side shields conforming to EN 166.

Skin Protection:

• Gloves: The selected protective gloves must comply with the specifications of EC Directive 2016/425 and the derived standard EN 374.
• Remarks: Splash protection: Disposable nitrile rubber gloves, e.g., Dermatril (thickness: 0.11 mm) from KCL, or gloves from other manufacturers with equivalent protective properties. For prolonged contact: Protective gloves made of nitrile rubber, e.g., Camatril (> 480 min, thickness: 0.40 mm), or butyl rubber, e.g., Butoject (> 480 min, thickness: 0.70 mm) from KCL, or gloves from other manufacturers with equivalent protective properties.

Respiratory Protection: Normally no personal respiratory protection required. Avoid contact with eyes.

Section 9: Physical and Chemical Properties

9.1 Basic Physical and Chemical Properties

Physical State: liquid

Color: yellow

Odor: almost odorless

Odor Threshold: not determined

Melting Point/Freezing Point: approx. 0 °C

Boiling Point/Boiling Range: approx. 100 °C

Flash Point: > 100 °C (Method: ISO 2719)

Evaporation Rate: No data available

Flammability (solid, gas): Not applicable

Upper/Lower Flammability or Explosive Limits: Not applicable

Vapor Pressure: No data available

Vapor Density: No data available

Relative Density: approx. 1.17 g/cm³ (20 °C)

Solubility(ies):

• Water Solubility: completely soluble (20 °C)

Partition Coefficient: n-Octanol/Water: Not applicable

Auto-ignition Temperature: No data available

Decomposition Temperature: No data available

Viscosity:

• Kinematic Viscosity: not determined

Explosive Properties: No data available

Oxidizing Properties: The substance or mixture is not classified as oxidizing.

Metal Corrosion Rate: > 6.25 mm/a (Corrosive to metals aluminum and steel)

9.2 Other Information

Explosive Substances/Mixtures: No data available

Flammability (Liquids): Not applicable

Section 10: Stability and Reactivity

10.1 Reactivity

No dangerous reactions known under normal use.

10.2 Chemical Stability

The product is chemically stable.

10.3 Possibility of Hazardous Reactions

Hazardous Reactions: Reaction with alkalis (lyes).

10.4 Conditions to Avoid

Conditions to Avoid: Protect from frost, heat, and sunlight.

10.5 Incompatible Materials

Substances to Avoid: Normally none to be expected.

10.6 Hazardous Decomposition Products

Normally none to be expected.

Section 11: Toxicological Information

11.1 Information on Toxicological Effects

Acute Toxicity

Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• Acute Oral Toxicity: LD50 (Mouse): 5,400 mg/kg (Method: OECD Guideline 401)
• Acute Inhalation Toxicity: Remarks: No data available
• Acute Dermal Toxicity: LD50 (Rat): > 2,000 mg/kg
• Acute Toxicity (other routes of exposure): LD50 intravenous (Rat): 725 mg/kg

Skin Corrosion/Irritation

Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• Species: Rabbit
• Result: Slight skin irritation

Serious Eye Damage/Eye Irritation

Causes serious eye irritation.

• Product:
• Assessment: Causes serious eye irritation.
• Method: Expert assessment and weighting of evidence.
• Ingredients:
• Citric acid monohydrate:
• Species: Rabbit
• Method: OECD Guideline 405
• Result: Eye irritation

Respiratory or Skin Sensitisation

Skin Sensitisation: Not classified based on available information.

Respiratory Sensitisation: Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• Method: OECD Guideline 406
• Result: Causes no skin sensitization.

Germ Cell Mutagenicity

Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• In vitro Mutagenicity: Test Type: Ames test. Test System: Salmonella typhimurium. Concentration: 0 - 5 mg/plate. Method: Mutagenicity (Salmonella typhimurium - Reverse Mutation Assay). Result: negative.
• In vivo Mutagenicity: Test Type: Micronucleus test. Test System: Human lymphocytes. Method: Mutagenicity (Mammalian cytogenetic in vitro test). Result: positive.

Carcinogenicity

Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• Carcinogenicity Assessment: Not classifiable as a human carcinogen.

