HP C4906Series Inkjet Printing Safety Data Sheet (SDS)

HP SAFETY DATA SHEET

1. Identification

Important information: *** This Safety Data Sheet is only authorised for use by HP for HP Original products. Any unauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal action being taken by HP. ***

Product identifier:

C4906Series

Other means of identification:

None.

Recommended use:

Inkjet printing

Recommended restrictions:

None known.

Manufacturer/Importer/Supplier/Distributor information:

HP Inc.
1501 Page Mill Road
Palo Alto, CA 94304-1112
United States

Telephone:

HP Inc. health effects line

(Toll-free within the US): 1-800-457-4209

(Direct): 1-760-710-0048

HP Inc. Customer Care Line

(Toll-free within the US): 1-800-474-6836

(Direct): 1-208-323-2551

Email:

hpcustomer.inquiries@hp.com

2. Hazard(s) identification

GHS Supplemental information:

This product is not classified as hazardous according to OSHA CFR 1910.1200 (HazCom 2012). 2-pyrrolidone: OSHA Hazard Communication Standard cut-off value, Reproductive toxicity Category 1B, fertility or the unborn child 3%. Cut-off value based on data.

Physical hazards:

Not classified.

Health hazards:

Not classified.

Environmental hazards:

Not classified.

OSHA defined hazards:

Not classified.

Label elements:

Hazard symbol:

None.

Signal word:

None.

Hazard statement:

Not available.

Precautionary statement:

Prevention:

Not available.

Response:

Not available.

Storage:

Not available.

Disposal:

Not available.

Hazard(s) not otherwise classified (HNOC):

Complete toxicity data are not available for this specific formulation.

Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions.

Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present this carcinogenic risk. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA.

3. Composition/information on ingredients

Substances:

Chemical name Common name and synonyms CAS number %
Water 7732-18-5 70-80
Hydroxy alkylated lactam* Proprietary* <15
Substituted diol* Proprietary* <7.5
Modified carbon black 11* Proprietary* <5.0
2-pyrrolidone 616-45-5 <3.0

Composition comments:

This ink supply contains an aqueous ink formulation.

This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard Communication Standard).

Carbon black is present only in a bound form in this preparation.

2-pyrrolidone: OSHA Hazard Communication Standard cut-off value 3%. Cut-off value based on data.

*Proprietary

4. First-aid measures

Inhalation:

Move to fresh air. If symptoms persist, get medical attention.

Skin contact:

Wash affected areas thoroughly with mild soap and water. If irritation persists get medical attention.

Eye contact:

Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention.

Ingestion:

If ingestion of a large amount does occur, seek medical attention.

Most important symptoms/effects, acute and delayed:

Not available.

5. Fire-fighting measures

Suitable extinguishing media:

CO2, water, dry chemical, or foam

Unsuitable extinguishing media:

None known.

Specific hazards arising from the chemical:

None known.

Special protective equipment and precautions for firefighters:

Not available.

Specific methods:

None established.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Wear appropriate personal protective equipment.

Methods and materials for containment and cleaning up:

Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps.

Environmental precautions:

Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

7. Handling and storage

Precautions for safe handling:

Avoid contact with skin, eyes and clothing.

Conditions for safe storage, including any incompatibilities:

Keep out of the reach of children. Keep away from excessive heat or cold.

8. Exposure controls/personal protection

Biological limit values:

No biological exposure limits noted for the ingredient(s).

Exposure guidelines:

Exposure limits have not been established for this product.

Appropriate engineering controls:

Use in a well ventilated area.

Individual protection measures, such as personal protective equipment:

Eye/face protection:

Not available.

Skin protection:

Hand protection:

Not available.

Other:

Use personal protective equipment to minimize exposure to skin and eye.

Respiratory protection:

Not available.

Thermal hazards:

Not available.

General hygiene considerations:

Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Appearance:

Physical state:

Liquid.

Form:

Not available.

Color:

Black.

Odor:

Not available.

Odor threshold:

Not available.

pH:

9.2

Melting point/freezing point:

Not available.

