Antialgas Extra - Safety Data Sheet

Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

1.1 Product Identifier

Product Name: Antialgas Extra

1.2 Relevant Identified Uses

Algaecide. Uses advised against: Uses other than those recommended.

1.3 Details of the Supplier

Company: FLUIDRA COMMERCIAL, S.A.U.

Address: Av. Alcalde Barnils, 69, 08174 Sant Cugat del Vallès (Barcelona) Spain

Telephone: +34 93 724 39 00, Fax: +34 93 724 29 93

Email: fds@inquide.com, Web: www.astralpool.com

1.4 Emergency Telephone Number

+34 93 724 39 00 (Office hours: Monday-Friday; 08:00-18:00)

Anti poisoning centres: ITALY (Rome): 06/305 43 43, ITALY (Milan): 02/66 10 10 29, SPAIN: +34 91 562 04 20, FRANCE (Paris): 01 40 05 48 48, FRANCE (Tolousse): 05 61 77 74 47, FRANCE (Marseille): 04 91 75 25 25, PORTUGAL: 808 250 143, BELGIQUE (Brussel): (+34) 070 245 245. CAV accredited: Roma +39 06 68 59 3726; Foggia +39 800 18 34 59; Napoli +39 081 54 53 333; Roma +39 06 49 97 80 00; Roma +39 06 30 54 343; Firenze +39 055 79 47 819; Pavia +39 0382 24 444; Milano +39 02 66 10 10 29; Bergamo +39 800 88 33 00; Verona +39 800 01 18 58.

Section 2: Hazards Identification

2.1 Classification of the Substance or Mixture

In accordance with Regulation (EU) No 1272/2008: Aquatic Chronic 1: Very toxic to aquatic life with long lasting effects.

2.2 Label Elements

Labelling in accordance with Regulation (EU) No 1272/2008:

Pictograms: ⚠️ [Environment Hazard Symbol]

Signal Word: Warning

Hazard Statements: H410 - Very toxic to aquatic life with long lasting effects.

Precautionary Statements:

• P102: Keep out of reach of children.
• P273: Avoid release to the environment.
• P391: Collect spillage.

2.3 Other Hazards

The mixture does not contain substances classified as PBT or vPvB. It does not contain endocrine disrupting properties substances. In normal use, the product does not involve other risks for health and the environment.

Section 3: Composition/Information on Ingredients

3.1 Substances

Not Applicable.

3.2 Mixtures

Substances posing a danger to health or the environment in accordance with Regulation (EC) No. 1272/2008:

Section 4: First Aid Measures

4.1 Description of First Aid Measures

In case of doubt or when symptoms persist, get medical attention. Never administer anything orally to unconscious persons.

Inhalation

Move victim to fresh air; keep warm and calm. If breathing is irregular or stops, perform artificial respiration.

Eye Contact

Remove contact lenses if present and easy to do. Wash eyes with plenty of clean, cool water for at least 10 minutes, pulling eyelids up. Seek medical assistance.

Skin Contact

Remove contaminated clothing. Wash skin vigorously with water and soap or a suitable skin cleaner. Never use solvents or thinners.

Ingestion

If accidentally ingested, seek immediate medical attention. Keep calm. Never induce vomiting.

4.2 Most Important Symptoms and Effects

No known acute or delayed effects from exposure.

4.3 Indication of Immediate Medical Attention and Special Treatment

In case of doubt or when symptoms persist, get medical attention. Never administer anything orally to unconscious persons.

Section 5: Firefighting Measures

The product is NOT classified as flammable.

5.1 Extinguishing Media

Suitable: Extinguisher powder, CO2, alcohol-resistant foam, water spray. Unsuitable: Direct water stream. Do not use water or foam if electrical voltage is present.

5.2 Special Hazards Arising from the Substance or Mixture

Exposure to combustion or decomposition products can be harmful.

5.3 Advice for Firefighters

Use water to cool tanks, cisterns, or containers near the fire. Consider wind direction. Prevent fire-fighting products from entering drains, sewers, or waterways. Product residues may contaminate the aquatic environment.

Fire Protection Equipment

Use protective suits, breathing equipment, gloves, goggles, or facemasks as necessary for the fire size.

Section 6: Accidental Release Measures

6.1 Personal Precautions, Protective Equipment, and Emergency Procedures

See section 8 for exposure control and personal protection.

6.2 Environmental Precautions

Product is dangerous for the environment. For large spills or contamination of water bodies, inform responsible authorities. Prevent contamination of drains, surface/subterranean waters, and the ground.

6.3 Methods and Material for Containment and Cleaning Up

Contain and collect spillage with inert absorbent material (earth, sand, vermiculite, Kieselguhr). Clean the area with a suitable decontaminant. Deposit waste in closed, suitable containers for disposal according to local/national regulations (see section 13).

6.4 Reference to Other Sections

See section 8 for exposure control and personal protection. See section 13 for waste disposal recommendations.