Reproductive Toxicity

Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• Effects on Foetal Development: Species: Rat. Route of Administration: Oral. Maternal Toxicity: NOAEL: 2,500 mg/kg body weight.
• Reproductive Toxicity Assessment: No reproductive toxicity.

Specific Target Organ Toxicity - Single Exposure

May cause respiratory irritation.

Ingredients:

Citric acid monohydrate:

• Routes of Exposure: Inhalation
• Assessment: May cause respiratory irritation.

Specific Target Organ Toxicity - Repeated Exposure

Not classified based on available information.

Ingredients:

Citric acid monohydrate:

• Remarks: No data available
• Toxicity on repeated administration:
• Species: Rat
• NOAEL: 4,000 mg/kg
• LOAEL: 8,000 mg/kg
• Route of Administration: Oral
• Exposure Time: 10 d

Aspiration Hazard

Not classified based on available information.

11.2 Information on Other Hazards

Endocrine Disrupting Properties

Product:

• Assessment: The substance/mixture contains no constituents that have endocrine-disrupting properties according to REACH Article 57(f) or delegated regulations (EU) 2017/2100 or (EU) 2018/605 in quantities of 0.1% or more.

Experiences with Human Exposure

Ingredients:

Citric acid monohydrate:

• Inhalation: Target organs: Respiratory tract irritation.

Product:

• Remarks: No data available for the product itself.

Section 12: Ecological Information

12.1 Toxicity

Ingredients:

Citric acid monohydrate:

• Toxicity to Fish: LC50 (Leuciscus idus (Golden orfe)): 440 - 760 mg/l (Exposure time: 96 h)
• Toxicity to Daphnia and other aquatic invertebrates: EC50 (Daphnia magna): 85 - 120 mg/l (Exposure time: 72 h)
• Toxicity to Algae/Aquatic Plants: NOEC (Scenedesmus quadricauda (Green algae)): 425 mg/l (Exposure time: 8 days) Test Type: Static test.
• Toxicity to Microorganisms: (Pseudomonas putida): > 10,000 mg/l (Exposure time: 16 h)

12.2 Persistence and Degradability

Product:

Biodegradability: Result: Readily biodegradable. Biological degradation: 97% (Exposure time: 28 d) Method: OECD Guideline 301 B.

Ingredients:

Citric acid monohydrate:

• Biodegradability: Result: Readily biodegradable. Biological degradation: 97% (Exposure time: 28 d) Method: OECD Guideline 301 B.

12.3 Bioaccumulative Potential

Ingredients:

Citric acid monohydrate:

• Bioaccumulation: Remarks: Bioaccumulation is not expected (log Pow <= 4).

12.4 Mobility in Soil

Ingredients:

Citric acid monohydrate:

• Mobility: Remarks: No data available

12.5 Results of PBT and vPvB Assessment

Product:

Assessment: This substance/mixture contains no components in concentrations of 0.1% or higher that are classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

12.6 Endocrine Disrupting Properties

Product:

Assessment: The substance/mixture contains no constituents that have endocrine-disrupting properties according to REACH Article 57(f) or delegated regulations (EU) 2017/2100 or (EU) 2018/605 in quantities of 0.1% or more.

12.7 Other Adverse Effects

Product:

Other Environmental Information: No data available for the product itself.

Section 13: Disposal Considerations

13.1 Waste Treatment Methods

Product: Dispose of product in accordance with the waste code number indicated.

Contaminated Packaging: Return packaging to the recycling collection after emptying.

Waste Code for unused product: AVV 070601*

Waste Code for unused product (group): Wastes from the manufacture, preparation, putting up for sale, and use (MFSU) of fats, lubricants, soaps, detergents, disinfectants and personal care products.