Initial boiling point and boiling range:

Not determined

Flash point:

> 230.0 °F (> 110.0 °C) Pensky-Martens Closed Cup

Evaporation rate:

Not determined

Flammability (solid, gas):

Not available.

Upper/lower flammability or explosive limits:

Flammability limit - lower (%):

Not determined

Flammability limit - upper (%):

Not available.

Explosive limit - lower (%):

Not available.

Explosive limit - upper (%):

Not available.

Vapor pressure:

Not determined

Vapor density:

> 1 (air=1)

Solubility(ies):

Solubility (water):

Soluble in water

Partition coefficient (n-octanol/water):

Not available.

Auto-ignition temperature:

Not determined

Decomposition temperature:

Not available.

Viscosity:

Not available.

Other information:

For other VOC regulatory data/information see Section 15.

Oxidizing properties:

Not determined

Percent volatile:

2.9 % estimated

Specific gravity:

1 - 1.1

VOC:

< 240 g/l

10. Stability and reactivity

Reactivity:

Not available.

Chemical stability:

Stable under recommended storage conditions.

Possibility of hazardous reactions:

Will not occur.

Conditions to avoid:

Not available.

Incompatible materials:

Incompatible with strong bases and oxidizing agents.

Hazardous decomposition products:

Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. hydrogen fluoride, fluorinated hydrocarbons

11. Toxicological information

Information on likely routes of exposure:

Inhalation:

Under normal conditions of intended use, this material is not expected to be an inhalation hazard.

Skin contact:

Contact with skin may result in mild irritation.

Eye contact:

Contact with eyes may result in mild irritation.

Ingestion:

Ingestion is not a likely route of exposure.

Symptoms related to the physical, chemical and toxicological characteristics:

Not available.

Information on toxicological effects:

Acute toxicity:

Based on available data, the classification criteria are not met.

Components:

Species Test Results
2-pyrrolidone (CAS 616-45-5)
Acute
Oral LD50 Rat > 5000 mg/kg

Skin corrosion/irritation:

Based on available data, the classification criteria are not met. Non irritant in rabbit (OECD 404)

Serious eye damage/eye irritation:

Based on available data, the classification criteria are not met. Not classified as an irritant according to, OECD 405.

Respiratory or skin sensitization:

Respiratory sensitization:

Based on available data, the classification criteria are not met.

Skin sensitization:

Based on available data, the classification criteria are not met.

Germ cell mutagenicity:

Based on available data, the classification criteria are not met.

Carcinogenicity:

Based on available data, the classification criteria are not met.

Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both organizations indicate that exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA.

IARC Monographs. Overall Evaluation of Carcinogenicity:

Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens:

Not listed.

Reproductive toxicity:

Based on available data, the classification criteria are not met.

2-pyrrolidone: This component showed developmental effects only at high, maternally toxic doses in test animals. Uptake by people of small doses is not expected to cause developmental toxicity.

Specific target organ toxicity - single exposure:

Based on available data, the classification criteria are not met.

Specific target organ toxicity - repeated exposure:

Based on available data, the classification criteria are not met.

Aspiration hazard:

Based on available data, the classification criteria are not met.

Further information:

Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures.

12. Ecological information

Aquatic toxicity:

Not expected to be harmful to aquatic organisms.

Ecotoxicity:

Product:

Species Test Results
C4906Series
Aquatic Acute
Fish LC50 Fathead minnow (Pimephales promelas) > 750 mg/l, 96 hours

Components:

Species Test Results
2-pyrrolidone (CAS 616-45-5)
Aquatic Crustacea EC50 Water flea (Daphnia pulex) 13.21 mg/l, 48 hours

Persistence and degradability:

Not available.

Bioaccumulative potential:

Not available.

Partition coefficient n-octanol / water (log Kow):

2-pyrrolidone:

-0.85

Mobility in soil:

Not available.

Other adverse effects:

Not available.

13. Disposal considerations

Disposal instructions:

Do not allow this material to drain into sewers/water supplies.

Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.

HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit http://www.hp.com/recycle.

14. Transport information

DOT:

UN number:

Not available.

UN proper shipping name:

Not Regulated

Transport hazard class(es):

Class:

Not available.

Subsidiary risk:

Not available.

