TotalBoat Gelcoat With or Without Wax | Marine Gelcoats (2023)
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DocumentDocumentTOTALBOAT GELCOAT - BLACK SAFETY DATA SHEET TO COMPLY WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR.1910.1200 & THE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS 1. Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product Identifier Product Form: Substance Substance Name: TotalBoat Gelcoat - Black Product Code(s): TB-1109 Chemical Family: Aromatic Synonyms: Not Available 1.2 Distributor Details TOTALBOAT LLC 17 Peckham Drive Bristol, RI 02809 T 800-497-0010 1.3 Emergency Telephone Number Emergency Number: INFOTRAC: Domestic - 800-535-5053 2. Hazards Identification This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) 2.1 Classification of the Substance or Mixture Flammable liquid and vapor. Category 3, H226 Acute toxicity Inhalation Category 4, H332 Eye irritation Category 2, H319 Skin irritation Category 2, H315 STOT-SE = Specific Target Organ Toxicity Single Exposure Category 3, H335 STOT-RE = Specific Target Organ Toxicity Repeated Exposure Category 1, H372 2.2 Label Elements GHS-US Labeling: Signal Word (GHS-US): Hazard Statement: February 16, 2022 DANGER H226-Flammable liquid vapor H315-Causes skin irritation TOTALBOAT GELCOAT - BLACK Page 1 H319-Causes serious eye irritation H332-Harmful if inhaled H335-May cause respiratory irritation H372-Causes damage to organs through prolonged or repeated exposure if inhaled H304-May be fatal if swallowed and enters airways Precautionary Statements (GHS-US) General P101-If medical advice is needed, have product container or label at hand P102-Keep out of reach of children Prevention P210-Keep away from heat/sparks/open flames/hot surfaces. NO smoking P233-Keep container tightly closed P240-Ground/bond container and receiving equipment P241-Use explosion-proof electrical/ventilating/lighting/equipment P242-Use only non-sparking tools P243-Take precautionary measures against static discharge P280-Wear protective gloves/protective clothing/eye protection/face protection P264-Wash with water thoroughly after handling P271-Use only outdoors or in a well-ventilated area P270-Do not eat, drink or smoke when using this product P261-Do not breathe vapor or mist Response: P370+P378-In case of fire: Use DRY chemicals, CO², water spray foam P308+P313-IF exposed or concerned: Get medical attention P304+P340+P312-IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P333+P313-If skin irritation occurs: Get medical attention P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313-If eye irritation persists: Get medical attention/advice P391-Collect spillage Storage: P403+P235-Store in a well-ventilated place. Keep cool P233-Keep container tightly closed P405-Store locked up Disposal: P501-Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3 Other Hazards Hazards not otherwise classified: None known 3. Composition/Information on Ingredients 3.1. Substances: Mixture Component Styrene Carbon Black Methyl Methacrylate Talc Silica, Amorphous Cobalt 2-Ethylhexanoate Concentration (%) 31-33 10 - <25 6.3 5 - <10 1 - <3 0.1 - <0.3 CAS Number 100-42-5 1333-86-4 80-62-6 14807-96-6 7631-86-9 136-52-7 February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 2 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupation exposure limits, if available, are listed in Section 8. 4. First Aid Measures 4.1. First Aid Measures Inhalation: Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Ingestion: Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Seek immediate medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby shampoo will aid in removal. If irritation persists, get medical attention. Most important symptoms/effects, Acute and Delayed: EYE CONTACT: Causes serious eye irritation INHALATION: Harmful if inhaled. May cause respiratory irritation. SKIN CONTACT: Causes skin irritation. INGESTION: Irritating to mouth, throat and stomach. Over-exposure signs/symptoms: EYE CONTACT: Adverse symptoms may include the following: pain or irritation, watering, redness INHALATION: Adverse symptoms may include the following: respiratory tract irritation, coughing SKIN CONTACT: Adverse symptoms may include the following: irritation, redness INGESTION: Adverse symptoms may include the following: irritating to mouth, throat and stomach Notes for physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. SEE TOXICOLOGICAL INFORMATION (SECTION 11) 5. Fire Fighting Measures EXTINGUISHING MEDIA 5.1. Suitable Extinguishing Media Use dry chemical, CO², water spray (fog) or foam 5.2. Unsuitable Extinguishing Media Do not use water jet 5.3. Special Hazards Arising from the Chemical Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. 5.4. Hazardous Thermal Decomposition Products February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 3 Decomposition products may include the following materials: carbon dioxide, carbon monoxide, sulfur oxides, halogenated compounds, metal oxide/oxides 5.5. Special protective actions for fire-fighters Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain 5.6. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures 6.1. For non-emergency personnel No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. 