Safety Data Sheet
HI-BK434-D
Information Sheet Revision 5.0, Page 1 of 11
Date of issue: 18/7/2022, Revised: 10/7/2025
1-Identification of the substance/preparation and of the company/undertaking
1.1 Product identifier
Product name: Pigment Ink
Product type/code: HI-BK434-D
1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance/the preparation: Ink-Jet Printing
1.3 Details of the supplier of the safety data sheet
Information not available.
1.4 Emergency telephone number
Oversea sales department: Tel: , Fax:
Emergency Phone:
2-Hazards Identification
2.1 Classification of the substance or mixture:
This product is not classified as hazard substance according to Regulation (EC) No 1272/2008 (CLP).
Regulation (EC) No 1272/2008 (CLP) and following amendments and adjustments.
Hazard classification and indication: --
2.2 Label elements
Hazard labelling pursuant to Regulation (EC) No 1272/2008 (CLP) and subsequent amendments and supplements.
- Hazard pictograms: --
- Signal words: --
- Hazard statements: --
Precautionary statements:
- P101 If medical advice is needed have product container or label at hand.
- P102 Keep out of reach of children.
2.3 Other hazards
Results of PBT and vPvB assessment: The mixture does not contain any substance which meet the criteria for PBT or vPvB in accordance with Annex XIII of the Regulation (EC) No.1907/2006 (REACH) as amended.
Results of endocrine disruptor: The mixture does not contain substances with endocrine disrupting properties in accordance with the criteria set out in the Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.
3-Composition/Information on Ingredients
3.1 Substances
Information not available.
3.2 Mixtures
Containing of the following components. The classification is mainly based on pure substance. The concentration of the substance in the mixture is very lower than the pure substance. The main substance in the mixture is water.
| CAS No / EC No | Components / Formula / classification / Specific Conc. Limits, M-factors | Range of concentration |
|---|---|---|
| Trade secret | Black Pigment / | 0.1%-5% |
| CAS: 56-81-5 EC: 200-289-5 |
Glycerol C3H8O3 / | 0.1%-9% |
| CAS: 143-22-6 EC: 205-592-6 |
Triethylene glycol monobutyl ether C10H22O4 Eye Dam. 1 H318 Eye Dam. 1 H318: C ≥ 30% Eye Irrit. 2 H319: 20% < C < 30% |
0.1%-9% |
| CAS: 3445-11-2 EC: 222-359-4 |
1-(2-hydroxyethyl)pyrrolidin-2-one C6H11NO2 / | 5%-15% |
| CAS: 7732-18-5 | Water H2O / | 50%-90% |
4-First Aid Measures
4.1 Description of first aid measures
In case of contact, ingestion or inhalation, the following general measures provided for a fist aid shall be taken.
- After eyes contact: Do not rub eyes. Immediately flush eyes with large amounts of clean, warm water (low pressure) for at least 15 minutes. If the irritation persists, seek medical advice.
- After skin contact: Immediately wash affected areas with mild soap and water. If the irritation persists, seek medical advice.
- After ingestion: Ingestion is not an expected route of exposure during normal use of the product. If ingested, seek medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person.
- After inhalation: Remove to fresh air. If respiration is difficult, administer artificial respiration and seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
Follow doctor's orders.
5- Firefighting measures
5.1 Extinguishing media
- Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or regular foam.
- Extinguishing media which shall not be used for safety reasons: No Information Available.
5.2 Special hazards arising from the substance or mixture:
Product is a nonflammable water-based solution.
Hazardous combustion products (gases/vapors) produced in fire can include carbon monoxide, carbon dioxide, nitrogen oxides, and smoke.
Flash point and method: >93.3℃ (>200°F) Closed Cup
Approximate Flammable Limits in Air,%by Volume: Not available
Autoignition Temperature: Not available
5.3 Advice for firefighters
This product is not flammable. Use normal firefighting procedures for the area.
6-Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear appropriate personal protective measures, avoid contact eyes and skin. Keep unprotected persons away.
6.2 Environmental precautions
The product must not penetrate the sewer system, surface water, ground water and neighbouring areas. Avoid birds or fish ingestion from drainage system, please thoroughly recycle.
6.3 Methods and material for containment and cleaning up
Transfer the leaked products to container. Absorb with inert absorbent such as dry, sand or diatomaceous earth, commercial sorbents, or recover using pumps.
Flush a small amount of residue with large amounts of water and detergent.
6.4 Reference to other sections
Any information about personal protection and disposal is given in sections 8 and 13.
7 - Handling and Storage
7.1 Information for safe handling
Wear appropriate personal protective measures, avoid contact eyes and skin. Ventilation is well and far away from heat.
Information about fire-and explosion protection
Do not spray onto a naked flame or any incandescent material. Keep ignition sources away. Do not smoke. Protect against electrostatic charges.
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
- Keep away from excessively alternate heat and cold, direct sunniness.
- Keep away from strong acid, strong base and strong oxidizing agent.
- Keep away from incompatible substance or mixtures.
- Store in a cool, dry, ventilated area.
Further information about storage conditions:
- Keep container tightly sealed.
- Keep out of the reach of children.
7.3 Specific end use(s)
No further relevant information available.
8-Exposure Controls, Personal Protection
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Information about design of technical facilities: To provide proper ventilation, use adequate general or local exhaust ventilation.
Ingredients with limit values that require monitoring at the workplace: No data available
Personal protective equipment:
- Respiratory protection: Respirators are not needed for normal use.
- Eye/Face protection: Wear safety glasses. Wear coverall chemical splash goggles and face shield when the possibility exists for eye and face contact due to splashing or spraying of the material.