Section 7: Handling and Storage

7.1 Precautions for Safe Handling

See section 8 for personal protection. Prohibit smoking, eating, and drinking in the application area. Follow occupational health and safety legislation. Do not use pressure to empty containers; they are not pressure-resistant. Keep product in original material containers.

7.2 Conditions for Safe Storage, Including Any Incompatibilities

Store according to local legislation and label indications. Store containers between 5-25°C in a dry, well-ventilated place, away from heat and direct sunlight. Keep away from ignition points, oxidising agents, and highly acidic or alkaline materials. Do not smoke. Prevent entry of unauthorised persons. Close opened containers carefully and keep them upright to prevent spills.

Classification and threshold amount of storage in accordance with Annex I to Directive 2012/18/EU (SEVESO III): E1

Section 8: Exposure Controls/Personal Protection

8.1 Control Parameters

The product does not contain substances with Professional Exposure Environmental Limit Values or Biological Limit Values.

8.2 Exposure Controls

Measures of a technical nature: Provide adequate ventilation using good local exhaust-ventilation and a good general exhaust system.

Concentration: 100%

Uses: Algaecide

Breathing Protection

PPE: Particle filter mask. Characteristics: CE marking, category III. Made of filtering material covering nose, mouth, and chin. CEN standards: EN 149. Maintenance: Check for tears/defects before use. Replace after use as it's disposable. Observations: Does not protect unless properly adjusted. Follow manufacturer's instructions. Filter Type needed: P2.

Hand Protection

PPE: Protective gloves against chemicals. Characteristics: CE marking, category III. CEN standards: EN 374-1, EN 374-2, EN 374-3, EN 420. Maintenance: Store in a dry place away from heat and sunlight. Do not alter gloves. Observations: Gloves should be appropriate size, fit well, and be used with clean, dry hands. Material: PVC (polyvinyl chloride). Breakthrough time: > 480 min. Material thickness: 0.35 mm.

Eye Protection

PPE: Protective goggles with built-in frame. Characteristics: CE marking, category II. Protects against dust, smoke, fog, and vapour. CEN standards: EN 165, EN 166, EN 167, EN 168. Maintenance: Clean daily. Disinfect periodically per manufacturer. Observations: Signs of wear include yellowing lenses, scratches.

Skin Protection

PPE: Chemical protective clothing. Characteristics: CE marking, category III. Protection level based on BT (Breakthrough Time). CEN standards: EN 464, EN 340, EN 943-1, EN 943-2, EN ISO 6529, EN ISO 6530, EN 13034. Maintenance: Follow manufacturer's washing and maintenance instructions. Observations: Clothing design should facilitate correct positioning and stay in place.

Footwear

PPE: Work footwear. Characteristics: CE marking, category II. CEN standards: EN ISO 13287, EN 20347. Observations: Adapts to user's foot shape; should not be used by others for hygiene reasons. Includes protection elements against injury.

Section 9: Physical and Chemical Properties

9.1 Information on Basic Physical and Chemical Properties

Physical state: Liquid. Colour: Dark blue. Odour: Characteristic (organic). Odour threshold: Not applicable. Melting point: Not applicable. Freezing point: Not applicable. Boiling point/range: >100 °C. Flammability: Not applicable. Lower/Upper explosion limit: Not applicable. Flash point: Not applicable. Auto-ignition temperature: Not applicable. Decomposition temperature: Not applicable. pH: 5.5 - 8.5 (20 °C). Kinematic viscosity: Not applicable. Solubility: Not applicable. Hydrosolubility: Not applicable. Liposolubility: Not applicable. Partition coefficient n-octanol/water: Not applicable. Vapour pressure: 23.248 (estimated). Absolute density: Not applicable. Relative density: 0.98 - 1.08 (20 °C). Relative vapour density: Not applicable. Particle characteristics: Not applicable.

9.2 Other Information

Viscosity: Not applicable. Explosive properties: Not applicable. Oxidizing properties: Not applicable. Dropping point: Not applicable. Blink: Not applicable.

Section 10: Stability and Reactivity

10.1 Reactivity

The product does not present hazards by its reactivity.

10.2 Chemical Stability

Unstable in contact with bases.

10.3 Possibility of Hazardous Reactions

Neutralization can occur on contact with bases.

10.4 Conditions to Avoid

Avoid contact with bases.

10.5 Incompatible Materials

Avoid the following materials: Bases.

10.6 Hazardous Decomposition Products

Depending on conditions of use, can generate corrosive vapors or gases.

Section 11: Toxicological Information

11.1 Information on Hazard Classes as Defined in Regulation (EC) No 1272/2008

Toxicological information about the substances present in the composition:

11.2 Information on Other Hazards

Endocrine disrupting properties: This product does not contain components with endocrine-disrupting properties affecting human health. Other information: No information available on other adverse health effects.

Section 12: Ecological Information

12.1 Toxicity

Ecotoxicity data for polyalkyl quaternary ammonium:

12.2 Persistence and Degradability

No information available on biodegradability, degradability, or persistence of the product.