6.2. For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in `For non-emergency personnel' 6.3. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up 6.4. Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. 6.5. Large spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: See Section 1 for emergency contact information and Section 13 for waste disposal. 7. Handling and Storage Precautions for safe handling 7.1. Protective measures Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Sore and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. 7.2. Advice on general occupational hygiene February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 4 Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.3. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information. 8. Exposure Controls/Personal Protection Control Parameters 8.1. Occupational Exposure Limits Component Styrene Methyl Methacrylate Talc Silica, Amorphous Cobalt 2-Ethylhexanoate Exposure Limits ACGIH TLV (United States, 3/2012) Absorbed through skin TWA: 20 ppm 8 hours TWA: 85 mg/m³ 8 hours STEL: 40 ppm 15 minutes STEL: 170 mg/m³ 15 minutes OSHA PEL Z2 (United States, 11/2006). TWA: 100 ppm 8 hours AMP: 600 ppm 5 minutes CEIL: 200 ppm NIOSH REL (United States, 6/2009). TWA: 50 ppm 10 hours TWA: 215 mg/m³ 10 hours STEL: 100 ppm 15 minutes STEL: 425 mg/m³ 15 minutes ACGIH TLV (United States, 3/2012) Skin sensitizer TWA: 50 ppm 8 hours TWA: 205 mg/m³ 8 hours STEL: 100 ppm 15 minutes STEL: 410 mg/m³ 8 hours NIOSH REL (United States, 6/2009). TWA: 100 ppm 10 hours TWA: 410 mg/m³ 10 hours OSHA PEL (United States, 6/2010). TWA: 100 ppm 8 hours TWA: 410 mg/m³ 8 hours NIOSH REL (United States, 6/2008). TWA: 2 mg/m³ 10 hours Form: Respirable fraction OSHA PEL Z3 (United States, 9/2005). : 1 f/cc 30 minutes. Form: not containing asbestos TWA: 20 mppcf 8 hours Form: not containing asbestos ACGIH TLV (United States, 1/2008). TWA: 0.1 f/cc 8 hours NIOSH REL (United States, 6/2009). TWA: 6 mg/m³ 10 hours OSHA PEL (United States). TWA: 0.1 mg/m³ Appropriate engineering controls: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 5 any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. 8.2. Individual protection measures Eye/Face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Hygiene measures: Hand protection: Body protection: Other skin protection: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and Chemical Properties 9.1. Information on Basic Physical and Chemical Properties Physical state: Liquid Color: Black Odor: Aromatic Odor Threshold: 0.01 0.1 ppm (styrene) pH: Not applicable Evaporation rate: <1 (Butyl acetate = 1) Melting Point: -23.8°F (-30.6°C) (styrene) Boiling point: 293°F (145°C) (styrene) Flash point: 88°F (31°C) (styrene) Auto-ignition Temperature: 914°F (490°C) (styrene) Decomposition Temperature: Not available Flammability (solid, gas): Not applicable Vapor pressure: 5.0 mm Hg@ 68°F (20°C) (styrene) Vapor density: 3.6 (Air = 1) (styrene) Relative density: 1.1 - 1.4 (water=1) Solubility: Slight Partition coefficient N-Octanol/water: Not available Viscosity: Not available Molecular Weight: 10,000 to 15,000 Explosive Limits: Upper - 6.1% Lower 1.1% (styrene) February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 6 9.2. Other Information None available 10. Stability and Reactivity 10.1. Reactivity No specific test data related to reactivity available for this product or its ingredients 10.2. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur 10.3. Chemical Stability This product is stable. Stable under recommended storage and handling conditions (see Section 7) 10.4. Conditions to Avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition 10.5. Incompatible Materials Reactive or incompatible with the following materials: oxidizing materials 10.6. Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. 11. Toxicological Information 11.1. Information on Toxicological Effects Acute toxicity Component Result Styrene LC50 Inhalation Gas. LC50 Inhalation Vapor LD50 Oral Methyl Methacrylate LC50 Inhalation Gas. LC50 Inhalation Vapor LD50 Dermal LD50 Oral Cobalt 2- LD50 Dermal Ethylhexanoate LD50 Oral LD50 Oral Species Rat Rat Rat Rat Rat Rabbit Rat Rabbit Rat Rat Dose 2770 ppm 11800 mg/m³ 2650 mg/kg 7094 ppm 78000 mg/m³ >5 g/kg 7872 mg/kg >5 g/kg 1.22 g/kg 6171 mg/kg Exposure 4 hours 4 hours ------ 4 hours 4 hours ----------- ---------------- Irritation/Corrosion Component Result Styrene Eyes Mild irritant Eyes Moderate irritant Eyes Severe irritant Skin Mild irritant Skin Moderate irritant Silica/Amorphous Eyes Mild irritant Species Human Rabbit Rabbit Rabbit Rabbit Score -------------------------- Rabbit ------ Exposure 50 ppm 24 hours 100 milligrams 100 milligrams 500 milligrams 100 Percent 24 hours 25 milligrams Observation -------------------------- ------ Sensitization: May cause sensitization by skin contact Carcinogenicity Classification Component Styrene Methyl Methacrylate ACGIH ----------- IARC 2B 3 NTP Reasonably anticipated to be a human carcinogen ------ February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 7 Talc ------ 1 Known to be a human carcinogen Silica, Amorphous ------ 3 ------ Cobalt 2-Ethylhexanoate ------ 2B ------ 1. Negative Study: A published study concluded that the mechanism for producing cancer in mice exposed to styrene is not applicable in human metabolism. (June 2013 Pharmacology & Toxicology 66 (2013)) 2. Negative Study: A recent update to an extensive study or reinforced plastic workers from 1948-1977 concluded that there was no coherent evidence that styrene exposure increased risk of cancer (March 2013 Epidemiology Vol. 24 Issue 2). 