- Body protection: If there is potential for significant dermal contact, wear appropriate impervious clothing and gloves.
9-Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
- Physical state: Liquid
- Colour: Black
- Odour: Slight
- Odour threshold: No data available
- Melting point/freezing point:
- Melting point: No data available
- Freezing point: No data available
- Boiling point or initial boiling point and boiling range: No data available
- Flammability: No data available
- Lower and upper explosion limit: No data available
- Flash point: >93.3℃ (>200°F) Pensky-Martens Closed Cup
- Auto-ignition temperature: No data available
- Decomposition temperature: No data available
- pH: 7-9
- Kinematic viscosity: >1cp
- Solubility: Soluble in water
- Partition coefficient n-octanol/water (log value): No data available
- Vapour pressure: No data available
- Density and/or relative density: Density at 20 ℃ (68 °F): 1 g/cm³(>8.345 lbs/gal) SG: 1.3-1.8
- Relative vapour density: No data available
9.2 Other information
Particle characteristics: Not applicable
9.2.1 Information with regard to physical hazard classes
No further relevant information available.
9.2.2 Other safety characteristics
No further relevant information available.
10-Stability and Reactivity
10.1 Reactivity
There are no particular risks of reaction with other substances in normal conditions of use.
10.2 Chemical stability
The product is stable in normal conditions of use and storage.
10.3 Possibility of hazardous reactions
Polymerization will not occur. No hazardous reactions are foreseeable in normal conditions of use and storage.
10.4 Conditions to avoid
No further relevant information available.
10.5 Incompatible materials
No further relevant information available.
10.6 Hazardous decomposition products
No decomposition reaction occure in normal conditions of use and storage.
11-Toxicological Information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
| PEL (OSHA): | TLV (ACGIH): | LD50 (rat, oral) : | LC50 (rat, inhalation/4 hr.): | |
|---|---|---|---|---|
| Glycerol | None Established | None Established | 27 200 mg/kg (RTECS) | 5.85 mg/L air |
| Triethylene glycol monobutyl ether | None Established | None Established | 5 000 - 11 300 mg/kg (RTECS) | No data available |
| 1-(2-hydroxyethyl)pyrrolidin-2-one | None Established | None Established | 7300 mg/kg (RTECS) | No data available |
| WATER | None Established | None Established | No data available | No data available |
Skin corrosion/irritation Does not meet the classification criteria for this hazard class.
Serious eye damage/irritation Does not meet the classification criteria for this hazard class.
Respiratory or skin sensitisation: Does not meet the classification criteria for this hazard class.
Germ cell mutagenicity Does not meet the classification criteria for this hazard class.
Carcinogenicity Does not meet the classification criteria for this hazard class.
Reproductive toxicity Does not meet the classification criteria for this hazard class.
STOT-single exposure Does not meet the classification criteria for this hazard class.
STOT-repeated exposure Does not meet the classification criteria for this hazard class.
Aspiration hazard Does not meet the classification criteria for this hazard class.
11.2 Information on other hazards
Endocrine disrupting properties None of the ingredients is listed.
Other information No further relevant information available.
12-Ecological Information
- 12.1 Toxicity: No further relevant information available.
- 12.2 Persistence and degradability: No further relevant information available.
- 12.3 Bioaccumulative potential: No further relevant information available.
- 12.4 Mobility in soil: No further relevant information available.
- 12.5 Results of PBT and vPvB assessment: No further relevant information available.
- 12.6 Endocrine disrupting properties: No further relevant information available.
- 12.7 Other adverse effects:
- General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13-Disposal Considerations
13.1 Waste treatment methods
- Product: Do not discharge into environment, directly. Disposal must be performed through an authorized waste management firm, in compliance with national and local regulations.
- Package: Contaminated or damaged package must be recovered or disposed of in compliance with national waste management regulations.
14-Transport Information
- 14.1 UN number or ID number: Not applicable.
- 14.2 UN proper shipping name: Not applicable.
- 14.3 Transport hazard class(es): Not applicable.
- 14.4 Packing group: Not applicable.
- 14.5 Environmental hazards: Not applicable.
- 14.6 Special precautions for user: Not applicable.
- 14.7 Maritime transport in bulk according to IMO instruments: Information not relevant.
15-Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.
- CLP category: None
- Restrictions relating to the product or contained substances pursuant to Table 3.1 to EC Regulation 1272/2008(CLP): None
- Substances in Candidate List(SVHC in REACH): None
15.2 Chemical safety assessment
A Chemical Safety Assessment has not been carried out.
16-Additional Information
Other information:
This SDS was prepared in accordance with CLP Regulation (EC) No 1272/2008, (EU) 2020/878, EC No 1907/2006, REACH, GB/T16483-2008 and GB13690-2009.
Disclaimer:
The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.
Abbreviations and acronyms:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CAS: Chemical Abstracts Service
- CLP: Classification, Labeling and Packaging of substances and mixtures
- SVHC: Substances of Very High Concern
- REACH: Registration, Evaluation, Authorization and Restriction of Chemicals
- DOT: Department of transportation
- EC: Effective concentration
- EC50: Effective concentration, 50 percent
- EINECS: European Inventory of Existing Chemical Substance
- IAIA: International Association for Impact Assessment
- ICAO: International Civil Aviation Organization
- IMO: International Maritime Organization
- IMDG: International Maritime Dangerous Goods
- LC50: Lethal concentration, 50 percent
- LD50: Lethal dose, 50 percent
- NOEC: No Observed Effect Concentration
- OSHA: Occupational Safety and Health Administration (U.S.A.)
- STEL: Short Term Exposure Limit
- TWA: Time Weighted Average
- TLVTN: Threshold Limit Value
- VOC: Volatile Organic Compounds