12.3 Bioaccumulative Potential

No information available on bioaccumulation.

12.4 Mobility in Soil

No information available on mobility in soil. The product must not enter sewers or waterways. Prevent penetration into the ground.

12.5 Results of PBT and vPvB Assessment

No information available.

12.6 Endocrine Disrupting Properties

This product does not contain components with environmental endocrine disrupting properties.

12.7 Other Adverse Effects

No information available on other adverse environmental effects.

Section 13: Disposal Considerations

13.1 Waste Treatment Methods

Do not dump into sewers or waterways. Handle and eliminate waste and empty containers according to current, local/national legislation. Follow Directive 2008/98/EC regarding waste management.

Section 14: Transport Information

Transport follows ADR (road), RID (railway), ADN (inland waterways), IMDG (sea), and ICAO/IATA (air) rules.

Land Transport

Road: ADR. Rail: RID. Documentation: Consignment note and written instructions.

Sea Transport

Ship: IMDG. Documentation: Bill of lading.

Air Transport

Plane: ICAO/IATA. Document: Airway bill.

14.1 UN Number or ID Number

UN No: UN3082

14.2 UN Proper Shipping Name

Description: ADR/RID: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS POLYALKYL QUATERNARY AMMONIUM), 9, PG III. IMDG: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS POLYALKYL QUATERNARY AMMONIUM), 9, PG III, MARINE POLLUTANT. ICAO/IATA: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS POLYALKYL QUATERNARY AMMONIUM), 9, PG III.

14.3 Transport Hazard Class(es)

Class(es): 9

14.4 Packing Group

Packing group: III

14.5 Environmental Hazards

Marine pollutant: Yes. Dangerous for the environment. Transport by ship, Emergency sheets (Fire): F-A, (Spills): S-F.

14.6 Special Precautions for User

Labels: 9. Hazard number: 90. ADR LQ: 5 L. IMDG LQ: 5 L. ICAO LQ: 30 kg B. Provisions concerning carriage in bulk ADR: Not authorized. Proceed in accordance with point 6.

14.7 Maritime Transport in Bulk

The product is not transported in bulk.

Section 15: Regulatory Information

15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture

The product is not affected by Regulation (EC) No 1005/2009 (ozone layer). Product classification according to Annex I of Directive 2012/18/EU (SEVESO III): E1.

Information related to Regulation (EU) No 528/2012 (biocidal products): Product Type: Disinfectants and algaecides not intended for direct application to humans or animals. Group: Disinfectants.

Active substances: polyalkyl quaternary ammonium, 11.28%. The product is not affected by Regulation (EU) No 649/2012 (export/import of dangerous chemicals). Kind of pollutant to water (Germany): nwg: Non-hazardous to water.

15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out by the supplier.

Section 16: Other Information

Complete Text of H Phrases

H302: Harmful if swallowed. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects.

Classification Codes

Acute Tox. 4: Acute toxicity (Oral), Category 4. Aquatic Acute 1: Acute toxicity to the aquatic environment, Category 1. Aquatic Chronic 1: Chronic effect to the aquatic environment, Category 1.

Changes Regarding Previous Version

• Modification of specific hazards (SECTION 2.3).
• Modification in firefighting measures (SECTION 5.2).
• Modifications in accidental release measures (SECTION 6.1, 6.2).
• Modification in physical and chemical properties (SECTION 9).
• Change in hazard classification (SECTION 11.1).
• Modification of classification ADR/IMDG/ICAO/IATA/RID (SECTION 14).
• Addition of abbreviations and acronyms (SECTION 16).

Classification and Procedure Used to Derive Classification for Mixtures according to Regulation (EC) 1272/2008 [CLP]

Basic training regarding health and safety at work is advisable for handling this product.

Abbreviations and Acronyms Used

• ADR/RID: European Agreement concerning the International Carriage of Dangerous Goods by Road.
• AwSV: Facility Regulations for handling substances that are hazardous for the water.
• CEN: European Committee for Standardization.
• EC50: Half maximal effective concentration.
• PPE: Personal protection equipment.
• IATA: International Air Transport Association.
• ICAO: International Civil Aviation Organization.
• IMDG: International Maritime Code for Dangerous Goods.
• LC50: Lethal concentration, 50%.
• LD50: Lethal dose, 50%.
• RID: Regulations Concerning the International Transport of Dangerous Goods by Rail.
• WGK: Water hazard classes.

Key Literature References and Sources for Data

• http://eur-lex.europa.eu/homepage.html
• http://echa.europa.eu/
• Regulation (EU) 2020/878.
• Regulation (EC) No 1907/2006.
• Regulation (EU) No 1272/2008.

The information in this Safety Data Sheet has been drafted in accordance with COMMISSION REGULATION (EU) 2020/878. The information is based on current knowledge and EC/national laws. The user is responsible for taking appropriate measures to comply with current legislation. This sheet describes safety requirements and does not guarantee properties.