Section 14: Transport Information

14.1 UN Number or ID Number

• ADR: UN 3265
• IMDG: UN 3265
• IATA: UN 3265

14.2 UN Proper Shipping Name

• ADR: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Citric acid monohydrate)
• IMDG: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (1,2,3-Propanetricarboxylic acid, 2-hydroxy-, monohydrate)
• IATA: Corrosive liquid, acidic, organic, n.o.s. (1,2,3-Propanetricarboxylic acid, 2-hydroxy-, monohydrate)

14.3 Transport Hazard Class(es)

• ADR: 8
• IMDG: 8
• IATA: 8

14.4 Packing Group

• ADR:
• Packing Group: III
• Classification Code: C3
• Hazard Identification Number: 80
• Hazard Label: 8
• Tunnel Restriction Code: (E)
• IMDG:
• Packing Group: III
• Hazard Label: 8
• EmS Code: F-A, S-B
• IATA (Cargo Aircraft):
• Packing Instruction (Cargo Aircraft): 856
• Packing Instruction (LQ): Y841
• Packing Group: III
• Hazard Label: Corrosive
• IATA (Passenger Aircraft):
• Packing Instruction (Passenger Aircraft): 852
• Packing Instruction (LQ): Y841
• Packing Group: III
• Hazard Label: Corrosive

14.5 Environmental Hazards

• ADR: Not environmentally hazardous
• IMDG: Not marine pollutant

14.6 Special Precautions for User

The transport classification(s) provided herein are for informational purposes only and are based on the properties of the unpacked material as described in this Safety Data Sheet. Transport classifications may vary with the transport method, packaging size, and regional or country-specific regulations.

Personal protective equipment see Section 8.

14.7 Mass Transport of Goods in Accordance with Annex II of MARPOL and the IBC Code

Not applicable to the product in delivered state.

Section 15: Regulatory Information

15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture

• REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles (Annex XVII): The conditions for restriction should be considered: Entry number 75, 3.
• REACH - List of Substances of Very High Concern (SVHC) (Article 59): Not applicable.
• Regulation (EC) on substances that deplete the ozone layer: Not applicable.
• Regulation (EU) 2019/1021 on persistent organic pollutants (Recast): Not applicable.
• Regulation (EU) No 649/2012 of the European Parliament and of the Council concerning the export and import of hazardous chemicals: Not applicable.
• REACH - List of Substances subject to authorisation (Annex XIV): Not applicable.
• Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances: Not applicable.

15.2 Chemical Safety Assessment

No chemical safety assessment has been carried out for this mixture.

Section 16: Other Information

Full text of H-statements referred to under sections 2 and 3:

• H319: Causes serious eye irritation.
• H335: May cause respiratory irritation.

Full text of other abbreviations and acronyms:

• Eye Irrit.: Eye irritation
• STOT SE: Specific target organ toxicity - single exposure
• DE TRGS 900: Germany. TRGS 900 - Occupational exposure limits
• AGW: Occupational exposure limit
• ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR: Agreement concerning the International Carriage of Dangerous Goods by Road; AIIC: Australian Inventory of Industrial Chemicals; ASTM: American Society for Testing and Materials; bw: body weight; CLP: Regulation on Classification, Labelling and Packaging of Substances, Regulation (EC) No 1272/2008; CMR: Carcinogenic, Mutagenic or toxic for reproduction; DIN: German Institute for Standardization; DSL: Domestic Substances List (Canada); ECHA: European Chemicals Agency; EC-Number: European Community number; ECx: Concentration of effector causing x% response; ELx: Loading rate of effector causing x% response; EmS: Emergency Schedule; ENCS: Existing and New Chemical Substances (Japan); ErCx: Concentration of effector causing x% growth rate; GHS: Globally Harmonized System; GLP: Good Laboratory Practice; IARC: International Agency for Research on Cancer; IATA: International Air Transport Association; IBC: International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50: Half maximal inhibitory concentration; ICAO: International Civil Aviation Organization; IECSC: Inventory of Existing Chemical Substances in China; IMDG: International Maritime Dangerous Goods Code; IMO: International Maritime Organization; ISHL: Industrial Safety and Health Law (Japan); ISO: International Organization for Standardization; KECI: Korean Existing Chemicals Inventory; LC50: Lethal Concentration to 50% of a test population; LD50: Lethal Dose to 50% of a test population (median lethal dose).