Packing group:

Not available.

Environmental hazards:

Marine pollutant: No

Special precautions for user:

Not available.

IATA:

UN number:

Not available.

UN proper shipping name:

Not Regulated

Transport hazard class(es):

Class:

Not available.

Subsidiary risk:

Not available.

Packing group:

Not available.

Environmental hazards:

No

Special precautions for user:

Not available.

IMDG:

UN number:

Not available.

UN proper shipping name:

Not Regulated

Transport hazard class(es):

Class:

Not available.

Subsidiary risk:

Not available.

Packing group:

Not available.

Transport hazard class(es):

Marine pollutant: No

EmS:

Not available.

Special precautions for user:

Not available.

ADR:

UN number:

Not available.

UN proper shipping name:

Not Regulated

Transport hazard class(es):

Class:

Not available.

Subsidiary risk:

-

Hazard No. (ADR):

Not available.

Tunnel restriction code:

Not available.

Packing group:

Not available.

Environmental hazards:

No

Special precautions for user:

Not available.

Further information:

Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. Transport in bulk according to Annex II of MARPOL73/78 and the IBC code: Not applicable.

15. Regulatory information

US federal regulations:

US TSCA 12(b): Does not contain listed chemicals.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4): Not listed.

SARA 304 Emergency release notification: Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not regulated.

Superfund Amendments and Reauthorization Act of 1986 (SARA):

Hazard categories:

Immediate Hazard - No

Delayed Hazard - No

Fire Hazard - No

Pressure Hazard - No

Reactivity Hazard - No

SARA 302 Extremely hazardous substance:

Not listed.

SARA 311/312 Hazardous chemical:

Yes

Other federal regulations:

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated.

Safe Drinking Water Act (SDWA): Not regulated.

US state regulations:

Not Listed

Other information:

VOC content (less water, less exempt compounds) = < 958 g/L (U.S. requirement, not for emissions)

VOC data based on formulation (Organic compounds minus solids)

Regulatory information:

All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China.

16. Other information, including date of preparation or last revision

Issue date:

05-Mar-2015

Revision date:

29-Jan-2020

Version #:

06

Other information:

This SDS was prepared in accordance with USA OSHA Hazard Communications regulation (29 CFR 1910.1200).

Disclaimer:

This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries.

This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled, remanufactured, compatible or other non-HP Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment, exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs.

Revision information:

  • 1. Product and Company Identification: Product and Company Identification
  • Hazard(s) identification: Hazard(s) not otherwise classified (HNOC)
  • Hazard(s) identification: GHS Supplemental information
  • Composition/information on ingredients: Composition comments
  • Fire-fighting measures: Suitable extinguishing media
  • Exposure controls/personal protection: Other
  • Physical and chemical properties: Color
  • Stability and reactivity: Hazardous decomposition products
  • Toxicological information: Corrosivity
  • Toxicological information: Reproductivity
  • Toxicological information: Ingestion
  • Ecological information: Aquatic toxicity
  • Disposal considerations: Disposal instructions
  • Transport information: Further information

Explanation of abbreviations:

  • ACGIH: American Conference of Governmental Industrial Hygienists
  • CAS: Chemical Abstracts Service
  • CERCLA: Comprehensive Environmental Response Compensation and Liability Act
  • CFR: Code of Federal Regulations
  • COC: Cleveland Open Cup
  • DOT: Department of Transportation
  • EPCRA: Emergency Planning and Community Right-to-Know Act (aka SARA)
  • IARC: International Agency for Research on Cancer
  • NIOSH: National Institute for Occupational Safety and Health
  • NTP: National Toxicology Program
  • OSHA: Occupational Safety and Health Administration
  • PEL: Permissible Exposure Limit
  • RCRA: Resource Conservation and Recovery Act
  • REC: Recommended
  • REL: Recommended Exposure Limit
  • SARA: Superfund Amendments and Reauthorization Act of 1986
  • STEL: Short-Term Exposure Limit
  • TCLP: Toxicity Characteristics Leaching Procedure
  • TLV: Threshold Limit Value
  • TSCA: Toxic Substances Control Act
  • VOC: Volatile Organic Compounds

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