3. Positive Study: Styrene induced pulmonary toxicity and carcinogenicity in mice was shown to be caused by a metabolite of styrene, probably styrene oxide. (Dec. 2001 Toxicology Vol. 169 Issue 2). Mutagenicity: No mutagenic effect Reproductive toxicity: Not considered to be toxic to the reproductive system Teratogenicity: No known effect according to our database Specific target organ toxicity (single exposure): No known effect according to our database Specific target organ toxicity (repeated exposure): A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a possible mild hearing loss. Aspiration hazard: No known effect according to our database Potential acute health effects Eye contact: No known effect according to our database Inhalation: Harmful if inhaled. May cause respiratory irritation. Skin contact: Causes skin irritation Ingestion: Irritating to mouth, throat and stomach Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Adverse symptoms may include the following: pain or irritation, watering, redness Inhalation: Adverse symptoms may include the following: respiratory tract irritation, coughing Skin contact: Adverse symptoms may include the following: irritation, redness Ingestion: Adverse symptoms may include the following: irritating to mouth, throat and stomach 12. Ecological Information 12.1. Toxicity Component Styrene Methyl Methacrylate Result Acute EC50 4.7 mg/l Fresh water Acute LC50 4.02 mg/l Fresh water Acute LC50 130000 µg/l Fresh water Species Daphnia-Daphnia magna Fish- Pimephales promelas Fish- Pimephales promelas Adult Exposure 48 hours 96 hours 96 hours 12.2. Persistence and Degradability Component Test Result Styrene EU 100% - Readily- 1 days Dose ------ Inoculum ------ Component Styrene Aquatic half-life ------ Photolysis ------ Biodegradability Readily 12.3. Bio-Accumulative Potential Component Styrene Methyl Methacrylate LogPow 2.95 1.38 BCF 13.49 ------ Potential low low 12.4. Mobility in Soil NA 12.5. Other Adverse Effects February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 8 No known effect according to our database 13. Disposal Considerations 13.1. Waste Treatment Methods Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Special precautions: This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 14. Transport Information 14.1 UN Number UN-No. (DOT): 14.2 UN Proper Shipping Name DOT Proper Shipping Name: DOT Hazard Class: Environmental hazards: 1866 Resin Solution 3-Class 3-Flammable and combustible liquid 49 CFR 173.120 Marine Pollutant: NO Hazard Labels (DOT): Packing Group (DOT): Special precautions for user: 14.3 Additional Information Other Information: III Transport within user's premises: Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident of spillage. No supplementary information available 15. Regulatory Information 15.1. Inventories (National and International) United States Inventory (TSCA 8b): All Components are listed or exempted. Australia: Not determined Canada: All Components are listed or exempted. China: All Components are listed or exempted. Europe: Not determined New Zealand: Not determined Philippines: Not determined Japan: Not determined Malaysia: Not determined Republic of Korea: All Components are listed or exempted. February 16, 2022 TOTALBOAT GELCOAT - BLACK Page 9 Taiwan: Not determined SARA 311/312 Composition/information on ingredients Name Fire Sudden release Reactive Hazard of pressure Styrene Yes No No Methyl Methacrylate Yes No No Talc No No No Silica, Amorphous No No No Cobalt 2-Ethylhexanoate No No No Immediate (acute) health hazard No Yes No Yes Yes Delayed (chronic) health hazard Yes No Yes No Yes SARA 313 Form R Reporting requirements Product Name Styrene Methyl Methacrylate Cobalt 2-Ethylhexanoate CAS Number 100-42-5 80-62-6 136-52-7 State regulations Prop65 WARNING: This product can expose you to chemicals including styrene which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov 15. Other Information 3 2 1 HMIS III Rating Health: Flammability: Physical: Personal Protection: 2-Moderate Hazard 3-Serious Hazard 1-Slight Hazard C TotalBoat believes the law requires us to inform you that detectable amounts of any of the listed chemicals might be present in TotalBoat products. Based on a review of the list, TotalBoat products, like all synthetic and naturally occurring chemical substances, may conceivably contain trace contaminants of some of the listed substances. While not necessarily added to our products as ingredients, some of the listed chemicals may be present in the raw materials as received from suppliers over which we have no control. Preparation Date: 2/16/2022 Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and TotalBoat LLC assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 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